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Refinement Mechanism of the Solidification Structure of Cu--20%Pb Hypomonotectic Alloy by Deeply Undercooled Treatment |
LIU Liqin; ZHANG Zhongming; XU Chunjie; GUO Xuefeng |
School of Materials Science and Engineering; Xi'an University of Technology |
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Cite this article:
LIU Liqin; ZHANG Zhongming; XU Chunjie; GUO Xuefeng. Refinement Mechanism of the Solidification Structure of Cu--20%Pb Hypomonotectic Alloy by Deeply Undercooled Treatment. Acta Metall Sin, 2007, 43(11): 1138-1144 .
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Abstract The solidification microstructure of Cu-20%Pb hypomonotectic alloy was investigated by means of combination of melted glass denucleation and cyclical superheating. The variation of thermomechanical parameters related to solidification of undercooled Cu-20%Pb hypomonotectic alloy was calculated based on the BCT-LKT dendritic growth model, thus the solidification mechanism of the alloy was discussed. The experimental results shows that the microstructure of Cu-20%Pb hypomonotectic alloy combines α(Cu) dendrites with Pb phases distributed between them at little undercooling solidification. Dendrites get refined and uniformed as undercooling increases. It can be concluded that the reason of dendrite refinement at different undercooling is not same. The melt can be heated above the solidus temperature due to release of latent heat during rapid solidification of the undercooled melt, thus part of solidified dendrites can be melted and refined when the undercooling is smaller than 200K. When undercooling is high, the contraction of different parts of dentrites and flow velocity of the melt are so high that the dendrites are impacted and become fragmented. Thus when undercooling is above 200K, dentrites will be refined by dendrite remelting and dendrite fragmentation together.
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Received: 06 March 2007
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