PHASE COMPOSITION STUDY FOR ZIRCONIUM-BASED PSEUDOBINARY ZrM_2(M=Ni,Mn,Cr,V)

Acta Metall Sin

1996, Vol. 32

Issue (7): 779-784 DOI:

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PHASE COMPOSITION STUDY FOR ZIRCONIUM-BASED PSEUDOBINARY ZrM_2(M=Ni,Mn,Cr,V)

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L Guanglie; LIU Shunhong;CHEN Linshen; WU Hongli (Hangzhuo University;Hangzhuo 310028); LEI Yongquan; YU Jinyun; YANG Xiaoguang; WANG Qidong(Zhejiang Universiyy; Hangzhuo 310027)(Manuscript received 1995-11-27). PHASE COMPOSITION STUDY FOR ZIRCONIUM-BASED PSEUDOBINARY ZrM_2(M=Ni,Mn,Cr,V). Acta Metall Sin, 1996, 32(7): 779-784.

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Abstract Phase composition of pseudobinary ZrM_2 alloy (M= Ni_(1.3), Mn_(0.6), Cr_(0.25), V_(0.05)) has been revealed by means of multiphase Rietveld analysis. It is consisted of C14, C15 Laves phase, ZrN, Zr_7M_(10) and Zr_9M_(11) intermediate phase. The abundance order of phases is following. ZrM2(C15)>Zr_7M_(10)> ZrM_2(C14)>Zr_9M_(11)>ZrN. Nonstoichiometry defects existing in A sites of C15 Laves phase were also discovered. The crystal types of Zr_7M_(10) and Zr_9M_(11) are the same with that of Zr_7Ni_(10) and Zr_9Ni_(11) respectively.Correspondent: L Guanglie, Institute of Material Structure, Hangzhuo University, Hangzhuo 310028

Key words: Laves phase hydrogen storage alloy phase composition multiphase Rietveld analysis

Received: 18 July 1996

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