Acta Metall Sin  2007, Vol. 43 Issue (11): 1228-1232     DOI:

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Characteristics of Proton Conductors BaCe1-xYxO3- and BaCe0.9Sm0.1O3- and Dehydrogenation of Al Melt with Composed Hydrogen Pump

WANG Dong; FAN Jianhua; LIU Chunming; WANG Changzhen

College of Materials and Metallurgy; Northeastern University

WANG Dong; FAN Jianhua; LIU Chunming; WANG Changzhen. Characteristics of Proton Conductors BaCe1-xYxO3- and BaCe0.9Sm0.1O3- and Dehydrogenation of Al Melt with Composed Hydrogen Pump. Acta Metall Sin, 2007, 43(11): 1228-1232 .

Abstract References Related Articles Recommended Metrics Download:  PDF(853KB)  Export:  BibTeX | EndNote (RIS)       Abstract  BaCe0.9Y0.1O3-α，BaCe0.85Y0.15O3-α and BaCe0.9Sm0.1O3-α proton conductors were prepared by solid state reaction. X-ray Diffraction(XRD) indicated the powders doped 10%Y were single perovskite phase. The powders doped 15%Y and 10%Sm didn`t have Y2O3 and Sm2O3 respectively. It was concluded that solid sulubility limit of Y is above 0.15 and that of Sm is above 0.10 in BaCeO3. By laser light scattering paticle size analysis indicated that average particle size of powders changed larger and particles that particle size is about 5μm accounted for the most quantitatively after calcination. TG-DSC analysis displayed the sintering temperature of proton conductors was about 1360℃. SEM showed these proton conductors were composed of two particles whose size ranged from 1μm to 10μm. The Dehydrogenation result indicated deydrogenation current getted higher when the temperature of Al melt,water vapor pressure and external voltage getted higher independently. By CaZr0.9In0.1O3-α hydrogen sensor the hydrogen activity was 0.0536 and 0.0445 mlH2/100gAl when the temperature of Al melt was 780℃, PH2O was apart 4122.8Pa and 4366.0Pa. Key words:  BaCe1-xYxO3-α      BaCe0.9Sm0.1O3-α      proton conductor      hydrogen pump      dehydrogenation of Al melt       Received:  12 February 2007      ZTFLH:  O646   Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors WANG Dong FAN Jianhua LIU Chunming WANG Changzhen URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2007/V43/I11/1228 [1]Iwahara H,Esaka T,Uchida H,Maeda N.Solid State Ion- its,1981;3/4:359 [2]Iwahara H,Uchida H,Tanaka S.Solid State lonics,1983; 9/10:1021 [3]Mitsui A,Miyayama M,Yanagida H.Proc 3rd Meeting on Chemical Sensors,Tokyo,Japan:1984 [4]Iwahara H,Uchida H,Ono K,Ogaki K.J Electrochem Soc,1988;135:529 [5]Hibino T,Mizutani K,Yajima T,Iwahara H.Solid State Ionics,1992;57:303 [6]Iwahara H,Esaka T,Uchida H,Yamauchi T,Ogaki K. Solid State Ionics,1986;18/19:1003 [7]Iwahara H,Uchida H,Nagano T,Koide K.Denki Kagaku, 1989;57:992 (岩原弘育，内田裕之，长野贵小，出邦博．电气化学，1989；57：992) [8]Iwahara H,Uchida H,Morimoto K.Denki Kagaku,1990; 58:178 (岩原弘育，内田裕之，森木清幸．电气化学，1990；58：178) [9]Iwahara H.Solid State Ionics,1992;52:99 [10]Iwahara H.Solid State Ionics,1995;77:289 [11]Hibino T,Hashimoto A,Suzuki M,Sano M.J Electrochem Soc,2002;149:A1503 [12]Gokcen N A,Chipman J.Trans AIME,1952;194:171 [13]Zhou G D.Dictionary of Chemistry.Beijing:Chemical Industry Press,2004:670 (周公度．化学辞典．北京：化学工业出版社，2004：670) [14]Yang N R,Yue W H.The Handbook of Inorganic Metal- loid Meterials Atlas.Wuhan:Wuhan University of Tech- nology Press,2000:213 (杨南如，岳文海．无机非金属材料图谱手册．武汉：武汉工业大学出版社，2000：213) [1] Lei XU, Ruipeng GUO, Jie WU, Zhengguan LU, Rui YANG. Progress in Hot Isostatic Pressing Technology ofTitanium Alloy Powder[J]. 金属学报, 2018, 54(11): 1537-1552. [2] LI Ying, DING Yushi, CUI Shaogang, WANG Changzhen. PREPARATION AND ELECTRICAL PROPERTIES OF Sc--DOPED CaZrO3[J]. 金属学报, 2012, 48(5): 575-578. [3] WANG Dong LIU Chunming WANG Changzhen. PREPARATION AND CHARACTERISTICS OF HIGH TEMPERATURE PROTON CONDUCTOR Ba3Ca1.18Nb1.82O9-δ[J]. 金属学报, 2009, 45(3): 345-350. [4] . Preparation Of High Temperature Proton Conductor Tube CaZr0.9In0.1O3-α And Its Properties[J]. 金属学报, 2008, 44(2): 177-182 . [5] ZHENG Minhui; CHEN Xiang (University of Science and Technology Beijing). SrCeO_3 BASED HIGH TEMPERATURE PROTON CONDUCTOR AND HYDROGEN PROBE[J]. 金属学报, 1994, 30(17): 238-242. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed