金属学报  1965, Vol. 8 Issue (1): 51-58

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铟-锑系统热力学性质的计算

朱锡熊;田德诚

中国科学院金属研究所;中国科学院金属研究所

CALCULATION OF THE THERMODYNAMICAL PROPERTIES OF In-Sb SYSTEM

CHU HSI-HSIUNG;T'IEN TEH-CHENG Institute of Metal Research; Academia Sinica

朱锡熊;田德诚. 铟-锑系统热力学性质的计算[J]. 金属学报, 1965, 8(1): 51-58.
, . CALCULATION OF THE THERMODYNAMICAL PROPERTIES OF In-Sb SYSTEM[J]. Acta Metall Sin, 1965, 8(1): 51-58.

摘要 参考文献 相关文章 Metrics 全文: PDF(548 KB)   摘要: 根据前文中求得的次正规溶体模型运用于同分熔解化合物的关系式,进一步讨论了In-Sb系统的热力学性质。由已经求得的两个次正规常数,计算了InSb化合物的标准形成自由能ΔF_(Insb)~o(T)(以液态组元In和Sb为标准态),并计算了In-Sb平衡图中和InSb化合物处于平衡的液相线,计算结果与实验数据均能良好符合。本文并针算了In-Sb溶液的各热力学函数及组元的活度,和Terpilowski的实验数据作了比较。 Abstract：On the basis of the relations derived in our previous paper on the application of thesub-regular solution model to the thermodynamic analysis of binary phase diagrams, thethermodynamic properties of In-Sb system are discussed. Using the constants of sub-regularity obtained, the standard free energy of formation of In-Sb and the liquidus inequilibrium with the congruent compound have been calculated. The results are in goodagreement with the experimental data. Various thermodynamic properties of the In-Sbmelts have been calculated and compared with the data of Terpilowski. 收稿日期: 1965-01-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 朱锡熊 田德诚 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1965/V8/I1/51 [1] 田德诚、乐锡熊,金属学报,1965． 1,38． [2] Liu, T. S. (刘天锡), Peretti, E. A.: Trans. Am. Soc. Metals, 1952, 44, 539, (参阅文献[4] ). [3] 1949, 17, 204, (参阅文献[4] ). [4] Hansen, M., Anderko, K.: Constitution of Binary Alloys, 2nd ed., (McGraw-Hill, 1958) , p. 858． [5] Schottky, W. F., Bever, M. B.: Acta Met., 1958, 6, 320． [6] Terpilowski, J.: Arch. Hutnictwa, 1959, 4, 369． [7] Bednar, J., Smirous, K.: Czech. J. Phys., 1955, 5, 546． [8] #12 [9] Terpilowski, J., Tzebiatowski, W.: Bull. Acad. Polon. Sci., Ser. Sci. Chim., 1960, 8, 95． [10] Kelley, K. K.: Contributions to the Data on Theoretical Metallurgy XIII. High Temperature Heat-Content, Heat-Capacity, and Entropy Data for the Elements and Inorganic Compounds, (U. S. Bureau of Mines, Bull. No. 584, 1960) , p. 15． [11] #12 No related articles found! Viewed Full text Abstract Cited   Shared      Discussed