Cyclicvoltamme Study on the Cathodic Behavior of CaO in CaCl2 and equalar mole CaCl2-X(X=NaCl, BaCl2, LiCl) Melts

Acta Metall Sin

2008, Vol. 44

Issue (6): 735-738 DOI:

Research Articles

Current Issue | Archive | Adv Search

Cyclicvoltamme Study on the Cathodic Behavior of CaO in CaCl2 and equalar mole CaCl2-X(X=NaCl, BaCl2, LiCl) Melts

东北大学

Cite this article:

. Cyclicvoltamme Study on the Cathodic Behavior of CaO in CaCl2 and equalar mole CaCl2-X(X=NaCl, BaCl2, LiCl) Melts. Acta Metall Sin, 2008, 44(6): 735-738 .

Download:

PDF(344KB)
Export: BibTeX | EndNote (RIS)

Abstract CaOˇs decomposition is an important reaction in the new titanium refining processes and is one of the key factors to affect the current efficiency and the energy consumption of the new titanium refining processes. In present work, the cathodic behaviors of CaO in CaCl2-0.5mol%CaO, equal molar CaCl2-NaCl-0.5mol%CaO, CaCl2-BaCl2-0.5mol%CaO and CaCl2-LiCl-0.5mol%CaOmelts were studied by cyclicvoltamme technique systematically. The reduced potentials of Ca2+ from CaCl2 and from CaO are different. NaCl doesnˇt affect the reduced potential of Ca2+ from CaO(hereafter named simply as φCa2+/Ca (⒐)), LiCl increases φCa2+/Ca (⒐) slightly, BaCl2 decreases φCa2+/Ca (⒐) evidently. The diffusion coefficients of Ca2+ from CaO in CaCl2-0.5mol%CaO, equal molar CaCl2-NaCl- 0.5mol%CaO, CaCl2-BaCl2-0.5mol%CaO and CaCl2-LiCl-0.5mol%CaO melts at 1173K were obtained.

Key words:

Received: 13 August 2007

ZTFLH:	TF803.2
	TG832

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

URL:

https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y2008/V44/I6/735

[1]Okabc T H,Nakamura M,Oishi T,Ono K.Metall Trans, 1993;20B:449
[2]Chen C Z,Fray D J,Farthing T W.Nature,2000;407: 361
[3]Yan X Y,Fray D J.Me,all Mater Trans,2000;33B:685
[4]Ono K,Suzuki R O.JOM,2002:54:59
[5]Jiao S Q,Zhu H M.J Mater Res,2006;21:2172
[6]Mohamedi M,Borresen B,Haarberg G M,Tunold R.J Electrochem Soc,1999;146:1472
[7]Mo W J,Duan S Z,Inman D.Chem J Chin Univ,1988; 9:547 (莫雯静，段淑珍，Inman D．高等学校化学学报，1988；9：547)
[8]Fray D J.In:Yamaguchi S ed.,16th IKETANI Conf: Electrochemistry and Thermodynamics on Materials Pro- cessing for Sustainable Production:Masuko Symposium, Tokyo:The 16th Iketani Conference Organizing Commit- tee,2006:269
[9]Freydina E B,Fray D J.Trans lnst Min Metall(Sect C: Miner Process Extr Metall),2002;111:C79
[10]Berzins T,Delahay P.J Am Chem Soc,1953;36:555

[1]	WANG Luning, LIU Lijun, YAN Yu, YANG Kun, LU Lili. *Influences of Protein Adsorption on the in vitro* Corrosion of Biomedical Metals**[J]. 金属学报, 2021, 57(1): 1-15.
[2]	TUNG Feng'en;WANG Yuming Institute of Materials Science; Jilin University; Changchun. X-RAY ANALYSIS OF WORK-HARDENING PROCESS FOR POLYCRYSTALLINE а-BRASS DURING UNIAXIAL TENSILE TEST[J]. 金属学报, 1989, 25(2): 82-84.
[3]	WANG Jinliang, WANG Chenchong, HUANG Minghao, HU Jun, XU Wei. The Effects and Mechanisms of Pre-Deformation with Low Strain on Temperature-Induced Martensitic Transformation[J]. 金属学报, 2021, 57(5): 575-585.
[4]	DU Hegui;LIU Xin Northeast University of Technology; Shenyang. KINETICS OF CARBON COMBUSTION IN PLASMA AIR[J]. 金属学报, 1989, 25(2): 85-88.
[5]	. [J]. 金属学报, 2001, 37(1): 42-46 .
[6]	. [J]. 金属学报, 1999, 35(3): 320-324 .
[7]	. [J]. 金属学报, 2000, 36(1): 72-76 .
[8]	. [J]. 金属学报, 1999, 35(3): 330-333 .
[9]	. [J]. 金属学报, 1999, 35(3): 334-336 .
[10]	. [J]. 金属学报, 2000, 36(6): 647-650 .
[11]	. [J]. 金属学报, 2000, 36(6): 655-658 .
[12]	No Author. ACTA METALLURGLCA SLNLCA Volume 28 Series A 1992 SUBJECT INDEX[J]. 金属学报, 1992, 28(12): 63-90.
[13]	. [J]. 金属学报, 2000, 36(7): 780-784 .
[14]	No Author. ACTA METALLURGICA SINICA(JINSHU XUEBAO) Volume 28 1992 AUTHOR INDEX[J]. 金属学报, 1992, 28(12): 71-94.
[15]	Хань Яо-вэнь Инсмцмум мемаддов АН КНР;Г.н.Ойкс Московскц цнсмцмум смадц. НЗУЧЕНИЕ ПРОЦЕССОВ ДЕСУЛЬФУРАЦИИ ХНДКОΓО МЕТАЛЛА В ВАКУУМЕ[J]. 金属学报, 1963, 6(2): 98-110.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed