EFFECT OF DAMNIFICATION IN RUST LAYER ON CORROSION BEHAVIORS OF LOWCARBON BAINITIC STEEL IN THE ENVIRONMENT CONTAINING Cl−

Acta Metall Sin

2009, Vol. 45

Issue (4): 442-449 DOI:

论文

Current Issue | Archive | Adv Search

EFFECT OF DAMNIFICATION IN RUST LAYER ON CORROSION BEHAVIORS OF LOWCARBON BAINITIC STEEL IN THE ENVIRONMENT CONTAINING Cl⁻

CUI Lei; YANG Shanwu; WANG Shutao; GAO Kewei; HE Xinlai

School of Materials Science and Engineer; University of Science and Technology Beijing; Beijing 100083

Cite this article:

CUI Lei YANG Shanwu WANG Shutao GAO Kewei HE Xinlai. EFFECT OF DAMNIFICATION IN RUST LAYER ON CORROSION BEHAVIORS OF LOWCARBON BAINITIC STEEL IN THE ENVIRONMENT CONTAINING Cl⁻. Acta Metall Sin, 2009, 45(4): 442-449.

Download:

PDF(2579KB)
Export: BibTeX | EndNote (RIS)

Abstract

The weatherability of weathering steel depends on the protection of the compact rust layers on its surface. However, the compact rust layers might be damaged when they were subject to external actions, for example, collision and scrape etc., which will influence the protective effect on steel base. It is deserved to put attention on further corrosion behavior of the samples with damaged rust layer, which will determine the long term corrosion property. In the present study, electrochemical measurement, metallographic observation and energy disperse spectrum analysis were employed to investigate the further corrosion behaviors of a low carbon bainitic steel in the environment containing Cl⁻, after its original rust layers had been damaged on different degrees. It was found that the damnification of rust layers on both the low carbon bainitic steel and low carbon steel as a contrast could be rapidly self–repaired in the further corrosion process. When damnification degree and further corrosion time are the same, the resistance and the repair ratio of damaged rust layers on the low carbon bainitic steel are higher than those of the low carbon steel. The fracture toughness of the steel base/rust layer interface of the low carbon bainitic steel is higher than that of the rust layers, so the rust layers would not be abscised thoroughly from the interface and some residual rust would be remained when the steel is subjected to applied actions. The formation of new rust at the damaged sites can be significantly promoted by the residual rust. The contents of Cu and Cr in the original rust layers are close to those in the newly formed rust layers, and both of them are equivalent to those in the steel base. These results indicate that low carbon bainitic steel with excellent mechanical properties and weld ability is a potential candidate for novel weathering steels with higher strength.

Key words: low carbon bainitic steel rust layer damnification self–repair

Received: 08 October 2008

ZTFLH:

TG172.3

Fund:

Supported by National Basic Research Program of China (No. 2004CB619102)

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	CUI Lei
	YANG Shan-Wu

URL:

https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y2009/V45/I4/442

[1] Zhao Z Y. The Design of Alloy Steels. Beijing: National Defense Industry Press, 1999: 106
(赵振业. 合金钢设计. 北京: 国防工业出版社, 1999: 106)
[2] Wang X M, Shang C J, Yang S W, He X L. Acta Metall Sin, 2002; 38: 661
(王学敏, 尚成嘉, 杨善武, 贺信莱. 金属学报, 2002; 38: 661)
[3] Shang C J, Wang X M, Yang S W, He X L, Wu H B. Acta Metall Sin, 2002; 39: 1019
(尚成嘉, 王学敏, 杨善武, 贺信莱, 武会宾. 金属学报, 2003; 39: 1019)
[4] Zhang Z G, Gu Z Y, Liao Y G, Guo Q L, Su F T, Chen Y Z. Electrochemistry, 2000; 6: 473
(张志刚, 辜志俊, 廖永贵, 郭琦龙, 苏方腾, 陈衍珍. 电化学, 2000; 6: 473)
[5] Tan Y J, Bailey S, Kinsella B. Corros Sci, 1996; 38: 1545
[6] Nishimura T, Kodama T. Corros Sci, 2003; 45: 1073
[7] Nishimura T, Tahara A, Kodama T. Mater Trans, 2001;42: 478
[8] Lin C, Li X G, Liu X D. J Chin Soc Corros Prot, 2005; 25: 4

(林翠, 李晓刚, 刘晓东. 中国腐蚀与防护学报, 2005; 25: 4)

[9] WanJ H, Wei F I, Chang Y S, Shih H C. Mater Chem Phys, 1997; 47: 1
[10] Han W, Wang J, Wang Z Y, Yu G C, Li H X. J Chin Soc Corros Prot, 2004; 24: 147
(韩薇, 汪俊, 王振尧, 于国才, 李洪锡. 中国腐蚀与防护学报, 2004; 24: 147)
[11] Nishimura T, Katayama H, Noda K, Kodama T. Corrosion, 2000; 56: 935
[12] Wang S T, Yang S W, Gao K W, Shen X A, He X L. Acta Metall Sin, 2008; 44: 1116
(王树涛, 杨善武, 高克玮, 沈晓安, 贺信莱. 金属学报, 2008; 44: 1116)
[13] Liu L H, Qi H B, Lu Y P, Li X G. Corros Sci Technol Prot, 2003; 15: 86
(刘丽宏, 齐慧滨, 卢燕平, 李晓刚. 腐蚀科学与防护技术, 2003; 15: 86)
[14] Choi Y S, Shim J J, Kim J G. J Alloys Compd, 2005; 391: 162
[15] Chi Y S, Shim J J, Kim J G. Mater Sci Eng, 2004; A385: 148
[16] Zhang Q C, Wang J J, Wu J S, Zheng W L, Chen J G, Li A B. Acta Metall Sin, 2001; 37: 193
(张全成, 王建军, 吴建生, 郑文龙, 陈家光, 李爱柏. 金属学报, 2001; 37: 193)
[17] Matsushima I, Ueno T, Tamada A, Kubota H. Nippon Kokan Technol Rep, 1969; 46: 249
[18] Okada H, Hosoi Y, Yukawa K, Naito H. Tetsu–to–Hagan´e, 1969; 55: 355
(岗田秀弥, 细井佑三, 汤川惠一,内藤浩光. 铁と钢, 1969; 55: 355)
[19] Misawa T, Yamashita M, Matsuda Y, Miyuki H, Nagano H. Tetsu–to–Hagan´e, 1993; 79: 69
(三尺俊平, 山下正人,松田恭司, 幸英昭, 长野博夫. 铁と钢, 1993; 79: 69)
[20] Yamashita M, Miyuki H, Matsuda Y, Nagano H, Misawa T. Corros Sci, 1994; 36: 283

[1]	CHEN Wenjuan, HAO Long, DONG Junhua, KE Wei, WEN Huailiang. EFFECT OF pH VALUE ON THE CORROSION EVOLUTION OF Q235B STEEL IN SIMULATED COASTAL-INDUSTRIAL ATMOSPHERES[J]. 金属学报, 2015, 51(2): 191-200.
[2]	PENG Xin WANG Jia SHAN Chuan WANG Haijie LIU Zaijian ZOU Yan. CORROSION BEHAVIOR OF LONG–TIME IMMERSED RUSTED CARBON STEEL IN FLOWING SEAWATER[J]. 金属学报, 2012, 48(10): 1260-1266.
[3]	LAN Liangyun QIU Chunlin ZHAO Dewen LI Canming GAO Xiuhua DU Linxiu. MICROSTRUCTURAL CHARACTERS AND TOUGHNESS OF DIFFERENT SUB–REGIONS IN THE WELDING HEAT AFFECTED ZONE OF LOW CARBON BAINITIC STEEL[J]. 金属学报, 2011, 47(8): 1046-1054.
[4]	LIU Jie LI Xiangbo WANG Jia. EFFECT OF HYDROSTATIC PRESSURE ON THE CORROSION BEHAVIORS OF TWO LOW ALLOY STEELS[J]. 金属学报, 2011, 47(6): 697-705.
[5]	GAO Guhui ZHANG Han BAI Bingzhe. EFFECT OF TEMPERING TEMPERATURE ON LOW TEMPERATURE IMPACT TOUGHNESS OF A LOW CARBON Mn-SERIES BAINITIC STEEL[J]. 金属学报, 2011, 47(5): 513-519.
[6]	CAO Guoliang LI Guoming CHEN Shan CHANG Wanshun CHEN Xuequn. STUDY ON RUST LAYERS AND PITTING CORROSION RESISTANCE OF Ni-Cu-P STEEL EXPOSED IN MARINE SPLASH ZONE[J]. 金属学报, 2011, 47(2): 145-151.
[7]	CAO Guoliang LI Guoming CHEN Shan CHANG Wanshun CHEN Xuequn. COMPARISON ON PITTING CORROSION RESISTANCE OF NICKEL AND CHROMIUM IN TYPICAL SEA WATER RESISTANCE STEELS[J]. 金属学报, 2010, 46(6): 748-754.
[8]	ZOU Yan ZHENG Yingying WANG Yanhua WANG Jia. CATHODIC ELECTROCHEMICAL BEHAVIORS OF MILD STEEL IN SEAWATER[J]. 金属学报, 2010, 46(1): 123-128.
[9]	ZHANG Hong QI Huibin DU Cuiwei LI Xiaogang. CORROSION BEHAVIOR OF THE HOT--DIP GALVANIZED STEEL SHEET UNDER ADHESION OF AN ALKALINE MUD IN HOT--HUMID ENVIRONMENTS[J]. 金属学报, 2009, 45(3): 338-344.
[10]	Shu-Tao WANG; Kewei GAO. CORROSION BEHAVIOR AND VARIATION OF APPARENT MECHANICAL PROPERTY OF ONE NEWLY-DEVELOPED LOW CARBON BAINITIC STEEL IN ENVIRONMENT CONTAINING CHLORIDE ION[J]. 金属学报, 2008, 44(9): 1116-1124 .
[11]	ZHANG Mingxing;KANG Mokuang Baotou Institute of Iron and Steel Technology; Noghwestern Polytechnical University; Xian. INFLUENCE OF Si ON MICROSTRUCTURE AND PROPERTIES OF LOW CARBON BAINITIC STEELS[J]. 金属学报, 1993, 29(1): 6-10.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed