金属学报  2004, Vol. 40 Issue (5): 531-536

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热蒸发法制备Mg和Mg-Ni薄膜及其氢化性能

王辉; 欧阳柳章; 曾美琴; 朱敏

华南理工大学机械工程学院; 广州 510640

Hydrogen Storage Properties of Mg and Mg-Ni Films Prepared by Thermal Evaporation

WANG Hui; OUYANG Liuzhang; ZENG Meiqin; ZHU Min

College of Mechanical Engineering; South China University of Technology; Guangzhou 510640

王辉; 欧阳柳章; 曾美琴; 朱敏 . 热蒸发法制备Mg和Mg-Ni薄膜及其氢化性能[J]. 金属学报, 2004, 40(5): 531-536 .
, , , . Hydrogen Storage Properties of Mg and Mg-Ni Films Prepared by Thermal Evaporation[J]. Acta Metall Sin, 2004, 40(5): 531-536 .

摘要 参考文献 相关文章 Metrics 全文: PDF(10662 KB)   摘要: 采用热蒸发法制备了纯Mg膜及Mg78Ni22合金膜, 研究了薄膜的结构及其氢化性能. Mg膜具有典型的柱状晶结构, 择优取向生长趋势明显; Mg78Ni22薄膜由纳米晶Mg2Ni, Mg及少量非晶组成, Mg2Ni相沿着平行于薄膜表面的(001)方向择优生长. 纯Mg膜的吸放氢温度分别为593和653 K, 其吸氢过程遵循形核长大机制. Mg78Ni22薄膜的压力-组成等温曲线存在低压和高压两个平台区, 分别对应Mg和Mg2Ni的氢化反应, 薄膜内Mg的吸放氢温度可分别降至473和503 K, 薄膜的最大吸氢量(质量分数)达到5.7%. Mg的氢化性能改善与薄膜中纳米晶Mg2Ni和非晶相起到的催化作用有关. 关键词 ： 储氢合金,  热蒸发,  Mg膜      Abstract：Microstructure and hydrogenation properties of Mg and Mg-Ni films fabricated by thermal evaporation method were investigated. The as deposited Mg film exhibits a preferred orientation and a typical columnar crystalline structure. The as deposited Mg-Ni film with a composition of Mg78Ni22 is composed of nanocrystalline Mg2Ni, Mg and a small amount of amorphous phase. Besides, the Mg2Ni crystallites grow with their (001) crystalline plane parallel to the substrate surface. The hydrogen absorption and desorption temperatures of pure Mg film are 593 K and 653 K, respectively and its hydriding reaction follows a nucleation and growth mechanism. Pressure-composition isotherms of Mg78Ni22 film show that its maximum hydrogen absorption capacity (mass fraction) reaches to 5.7\% and there are the lower and higher pressure plateaus corresponding to the hydriding reactions of Mg and Mg2Ni, respectively. The hydriding/dehydriding temperatures of Mg in Mg78Ni22 film decreased down to 473 K and 503 K, respectively. The improvement on the hydrogenation properties of Mg is related to the catalytic role of nanocrystalline Mg2Ni and amorphous phase. Key words： hydrogen storage alloy    thermal evaporation    Mg film 收稿日期: 2003-05-09      ZTFLH:  TG139.7   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王辉 欧阳柳章 曾美琴 朱敏 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2004/V40/I5/531 [1] Zaluska A, Zaluski L, Strom-Olsen J O. Appl Phys, 