金属学报  2004, Vol. 40 Issue (2): 168-172

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水杨酸钠对电镀锌钢板上电聚合吡咯的作用

印仁和; 赵亚萍; 戴迎春; 张新胜

上海大学理学院化学系; 上海 200436;华东理工大学国家重点化学工程联合实验室; 上海 200237

Effect of Sodium Salicylate on Electropolymerization of Pyrrole on Zincated Steel

YIN Renhe; ZHAO Yaping;DAI Yingchun; ZHANG Xinsheng

Department of Chemistry; College of Science; Shanghai University; Shanghai 200436;National United Chemical Engineering Laboratory; East China University of Science and Technology; Shanghai 200237

印仁和; 赵亚萍; 戴迎春; 张新胜 . 水杨酸钠对电镀锌钢板上电聚合吡咯的作用[J]. 金属学报, 2004, 40(2): 168-172 .
, , , . Effect of Sodium Salicylate on Electropolymerization of Pyrrole on Zincated Steel[J]. Acta Metall Sin, 2004, 40(2): 168-172 .

摘要 参考文献 相关文章 Metrics 全文: PDF(3961 KB)   摘要: 利用循环伏安法等方法分析了水杨酸钠对电镀锌钢板上电聚合吡咯的作用. 结果表明, 水杨酸钠作为支持电解质, 对锌镀层表面起钝化作用, 抑制了Zn的溶解, 有利于吡咯的电聚合, 可在电镀锌钢板表面形成均匀致密的聚吡咯膜. 关键词 ： 水杨酸钠,  电聚合,  循环伏安法     Abstract：The role of sodium salicylate in electropolymerization of pyrrole on zincated steel was studied by cyclic voltammetry. The results show that as supporting electrolyte, the sodium salicylate inhibits the zinc dissolution and favours the electropolymerization of pyrrole by passivating the substrate. Consequently, an uniform and compact polypyrrole film may be formed on zincated steel. Key words： sodium salicylate    electropolymerization    cyclic voltammetry 收稿日期: 2003-01-28      ZTFLH:  TG174.2   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 印仁和 赵亚萍 戴迎春 张新胜 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2004/V40/I2/168 [1] Ferreira C A, Aeiyach S, Aaron J J, Lacaze P C. Electrochim Acta, 1996; 41: 1801 [2] Hlser P, Beck F. J Appl Electrochem, 1990; 20: 596 [3] Warren L F, Anderson D P. J Electrochem Soc, 1987; 134: 101 [4] Hermelin E, Petitjean J, Aeiyach S, Lacroix J C, Lacaze P C. J Appl Electrochem, 2001; 31: 905 [5] Gu SY. Mater Protect, 2000; 33(4) : 41(顾书英.材料保护,2000;33(4) :41) [6] Zheng Y B, Zhang S J, Ke Y C, Wu Z W. J Funct Polym, 1996; 9: 613(郑玉斌,张善举,柯杨船,吴忠文.功能高分子学报,1996:9:613) [7] Li C G, Cui G, Yin S L, Jiang G Z. Chin J Anal Chem, 1994; 22: 922(李春光,崔刚,尹寿立,姜光哲.分析化学,1994;22:922) [8] Xiao S T, Xu J, Huang Y, Li L. J South Chin Univ Technol (Nat Sci), 1998; 26(1) : 95(肖诗铁,徐俊,黄怡,李炼.华南理工大学学报(自然科学版),1998;26(1) :95) [9] Wei P H, Liang W, Wang Y J. J Shandong Educ Coll, 2002; 17(1) : 84(魏培海,梁玮,王娅娟.山东教育学院学报,2002;17(1) :84) [10] Petitjean J, Aeiyach S, Lacroix J C, Lacaze P C. J Electroanal Chem, 1999; 478: 92 [11] Liu Y H. Electrochemical Techniques. Beijing: Beijing Aeronautics College Press, 1987: 136(刘永辉.电化学测试技术.北京:北京航空学院出版社,1987:136) [12] Silverstein R M, Webster F X. Spectrometric Identification of Organic Compounds: 6th ed., New York: John Wiley & Sons, 1998 [13] Zhou M, Heinze J. Electrochim Acta, 1999; 44: 1733 [14] Gilani T H, Ishiguro T. Synth Met, 1997; 84: 845 [15] Garcia B, Blanger D. Synth Met, 1998; 98: 135 [1] 杨玉林, 穆张岩, 范铮, 淡振华, 王莹, 常辉. 电化学脱合金制备纳米多孔Ag及其甲醛检测性能[J]. 金属学报, 2019, 55(10): 1302-1310. [2] 王旭; 翟玉春; 谢宏伟 . 熔盐电解法制备CaB6及其表征[J]. 金属学报, 2008, 44(10): 1243-1246 . [3] 印仁和; 姬学彬; 王慧娟; 张磊; 石新红; 钱余海; 张新胜 . 钢板电镀锌表面耐蚀性聚苯胺膜的制备及辐射改性[J]. 金属学报, 2007, 43(3): 273-280 . [4] 印仁和; 董晓明; 王慧娟; 戴迎春; 张新胜; 钱余海 . 电镀锌钢板上2--Vpy阴极电聚合及其腐蚀行为的研究[J]. 金属学报, 2005, 41(10): 1111-1115 . [5] 杜森林;苏明忠. 氯化物熔盐中Nd~(3+)在液体Ga电极上还原的电化学行为[J]. 金属学报, 1991, 27(3): 111-115. Viewed Full text Abstract Cited   Shared      Discussed