THERMAL STABILITY AND DEUTERIUM ABSORPTION AT ROOM TEMPERATURE OF Ti36Zr40Ni20Pd4 QUASICRYSTAL

doi:10.3724/SP.J.1037.2009.00821

Acta Metall Sin

2010, Vol. 46

Issue (5): 629-633 DOI: 10.3724/SP.J.1037.2009.00821

论文

Current Issue | Archive | Adv Search

THERMAL STABILITY AND DEUTERIUM ABSORPTION AT ROOM TEMPERATURE OF Ti₃₆Zr₄₀Ni₂₀Pd₄ QUASICRYSTAL

HUANG Huogen¹⁾; CHEN Liang²⁾; LI Rong²⁾; LUO Deli²⁾

1) National Key Lab for Surface Physics and Chemistry; Mianyang 621907 2) China Academy of Engineering Physics; Mianyang 621900

Cite this article:

HUANG Huogen CHEN Liang LI Rong LUO Deli. THERMAL STABILITY AND DEUTERIUM ABSORPTION AT ROOM TEMPERATURE OF Ti₃₆Zr₄₀Ni₂₀Pd₄ QUASICRYSTAL. Acta Metall Sin, 2010, 46(5): 629-633.

Download:

PDF(754KB)
Export: BibTeX | EndNote (RIS)

Abstract

Ti-Zr-Ni quasicrystals can absorb a large amount of hydrogen, so have strong application potential in the hydrogen energy field and international thermonuclear experimental reactor (ITER) program. However, the hydrogenation of the quasicrystals is often hindered and even poisoned due to their surface oxidation. To inhibit the oxidation, Pd has been selected, because of its catalysis to hydrogen absorption, as a minor alloying element in Ti-Zr-Ni quasicrystals. In this paper, the Ti₃₆Zr₄₀Ni₂₀Pd₄ alloy was designed and its thermal stability and room--temperature deuteration were studied with XRD, DSC, OM, XPS and gas--solid reaction measurement apparatus. The XRD result shows that a single icosahedral quasicrystal (IQC) phase with a quasilattice constant a_R=0.5174 nm was formed in the alloy by suction-casting method, which is metastable and transforms to conventional crystals tI-Zr₂Ni and C14-TiZrNiPd (MgZn₂ type) phase at about 400℃. The deuteration test below the transformed temperature indicates that the alloy can absorb deuterium up to a large concentration of 11.0 mmol/g (corresponding to 2.2%H, mass fraction) at room temperature after vacuuming and heating activation without any surface treatment. Once fully activated, the IQC can load deuterium rapidly with an absorption rate of\linebreak 0.030 s^-1 at ambient temperature, and has the quasilattice constant with about 5.5% expansion after two absorption cycles. The Ti₃₆Zr₄₀Ni₂₀Pd₄ IQC has better activation property and hydrogen capacity than the Ti₄₀Zr₄₀Ni₂₀ IQC, which shows the catalyzing function of Pd.

Key words: Ti-Zr-Ni-Pd alloy quasicrystal deuterium catalyzing

Received: 10 December 2009

Fund:

Supported by Science and Technology Development Foundation of China Academy of Engineering Physics (No.2007A07002)

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	HUANG Huo-Gen
	CHEN Liang
	LI Rong

URL:

https://www.ams.org.cn/EN/10.3724/SP.J.1037.2009.00821 OR https://www.ams.org.cn/EN/Y2010/V46/I5/629

[1] Bogdanovic B, Schwickardi M. Appl Phys, 2001; 72A: 221
[2] Chen P, Xiong Z T, Luo J Z, Lin J Y, Tan K L. Nature, 2002; 420: 302
[3] Xiong Z T, Yong C K, Wu G T, Chen P, Shaw W, Karkamkar A, Autrey T, Jones M O, Johnson S R, Edwards P P, David W I F. Nat Mater, 2008; 7: 138
[4] Feng K M. Chin Nucl Power, 2009; 2: 212
(冯开明. 中国核电, 2009; 2: 212)

[5] Gibbons P C, Hennig R G, Huett V T, Kelton K F. J Non–Cryst Solids, 2004; 334: 461
[6] Kelton K F, Hartzell J J, Hennig R G, Huett V T, Takasaki A. Philos Mag, 2006; 86: 957
[7] Liu B Z, Liu D M, Wu Y M, Li L Q, Wang L M. Int J Hydro Energy, 2007; 32: 2429
[8] Liu B Z, Wu Y M, Wang L M. J Power Source, 2006; 162: 713
[9] Liu B Z, Wu Y M, Wang L M. J Power Source, 2006; 159: 1458
[10] Liu B Z, Wu Y M, Wang L M. Int J Hydrogen Energy, 2006; 31: 1394
[11] Liu B Z, Wu Y M, Wang L M. Rare Met, 2007; 26: 440
[12] Takasaki A, Huett V T, Kelton K F. J Non–Cryst Solids, 2004; 334: 457
[13] Takasaki A, Kelton K F. Int J Hydrogen Energy, 2006; 31: 183
[14] Hennig R G, Majzoub E H, Carlsson A E, Kelton K F, Henley C L, Yelon W B, Misture S. Mater Sci Eng, 2000; 294A: 361
[15] Kim J Y, Hennig R, Huett V T, Gibbons P C, Kelton K F. J Alloys Compd, 2005; 404: 388
[16] Huang H G, Dong P, Yin C, Zhang P C, Bai B, Dong C. Int J Hydrogen Energy, 2008; 33: 722
[17] Huang H G, Li R, Yin C, Zheng S T, Zhang P C. Int J Hydrogen Energy, 2008; 33: 4607
[18] Liu B Z, Liu J J, Mi G F, Zhang Z, Wu Y M, Wang L M. J Alloys Compd, 2009; 475: 881
[19] Liu B Z, Zhang Y D, Mi G F, Zhang Z, Wang L M. Int J Hydrogen Energy, 2009; 34: 6925
[20] Huang H G, Yin C, Wu J, Zhang P C. Chin J Nonferrous Met, 2008; 18: 108
(黄火根, 银陈, 吴江, 张鹏程. 中国有色金属学报, 2008; 18: 108)

[21] Cahn J W, Shechtman D, Gratias D. J Mater Res, 1986; 1: 13
[22] Qiang J B, Wang Y M, Wang D H, Dong C. Rare Met Mater Eng, 2004; 33: 949
(羌建兵, 王英敏, 王德和, 董闯. 稀有金属材料与工程, 2004; 33: 949)

[23] Huang H G, Jia J P, Li R. Acta Metall Sin, 2009; 45: 1272
(黄火根, 贾建平, 李嵘. 金属学报, 2009; 45: 1272)
[24] Hirooka Y, Miyake M, Sano T. J Nucl Mater, 1981; 96: 227
[25] Huang L J, Yu B X, Gao S J. Met Funct Mater, 1998; 5: 124
(黄利军, 虞炳西, 高树浚. 金属功能材料, 1998; 5: 124)
[26] Wang W W, Long X G. J Nucl Radiochem, 2007; 29: 80
(王伟伟, 龙兴贵. 核化学与放射化学, 2007; 29: 80)
[27] Coddens G, Viano A M, Gibbons P C, Kelton K F, Kramer M J. Solid State Comm, 1997; 104: 179
[28] Faust K R, Pfitsch D W, Stojanovich N A, McDowell A F, Adolphi N L, Majzoub E H, Kim J Y, Gibbons P C, Kelton K F. Phys Rev, 2000; 62B: 11444

