Acta Metall Sin  1994, Vol. 30 Issue (24): 527-531    DOI:

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PREPARATION OF HIGH QUALITY ULTRAFINE ZrO_2 POWDER WITH REVERSED MICELLAR SOLUTION FROM SOLVENT EXTRACTION

YANG Chuanfang; CHEN Jiayong(Institute of Chemical Metallurgy; Chinese Academy of Sciences; Beijing)

YANG Chuanfang; CHEN Jiayong(Institute of Chemical Metallurgy; Chinese Academy of Sciences; Beijing). PREPARATION OF HIGH QUALITY ULTRAFINE ZrO_2 POWDER WITH REVERSED MICELLAR SOLUTION FROM SOLVENT EXTRACTION. Acta Metall Sin, 1994, 30(24): 527-531.

Abstract References Related Articles Recommended Metrics Download:  PDF(321KB)  Export:  BibTeX | EndNote (RIS)       Abstract  A new method for synthesizing ultrafine metal oxide powders was presented in combination with solvent extraction. The extraction system used for Zr in HCl solution was selected based on industrial practice with tri-n-butyl phosphate(TBP) as extractant and kerosene as diluent. Conditions used to obtain reversed micellar solution were experimentally determined, i.e. high aqueous acidity and relatively high metal ion concentration. The micellar solution was then used to react with aqueous ammonia to produce precipitate followed by washing, drying and calcining of the precipitate, monodispersed ZrO_2 powders with an average diameter of 10 nm were obtained. Key words:  ultrafine powder      zirconia      reversed micelle      solvent extraction      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1994/V30/I24/527 1小林启佑,化学总说,1985;48:1852TaniE,YoshimuraM,SomiyaS．JAmCeramSoc,1983;66(1):113SegalD．ChemicalSynthesisofAdvancedCeramicMaterials．Cambridge:CambridgeUniv．Press,19894池本正,水谷惟恭,加藤诚轨,御手洗证明.窑业协会志,1985;93(9):5855DoyleMF,YeW,JMet,1987:39(7):346DemopoulosGP．In:SekineTed,SolventExtraction1990,Elsevier,1992:10997KertesAS．JInorgChem,1960;14:1048BonedC,ClausseM,LagouretteB,PeyrelasseJ,McCleanVER,SheppardRJ．JPhysChem,1980;84:15209Osseo-AsareK．ColloidsSurf,1990;50:37310Osseo-AsareK．AdvColloidInterfaceSci,1991;37:12311YuJiaguo,PanMu,ZhangLianmeng．ChinSciBull,1992;37(5):423 [1] LIAO Jingjing, ZHANG Wei, ZHANG Junsong, WU Jun, YANG Zhongbo, PENG Qian, QIU Shaoyu. Periodic Densification-Transition Behavior of Zr-Sn-Nb-Fe-V Alloys During Uniform Corrosion in Superheated Steam[J]. 金属学报, 2023, 59(2): 289-296. [2] GAO Yunming, HE Lin, QIN Qingwei, LI Guangqiang. ZrO2 Solid Electrolyte Aided Investigation on Electrodeposition in Na3AlF6-SiO2 Melt[J]. 金属学报, 2022, 58(10): 1292-1304. [3] LI Jiguang;SUN Xudong;WANG Yarong;DONG Wenxin;RU Hongqiang;HAO Shiming (School of Materials and Metallurgy; Northeastern University; Shenyang 110006). STUDY OF INITIAL STAGE SINTERING OF NANOCRYSTALLINE α-Al_2O_3 POWDER BY ISOTHERMAL METHOD[J]. 金属学报, 1998, 34(2): 189-194. [4] WANG Liduo;WANG Yinghua;LI Wenzhi; LI Hengde (Tsinghua University; Beijing 100084); OKI Takeo (Naguya University; Japan). REACTION BEHAVIOUR OF ZrO_2/Ti INTERFACE IN JOINTING ZIRCONIA CERAMICS AND STAINLESS STEEL 304 WITH Ti FOIL[J]. 金属学报, 1997, 33(7): 756-762. [5] Li Ying;Wang Xiaotian;Jin zhihao;Shi Guoshung Xi'an Jiaotong University Beijing Measuring and Analysing Center Correspondent Professor; Institute for Strength; of Metals Xi`an Jiaotong University; Xi`an 710049. EFFECT OF SUBZERO TREATMENT ON MICROSTRUCTUE AND MECHANICAL PROPERTIES OF Y_2O_3-ZrO_2CREAMIC[J]. 金属学报, 1992, 28(6): 90-94. [6] HUANG Kelong;SHU Wanyin;DING Dunhuang;LIU Guogen;DONG Ping Central South University of Technology; Changsha. COMPLEX FORMED IN EXTRACTION OF DIVALENT Mn BY ALKYLPHOSPHONIC ACID MONOESTER[J]. 金属学报, 1991, 27(4): 88-92. [7] JIANG Tao;SU Yuanfu East China University of Chemical Technology; Shanghai. EXTRACTION OF Zn AND Cd FROM CHLORIDE SOLUTIONS BY TRI-n-BUTYL PHOSPHATE[J]. 金属学报, 1990, 26(4): 87-92. [8] XU Huibin;TAN Shusong Technische Universitat Berlin. FRG Department of Materials;Central South University of Technology; Changsha 410083. PREPARATION OF ULTRAFINE PARTICLES OF Fe AND ZrO_2 WITH METASTABLE PHASES BY HIGH POWER LASER BEAMS[J]. 金属学报, 1990, 26(2): 152-155. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed