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Acta Metall Sin  2004, Vol. 40 Issue (1): 27-30     DOI:
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Modeling Of The Liquid--Liquid Phase Transformation Of Immiscible Alloys
ZHAO Jiuzhou; HU Zhuangqi
Institute of Metal Research; The Chinese Academy of Sciences
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ZHAO Jiuzhou; HU Zhuangqi. Modeling Of The Liquid--Liquid Phase Transformation Of Immiscible Alloys. Acta Metall Sin, 2004, 40(1): 27-30 .

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Abstract  A numerical model describing the microstructure evolution under the common action of the nucleation, the diffusional growth, the collisions and coagulations of the minority phase droplets and the spatial separation of the two liquid phases has been developed. The microstructure development in an unidirectionally solidified Al--Pb alloy has been simulated by coupling the calculated temperature and concentration fields with the kinetic equation which controls the microstructure evolution. It is indicated that the liquid--liquid transformation region moves from the bottom to the top of the sample during cooling. The Marangoni migration and the Stokes movement of droplets may cause a decrease of the local number density of droplets and an increase of the local supersaturation. The repeated nucleation of minority phase droplets may, therefore, occur locally.
Key words:  immiscible alloy      liquid--liquid phase transformation      
Received:  12 December 2002     
ZTFLH:  TG113.12  
  TG111.4  

URL: 

https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2004/V40/I1/27

[1] Davis R, Hassen M J. Fluid Mech, 1988; 196:107
[2] Alkemper J, Ratke L. Z Metallkd, 1994; 85:365
[3] Ratke L, Alkemper J. Adv Colloid Interf Sci, 1995; 58: 151
[4] Zhao J Z, Guo J J, Jia J, Li Q C. Trans Nonferr Met Soc Chin, 1995; 5:85(赵九洲,郭景杰,贾均,李庆春.有色金属学报,1995;5:85)
[5] Zhao J Z, Ratke L, Feuerbacher B. Modell Simul Mater Sci Eng, 1998; 6:123
[6] Zhao J Z, Ratke L. Mater Lett, 1999; 38:235
[7] Zhao J Z, Ratke L. Z Metallkd, 1998; 89:241
[8] Zhao J Z, Ratke L. Scr Mater, 1998; 39:181
[9] Zhao J Z, Drees S, Ratke L. Mater Sci Eng, 2000; 282A: 262
[10] Guo J J, LiuY, Jia J, Su Y Q, Ding H S, Zhao J Z, Xue X. Scr Mater, 2001; 45:1197
[11] Guo J J, Liu Y, Jia J, Su Y Q, Ding H S. Acta Metall Sin, 2001; 37:363(郭景杰,刘源,贾均,苏彦庆,丁宏升.金属学报,2001;37:363)
[12] Jia J, Zhao J Z, Guo J J, Liu Y. Immiscible Alloys and Their Manufacturing Technique. Harbin: Harbin Institute of Technology Press, 2002:1(贾均,赵九洲,郭景杰,刘源.难混溶合金及其制备技术.哈尔滨:哈尔滨工业大学出版社,2002:1)
[13] Zhao J Z, Ratke L, Jia J, Li Q C. J Mater Sci Technol, 2002; 18:197
[14] Zhao J Z. PhD Dissertation, Harbin Institute of Technology, Harbin, 1994(赵九洲.哈尔滨工业大学博士学位论文,1994)
[15] Patankar S V. Numerical Heat Transfer and Fluid Flow. New York: McGraw-Hill, 1980:1
[16] Yu Sun-Keun, Sommer F. Z Metallkd, 1996; 87:574
[17] Eustathopoulos N, Chatain D, Vahlas C. Scr Metall, 1984; 18:1
[18] Falk F. In: Ratke L. Immiscible Metals and Organics. Oberursel, Germany: DGM-Informationsgesellschaft, 1993:93
[19] Falk F, Langbein D, Heide W. In: Ratke L ed., Immiscible Metals and Organics. Oberursel, Germany: DGM-Informationsgesellschaft, 1993:111
[20] Ratke L. Diefenbach S. Mater Sci Eng, 1995; R15:263
[21] Prinz B, Romero A. In: Ratke L ed., Immiscible Metals and Organics. Oberursel, Germany: DGM-Informationsgesellschaft, 1993:281!
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