[1]	CHEN Yongjun, BAI Yan, DONG Chuang, XIE Zhiwen, YAN Feng, WU Di. Passivation Behavior on the Surface of Stainless Steel Reinforced by Quasicrystal-Abrasive via Finite Element Simulation[J]. 金属学报, 2020, 56(6): 909-918.
[2]	Dongjun FAN, Guangda LU, Guikai ZHANG, Jinchun BAO, Feilong YANG, Xin XIANG, Chang'an CHEN. Deuterium and Tritium Permeation in the Reduced Activation Ferritic/Martensitic Steel[J]. 金属学报, 2018, 54(4): 519-526.
[3]	Gaowu QIN, Hongbo XIE, Hucheng PAN, Yuping REN. A New Class of Ordered Structure Between Crystals and Quasicrystals[J]. 金属学报, 2018, 54(11): 1490-1502.
[4]	Zhibin FAN, Xiaoping LIN, Yun DONG, Jie YE, Chan LI, Bo LI. AGE-HARDENING RESPONSE FOR Mg_96.17Zn_3.15Y_0.5Zr_0.18 SOLID SOLUTION ALLOY UNDER HIGH PRESSURE[J]. 金属学报, 2016, 52(12): 1491-1496.
[5]	Cheng ZHANG,Xiping SONG,Jingru LIU,Yun YANG,Li YOU. EFFECTS OF DEUTERIUM CONTENT ON MICROSTRUCTURE AND MECHANICAL PROPERTIES OF Zr-4 ALLOY[J]. 金属学报, 2016, 52(12): 1572-1578.
[6]	Yongjun CHEN, Xiaogang HU, Jianbing QIANG, Chuang DONG. QUASICRYSTAL ABRASIVE POLISHING ON SOFT METALS VIA A CHARACTERISTIC SMEARING WEAR MECHANISM FOR EFFICIENT SURFACE FLATTENING, HARDENING AND CORROSION ENHANCEMENT[J]. 金属学报, 2016, 52(10): 1353-1362.
[7]	Yun YANG,Xiping SONG. INFLUENCE OF ALLOY ELEMENT Cu ON KINETIC MECHANISMS OF DEUTERIUM ABSORPTION IN ZIRCONIUM[J]. 金属学报, 2016, 52(1): 100-104.
[8]	TONG Jian HUANG Hua YUAN Guangyin DING Wenjiang. HOT COMPRESSION DEFORMATION BEHAVIOR OF Mg–Zn–Al–(Y) ALLOYS REINFORCED WITH QUASICRYSTAL[J]. 金属学报, 2011, 47(12): 1520-1526.
[9]	HUANG Huogen JIA Jianping LI Rong. EFFECT OF Pd SUBSTITUTION ON THE STRUCTURES OF Ti-Zr-Ni QUASICRYSTALLINE ALLOYS[J]. 金属学报, 2009, 45(10): 1272-1276.
[10]	. Quasicrystals in Al-Cu-Ni-Fe Quaternary System[J]. 金属学报, 2007, 43(4): 374-378 .
[11]	QIANG Jianbing; HUANG Huogen; WANG Yingmin; JIANG Nan; DONG Chuang. COMPOSITIONAL CHARACTERISTIC OF TERNARY QUASICRYSTALS IN Ti--Zr--Ni SYSTEM[J]. 金属学报, 2004, 40(7): 677-682 .
[12]	DENG Binbin; GUO Kexin. Stability of the Ag42In42Ca16 Icosahedral Quasicrystal and Its 2/1 Cubic Approximant[J]. 金属学报, 2004, 40(2): 120-124 .
[13]	QI Yuhong;ZHANG Zhanping;HEI Zukun (Institute of Metal and Technology; Dalian Maritime University; Dalian 116026)QUAN Mingliu (Institute of Metal Research; The Chinese Academy of Sciences; Shenyang 110015)DONG Chuang (Dalian University of Technology; 116024). DIFFUSION-CONTROLLED PHASE TRANSFORMATIONS OF Al_(65)Cu_(20)Cr_(15) QUASICRYSTALLINE PARTICLES/AI MATRIX COMPOSITES[J]. 金属学报, 1998, 34(1): 19-23.
[14]	CHEN Lifan;CHEN Xichen;(Institute of physics;Chinese A cademy of Sciences;Beijing 100080)(Manuscript received 94-07-05). Al-Cu-Co-Ge SINGLE DECAGONAL QUASICRYSTALS GROWTH BY DIRECTIONAL SOLIDIFICATION[J]. 金属学报, 1995, 31(1): 1-6.
[15]	GUAN Shaokang; TANG Yali; SHEN Ningfu(Zhengzhou Institute of Technology);HU Hanqi(University of Science and Technology Beijing)(Manuscript received 8 April; 1993; in revised form 14 June; 1993). FORMATION AND STABILITY OF QUASICRYSTALLINE PHASE IN RS Al-Fe BASED ALLOY RIBBON[J]. 金属学报, 1994, 30(4): 150-154.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed