金属学报  1965, Vol. 8 Issue (1): 38-50

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溶体的次正规模型对二元平衡图热力学分析的运用

田德诚;朱锡熊

中国科学院金属研究所;中国科学院金属研究所

APPLICATION OF THE SUB-REGULAR SOLUTION MODEL TO THE THERMODYNAMICAL ANALYSIS OF BlNARY EQUILIBRIUM DIAGRAMS

T'IEN TEH-CHENG;CHU HSI-HSIUNG Institute of Metal Research; Academia Sinica

田德诚;朱锡熊. 溶体的次正规模型对二元平衡图热力学分析的运用[J]. 金属学报, 1965, 8(1): 38-50.
, . APPLICATION OF THE SUB-REGULAR SOLUTION MODEL TO THE THERMODYNAMICAL ANALYSIS OF BlNARY EQUILIBRIUM DIAGRAMS[J]. Acta Metall Sin, 1965, 8(1): 38-50.

摘要 参考文献 相关文章 Metrics 全文: PDF(969 KB)   摘要: 讨论了利用次正规溶体模型对二元平衡图进行热力学分析的一些结果,得出了各种典型复相平衡情况下溶体次正规性的判别式。计算表明,周期表第Ⅲ_B,Ⅳ_B,Ⅴ_B族各元素和Ge形成的溶液可以近似地用次正规模型描述;至少在化合物成分附近,Ga-As系统的溶液近似是正规的,In-Sb系统溶液是次正规的,并求出了它们相应的正规和次正规常数。从平衡图得到的次正规常数可以用来对溶液的热力学性质进行估算。 Abstract：The application of the sub-regular solution model to the thermodynamical analysisof binary equilibrium diagrams has been discussed. A number of criterion-relations ofsub-regularity have been derived for different typical equilibrium cases. Calculationsshow that the solutions formed by the Ⅲ_B, Ⅳ_B, Ⅴ_B elements with Ge can be describedapproximately by the sub-regular solution model; the Ga-As melts in the region close tostoichiometry are nearly regular whereas the In-Sb melts are shown to be sub-regular. The constants of sub-regularity obtained can be used to calculate the thermodynamicquantities of the corresponding solutions. 收稿日期: 1965-01-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 田德诚 朱锡熊 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1965/V8/I1/38 [1] Hildebrand, J. H.: J. Am. Chem. Soc., 1929, 51, 66． 参阅Hildebrand, J. H., Scott, R. L.: The Solubility of Nonelectrolytes, 3rd ed., (Reinhold, 1950) , p. 46． [2] Becker, R.: Z. Metallk., 1937, 29, 245． [3] #12 [4] #12 [5] #12 [6] Hardy, H. K.: Acta Met., 1953, 1, 202． [7] #12 [8] Guggenheim, E. A.: Trans. Faraday Soc., 1937, 33, 151． [9] Lawson, A. W.: Thermodynamics in Physical Metallurgy, (ASM. 1950) , p. 85． [10] Hansen, M., Anderko, K.: Constitution of Binary Alloys, 2nd ed., (McGraw-Hill, 1958) . [11] Kelley, K. K.: Contributions to the Data on Theoretical Metallurgy XIII. High Temperature Heat-Content, Heat-Capacity, and Entropy Data for the Elements and Inorganic Compounds, (U. S. Bureau of Mines, Bull. No. 584, 1960) . [12] Kubaschewski, O., Evans, E. LL.: Metallurgical Thermochemistry, (Pergamon, 1958) , p. 344． [13] Vieland, L. J.: Actd Met., 1963, 11, 137． [14] Liu, T S. (刘天锡), Peretti, E. A.: Trans. Am. Soc. Metals, 1952, 44, 539． [15] #12 [16] Schottky, W. F., Bever, M. B.: Acta Met., 1958, 6, 320． [17] Darken, L. S., Gurry, R. W.: Physical Chemistry of Metals, (Department of Metallurgy Massachusetts Institute Technology, 1953) , p. 235--282． [18] Lumsden, J.: Thermodynamics of Alloys, (Inst. Metals, 1952) , p. 203． [19] Nachtrieb, N. H., Clement, N.: J. Phys. Chem., 1958, 62, 876． No related articles found! Viewed Full text Abstract Cited   Shared      Discussed