2001; 72A: 157 [2] Orimo S, Fujii H. Appl Phys, 2001; 72A: 167 [3] Huot J, Liang G, Schulz R. Appl Phys, 2001; 72A: 187 [4] Chiaki I, Ryuji S, Keisuke M, Shinji N, Hiroshi I. Electrochem Acta, 2001; 46:2781 [5] Han S C, Lee P S, Lee J Y, Zuttel A, Schlabch L. J Alloys Compd, 2000; 306:219 [6] Goo H N, Jeong W T, Lee K S. J Power Source, 2000; 87: 118 [7] Liu F J, Suda S. J Alloys Compd, 1996; 232:212 [8] Wang C Y, Yao P, Bradhurst D H. J Alloys Compd, 1999; 285:267 [9] Luo J L, Cui N. J Alloys Compd, 1998; 264:299 [10] Zaluska A, Zaiuski L. J Alloys Compd, 1999; 288:217 [11] Liang G, Huot J, Boily S, van Neste A, Schulz R. J Alloys Compd, 1999; 292:247 [12] Song M Y, Bobet J-L, Darriet B. J Alloys Compd, 2002; 340:256 [13] Zhu W H, Zhu M, Luo K C, Che X Z. Acta Metall Sin, 1999: 35:541(朱文辉,朱敏,罗堪昌,车晓舟.金属学报,1999;35:541) [14] Terzieva M, Khrussanova M, Peshev P. J Alloys Compd, 1998; 267: 235 [15] Zhu M, Gao Y, Che X Z, Yang Y Q, Chang C Y. J Atloys Compd, 2001; 17:708 [16] Wang Z M, Peng C H, Ouyang L Z, Li Z X, Zhu M. Acta Metall Sin, 2002; 38:189(王仲民,彭成红,欧阳柳章,李祖鑫,朱敏.金属学报,2002;38:189) [17] Zaluski L, Zaluska A. J Alloys Compd, 1995; 217:245 [18] Chiaki I. J Alloys Compd, 1999; 285:246 [19] Lei Y Q, Wu Y M, Yang Q M, Wu J, Wang Q D. Z Phys Chem, 1994; 183:379 [20] Zhu M, Gao Y, Che X Z, Yang Y Q, Chang C Y. J Alloys Compd, 2002; 330-332:708 [21] Higuchi K, Yamamoto K, Kajioka H, Toiyama K, Honda M, Orimo S, Fujii H. J Alloys Compd, 2002; 330-332:526 [22] Huot J, Liang G, Boily S, van Neste A. Schulz R. J Alloys Compd, 1999; 293-295:495 [23] Fujii H, Orimo S, Ikeda K. J Alloys Compd, 1997; 253-254:80 [24] Orimo S, Fujii H. Appl Phys, 2001; 72A: 167 [25] Zaluska A, Zaiuski L, Strom-Olsen J O. J Alloys Compd, 1999: 253-254:70 [26] Zaluska A, Zaiuski L. J Alloys Compd, 1999; 288:217 [1] 朱敏, 欧阳柳章. 镁基储氢合金动力学调控及电化学性能[J]. 金属学报, 2021, 57(11): 1416-1428. [2] 赵炳建 鲁雄刚 李重河 钟庆东. 固体透氧膜法直接还原NiO-CeO2制备CeNi5合金[J]. 金属学报, 2009, 45(10): 1255-1260. [3] 菅晓玲; 黄存可; 郑定山; 韦文楼; 郭进 . ZrMn2合金及其氢化物的电子结构与成键特性的第一原理研究[J]. 金属学报, 2006, 42(2): 123-128 . [4] 王仲民; 彭成红; 欧阳柳章; 李祖鑫; 朱敏 . 纳米化对Mg2Ni/MmNi5-x(CoAlMn)x复合储氢合金电极特性的影响[J]. 金属学报, 2002, 38(2): 189-192 . [5] 朱文辉; 朱敏; 罗堪昌 . 高能球磨在MmNi5-x（Co,Al,Mn）x／Mg体系中诱发的固态反应及纳米相复合储氢合金的形成[J]. 金属学报, 1999, 35(5): 541-545 . [6] 吕光烈;刘顺洪;陈林深;吴红丽;雷永泉;于进云;杨晓光;王启东. 多相Rietveld分析法研究锆基伪二元储氢合金ZrM_2(M=Ni,Mn,Cr,V)的相结构[J]. 金属学报, 1996, 32(7): 779-784. Viewed Full text Abstract Cited   Shared      Discussed