Please wait a minute...
Acta Metall Sin  2014, Vol. 50 Issue (10): 1179-1188    DOI: 10.11900/0412.1961.2014.00078
Current Issue | Archive | Adv Search |
INVESTIGATION OF AUSTENITIZATION DURING CONTINUOUS HEATING PROCESS IN HYPEREUTECTOID STEELS
LI Junjie, Godfrey Andrew(), LIU Wei, ZHANG Chi
Key Laboratory of Advanced Materials, Ministry of Education, School of Materials Science and Engineering, Tsinghua University, Beijing 100084
Cite this article: 

LI Junjie, Godfrey Andrew, LIU Wei, ZHANG Chi. INVESTIGATION OF AUSTENITIZATION DURING CONTINUOUS HEATING PROCESS IN HYPEREUTECTOID STEELS. Acta Metall Sin, 2014, 50(10): 1179-1188.

Download:  HTML  PDF(9202KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

Cold-drawn pearlitic steel wires exhibit ultrahigh strength and have important applications where high strength and wear resistance are required. The hypereutectoid compositions present a promising potential for increasing the mechanical properties, especially the strength. The austenitization process strongly influences the following pearlitic microstructure and thus the mechanical properties. Continuous heating is always used in the industrial processing. However, the austenitization of pearlite in hypereutectoid steels during continuous heating has not been investigated systematically. In this work, the dilatometer and DSC were employed to investigate the austenitization kinetics of hypereutectoid steels during continuous heating. Microstructure evolution was observed with SEM and EBSD. The dilatometer and DSC curves were analyzed with derivative method. The whole austenitization can be divided into five stages: initial microstructure, reverse eutectoid transformation, retained cementite dissolution, homogenization and homogeneous austenite. Tangent method was used for measuring the critical temperatures of different stages. Experimental determination of transformed fraction was obtained through the lever method. Calculation with Thermo-Calc and Dictra software was carried out for the austenitization and considered to be a reasonable result by comparing with the experimental data. There is a turning point for the reduction rate of cementite and formation of austenite at the finishing temperature of reverse eutectoid transformation, which is similar with the austenitization in low carbon steel and spheroidal pearlite of hypereutectoid steel. Effects of heating rates, initial microstructure and carbon content were studied by varying the relevant parameters. Higher heating rate increases the starting and finishing temperatures of reverse eutectoid transformation and widens the temperature range, has no effect on the finishing temperature of retained cementite dissolution, increases the finishing temperature of homogenization. Coarser initial pearlitic microstructure increases the starting and finishing temperatures, widens the temperature range for reverse eutectoid transformation, increases the finishing temperature for retained cementite dissolution and homogenization. Enhancement of carbon content has little effect on the reverse eutectoid transformation, but increases the finishing temperature for retained cementite dissolution and homogenization. The effects mentioned above on the austenitization kinetics were discussed for mechanism analysis and compared with the observations of relevant systems provided by other research.

Key words:  continuous heating      hypereutectoid steel      austenitization      heating rate      initial microstructure      carbon content     
ZTFLH:  TG142.1  

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2014.00078     OR     https://www.ams.org.cn/EN/Y2014/V50/I10/1179

Fig.1  SEM images of initial microstructures in 0.90C (a), 1.05C (b), 1.10C (c) and 1.10C-c (d) hypereutectoid steel samples
Fig.2  EBSD images of initial nodule microstructures in 0.90C (a), 1.05C (b), 1.10C (c) and 1.10C-c (d) hypereutectoid steel samples
Fig.3  Dilatometric raw curve (a) and dilatometric derivative curve (b) in 1.10C sample with heating rate of 0.5 ℃/s
Fig.4  SEM images of microstructure evolution in 1.10C sample with heating rate of 0.5 ℃/s at 700 ℃ (a), 740 ℃ (b), 800 ℃ (c), 900 ℃ (d) and 950 ℃ (e)
Fig.5  Determination of transformed fraction through lever rule (a) and kinetics curve of reverse eutectoid transformation (b) in 1.10C sample with heating rate of 0.5 ℃/s
Fig.6  DSC raw curve (a) and derivative curve (b) in 1.10C sample with heating rate of 0.5 ℃/s
Fig.7  Calculation results for volume fraction of different phases in 1.10C sample with heating rate of 0.5 ℃/s (The arrow shows the turning point of cementite reduction rate)
Fig.8  Dilatometric derivative curves (a) and kinetics curves of reverse eutectoid transformation (b) in 1.10C sample with heating rates of 0.5, 10 and 45 ℃/s
Fig.9  Dictra calculation result for change of reverse eutectoid transformation rates with temperature in 1.10C sample
Fig.10  Dilatometric derivative curves (a) and kinetics curves of reverse eutectoid transformation (b) for 1.10C and 1.10C-c samples with heating rate of 0.5 ℃/s
Fig.11  Dilatometric derivative curves (a) and kinetics curves of reverse eutectoid transformation (b) in 0.90C, 1.05C and 1.10C samples with heating rate of 10 ℃/s
[1] Li Y J, Choi P, Goto S, Borchers C, Raabe D, Kirchheim R. Acta Mater, 2012; 60: 4005
[2] Tashiro H. Nipp Steel Technol Rep, 1999; 80: 6
[3] Choi H C, Park K T. Scr Mater, 1996; 34: 857
[4] Taleff E M, Sridhar G B, Pourladian B. Wire J Int, 2003; 36: 73
[5] Bae C M, Nam W J, Lee C S. Metall Mater Trans, 2000; 31A: 2665
[6] Li J J, Godfrey A, Liu W. Acta Metall Sin, 2013; 49: 583
(李俊杰, Godfrey Andrew, 刘 伟. 金属学报, 2013; 49: 583)
[7] Lee S J, Park J S, Lee Y K. Scr Mater, 2008; 59: 87
[8] Chae J Y, Jang J H, Zhang G, Kim K H, Lee J S, Bhadeshia H, Suh D W. Scr Mater, 2011; 65: 245
[9] San Martin D, Rivera-Diaz-Del-Castillo P E J, Garcia-De-Andres C. Scr Mater, 2008; 58: 926
[10] Shtansky D V, Nakai K, Ohmori Y. Acta Mater, 1999; 47: 2619
[11] Karmazin L, Krejci J. Mater Sci Eng, 1994; A185: 5
[12] De Andres C , Caballero F G, Capdevila C, Alvarez L F. Mater Charact, 2002; 48: 101
[13] Gupta C, Dey G K, Chakravartty J K, Srivastav D, Banerjee S. Scr Mater, 2005; 53: 559
[14] Xu G, Wan L, Yu S F, Liu L, Luo F. Mater Lett, 2008; 62: 3978
[15] Li Z D, Miyamoto G, Yang Z G, Furuhara T. Metall Mater Trans, 2011; 42A: 1586
[16] Yang Z N, Yang Z G, Xia Y, Zhang C. Acta Metall Sin, 2013; 49: 890
(杨泽南, 杨志刚, 夏 苑, 张 弛. 金属学报, 2013; 49: 890)
[17] Xia Y, Enomoto M, Yang Z G, Li Z D, Zhang C. Philos Mag, 2013; 93: 1095
[18] Han K, Mottishaw T D, Smith G, Edmonds D V, Stacey A G. Mater Sci Eng, 1995; A190: 207
[19] Zhang Y D, Esling C, Gong M L, Vincent G, Zhao X, Zuo L. Scr Mater, 2006; 54: 1897
[20] Walentek A, Seefeldt M, Verlinden B, Aernoudt E, Van Houtte P. J Microsc, 2006; 224: 256
[21] Farahat A. J Mater Process Technol, 2008; 204: 365
[22] Liu Y C, Sommer F, Mittemeijer E J. Acta Mater, 2006; 54: 3383
[23] Liu Y C, Sommer F, Mittemeijer E J. Acta Mater, 2003; 51: 507
[24] Oliveira F L G, Andrade M S, Cota A B. Mater Charact, 2007; 58: 256
[25] Scheil E. Arch Eisenhutten, 1935; 8: 565
[26] Li Z D, Miyamoto G, Yang Z G, Furuhara T. Scr Mater, 2009; 60: 485
[27] Caballero F G, Capdevila C, de Andres C G. Mater Sci Technol, 2001; 17: 686
[28] Caballero F G, Capdevila C, de Andres C . Metall Mater Trans, 2001; 32A: 1283
[1] Zukun YANG, Changsheng ZHANG, Beibei PANG, Yanyan HONG, Fangjie MO, Zhao LIU, Guang'ai SUN. Effect of Initial Microstructures on the Macroscopic Mechanical Properties of Polycrystalline Beryllium[J]. 金属学报, 2018, 54(8): 1150-1156.
[2] Yonghua RONG,Nailu CHEN. The Principle and Mechanism of Enhancement of Both Strength and Ductility of Martensitic Steels by Carbon[J]. 金属学报, 2017, 53(1): 1-9.
[3] HU Ke, LI Xiaoqiang, QU Shengguan, YANG Chao, LI Yuanyuan. DEVELOPMENT OF MASTER SINTERING CURVE FOR SPARK PLASMA SINTERING OF 93W-5.6Ni-1.4Fe HEAVY ALLOY[J]. 金属学报, 2014, 50(6): 727-736.
[4] XIA Dongsheng, YANG Ping, XIE Li, MAO Weimin. INFLUENCE OF HEATING RATE ON THE DECARBU- RIZED ANNEALING MICROSTRUCTURE AND TEXTURE IN LOW-CARBON NON-ORIENTED ELECTRICAL STEEL[J]. 金属学报, 2014, 50(12): 1437-1445.
[5] LI Junjie, Godfrey Andrew, LIU Wei. EFFECTS OF AUSTENITIZATION AND COOLING RATES  ON THE MICROSTRUCTURE IN A HYPEREUTECTOID STEEL[J]. 金属学报, 2013, 49(5): 583-592.
[6] FU Bo, YANG Wangyue, LI Longfei, SUN Zuqing. EFFECT OF CARBON CONTENT ON MICROSTRUCTURE AND MECHANICAL PROPERTIES OF COLD-ROLLED C-Mn-Al-Si TRIP STEEL[J]. 金属学报, 2013, 29(4): 408-414.
[7] ZHANG Jie, CAI Qingwu, WU Huibin, FAN Yanqiu. EFFECT OF TEMPERING TEMPERATURE ON MICRO-STRUCTURE AND PROPERTY OF 690 MPa GRADE OCEAN ENGINEERING STEEL UNDER FAST HEATING RATE[J]. 金属学报, 2013, 49(12): 1549-1557.
[8] LI Zhaodong MIYAMOTO Goro YANG Zhigang ZHANG Yuduo ZHANG Chi FURUHARA Tadashi. EFFECTS OF Mn AND Si ADDITIONS ON PEARLITE-AUSTENITE PHASE TRANSFORMATION IN Fe-0.6C STEEL[J]. 金属学报, 2010, 46(9): 1066-1074.
[9] CHEN Wei LI Longfei SUN Zuqing ZHANG Yan YANG Wangyue. ULTRAFINED MICROSTRUCTURE OF HYPEREUTECTOID STEEL BY WARM DEFORMATION OF MARTENSITE[J]. 金属学报, 2009, 45(6): 697-703.
[10] CHEN Wei LI Longfei YANG Wangyue SUN Zuqing ZHANG Yan. MICROSTRUCTURE EVOLUTION OF HYPEREUTECTOID STEELS DURING WARM DEFORMATION II. Cementite Spheroidization and Effects of Al[J]. 金属学报, 2009, 45(2): 156-160.
[11] ;. Dynamic Phase Transformation and Spheroidization of Cementite of Hypereutectoid Steel Containing Aluminum during Deformation[J]. 金属学报, 2008, 44(9): 1069-1075 .
[12] WANG Shun-Cheng; Yuan-Yuan LI; Wei-Ping CHEN; Guo-Ru PAN. Effect of heating rate on microstructure of semi-solid 2024 alloy during partial remelting[J]. 金属学报, 2008, 44(8): 905-910 .
[13] WANG Xiaoying; ZHANG Ruijie; JIE Wanqi. DISSOLUTION OF THE SECOND PHASE DURING CONTINUOUS HEATING PROCESS[J]. 金属学报, 2004, 40(4): 434-438 .
[14] JIANG Qing;XU Xiaoya;ZHAO Ming (Jilin University of Technoloasl; Changchun 130025). RELATIONSHIP BETWEEN VOGELFULCHER LAW AND GLASS TRANSITION TEMPERATURE[J]. 金属学报, 1997, 33(7): 763-768.
[15] KANG Mokuang; YANG Yanqing; ZHANG Xiyan; SUN Jialin; JIA Husheng; WU Hiaolei (Northwestern Polytechnical University; Xi'an 710072). BAINITIC TRANSFORMATIONS IN SILICON-CONTAINING STEELS[J]. 金属学报, 1996, 32(9): 897-903.
No Suggested Reading articles found!