金属学报  2004, Vol. 40 Issue (2): 173-178

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六方BN微颗粒表面化学镀Ni及动力学模型

李 钒;张登君;李报厚;罗世民

中国科学院过程工程研究所; 北京 100080

Chemical Plating Nickel on the Surface of Hexagonal Boron Nitride Micro-Particles and Its Kinetic Model

LI Fan; ZHANG Dengjun; LI Baohou; LUO Shimin

Institute of Process Engineering; The Chinese Academy of Sciences; Beijing 100080

李钒; 张登君; 李报厚; 罗世民 . 六方BN微颗粒表面化学镀Ni及动力学模型[J]. 金属学报, 2004, 40(2): 173-178 .
, , , . Chemical Plating Nickel on the Surface of Hexagonal Boron Nitride Micro-Particles and Its Kinetic Model[J]. Acta Metall Sin, 2004, 40(2): 173-178 .

摘要 参考文献 相关文章 Metrics 全文: PDF(5624 KB)   摘要: 以肼为还原剂在平均粒径为104 μm的BN颗粒表面进行了化学镀Ni, 提出了近球 形颗粒表面“扩展-缩小自催化沉积”模型, 较好地解释沉积量随时间的变 化规律. 依此模型推导了化学镀Ni沉积过程的动力学表达式. 观测了不同沉积 时间表面沉积Ni颗粒的SEM形貌变化规律, 证实了动力学模型的正确性. 关键词 ： 动力学模型,  化学镀Ni,  BN微颗粒      Abstract：The kinetic investigation of hydrazine reduction chemical plating nickel on the surface of hexagonal boron nitride with the average diameter 104 μm particles has been carried out. A model, extension-contraction autocatalysis reaction interface, was created which can demonstrate the curves of deposited nickel with time. Based on the model a kinetic expression for the chemical planting process has been derived, and with the expression the experimental kinetic curves could be fitted, experiments verified the model being suitable. SEM morphologies and EDS analysis of the deposited nickel on the BN surface for different times also supported the model. Key words： kinetic model    chemical plating nickel    boron nitride micro-particle 收稿日期: 2003-02-19      ZTFLH:  TQ153.12   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 李钒 张登君 李报厚 罗世民 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2004/V40/I2/173 [1] Li F, Zhang D J, Li B H, Luo S M. Chin J Proc Eng, 2002; 2: 425(李钒,张登君,李报厚,罗世民.过程工程学报,2002;2:425) [2] Levy D J. Electrochem Technol, 1963; 1: 38 [3] Liang H Z, Sun J C, Huang J Z, Li J Y. Eng Chem Metall, 1984: 5: 18(梁焕珍,孙京成,黄建忠,李晋尧.化工冶金,1984;5:18) [4] Chai L Y. Zhong H Y, Min X B. J Cent South Univ Technol (Nat Sci), 1997; 28: 470(柴立元,钟海云,闵小波.中南工业大学学报(自然科学版),1997;28:470) [5] Shao Z C, Tian Y W, Zhai Y C, Li B S. J Inorg Mater, 1999: 14: 397(邵忠财,田彦文,翟玉春,李保山.无机材料学报,1999;14:397) [6] Egorova L G, Sakhieva A S, Bassele A B, Vreyter A L, Lozhnikova O P. Prot Met, 1975; 11: 505 (1975; 11: 505) [7] Jiang X X, Shen W. The Fundamental and Practice of Electroless Plating. Beijing: National Defence Industry Press, 2000: 23(姜晓霞,沈伟.化学镀理论与实践.北京:国防工业出版社,2000:23) [8] Chen J Y, Yang S Z, Ke J J, Mao M H. Research and Development of Hydrometallurgy. Beijing: Metallurgical Industry Press, 1998: 444(陈家镛,杨守志,柯家骏,毛铭华.湿法冶金的研究与发展.北京:冶金工业出版社,1998:444) [9] Zhou G D, Duan L Y. The Fundamental of Structural Chemistry. 2nd ed., Beijing: Peking University Press, 1995: 473(周公度,段连运.结构化学基础.第2版,北京:北京大学出版社,1995:473) [10] L M X, Huang C B, Song Y J. Chemical Power Source. Tianjin: Tianjin University Press. 1992: 127(吕鸣祥,黄长保,宋玉瑾.化学电源.天津:天津大学出版社,1992:127) [11] Zhang J Y, Zhou T P, Ma Y J, Fang X L, Lei J B. Steel Res, 1997; 68: 3 [12] Qu J X, Wang H H. Handbook of Surface Engineering. Beijing: Chemical Industry Press, 1998: 179(曲敬信,汪鸿宏.表面工程手册.北京:化学工业出版社,1998:179) [1] 许坤, 王海川, 孔辉, 吴朝阳, 张战. 一种新分组团簇动力学模型模拟铝合金中的Al3Sc析出[J]. 金属学报, 2021, 57(6): 822-830. [2] 黄明亮，周少明，陈雷达，张志杰. Ni-P消耗对焊点电迁移失效机理的影响[J]. 金属学报, 2013, 49(1): 81-86. [3] 刘娟 李居强 崔振山 阮立群. 新的单参数动态再结晶动力学建模及晶粒尺寸预测[J]. 金属学报, 2012, 48(12): 1510-1519. [4] 李均明 薛晓楠 蔡辉 蒋百灵. 多孔结构MgO表面化学镀Ni层的制备与表征[J]. 金属学报, 2010, 46(9): 1103-1108. [5] 余勇 潘晓霞. Frank-Read位错源的细观级模拟[J]. 金属学报, 2009, 45(11): 1309-1313. [6] 陈卫武;邹宗树;王天明. CVD法合成SiC晶须的实验研究[J]. 金属学报, 1997, 33(6): 643-649. Viewed Full text Abstract Cited   Shared      Discussed