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金属学报  1987, Vol. 23 Issue (4): 357-362    
  论文 本期目录 | 过刊浏览 |
理论计算和实验测定相结合构筑熔盐相图
乔芝郁;段淑贞;桂玮珍;孙民生
北京钢铁学院;北京钢铁学院;北京钢铁学院;北京钢铁学院
CONSTRUCTION OF MOLTEN SALT PHASE DIAGRAMS BY COMBINATION OF CALCULATION WITH MEASUREMENT
by QIAO Zhiyu; DUAN Shuzhen; GUI Weizhen; SUN Minsheng (Beijing University of Iron and Steel Technology) (Manuscript received 31 March; 1986; revised manuscript 24 November; 1986)
引用本文:

乔芝郁;段淑贞;桂玮珍;孙民生. 理论计算和实验测定相结合构筑熔盐相图[J]. 金属学报, 1987, 23(4): 357-362.
, , , . CONSTRUCTION OF MOLTEN SALT PHASE DIAGRAMS BY COMBINATION OF CALCULATION WITH MEASUREMENT[J]. Acta Metall Sin, 1987, 23(4): 357-362.

全文: PDF(475 KB)  
摘要: 本文阐述了相图计算的基本原理和确定体系中各相的全摩尔和偏摩尔过剩自由能的方法,特别是由二元系性质预示三元系性质的几何模型.在指出相图计算的意义和局限性的同时,阐明了理论计算和实验测定相结合是构筑熔盐相图的最佳方法及该方法的主要步骤.
Abstract:The principle and mathods of calculation of phase diagram, especially the geometric models for determination of excess molar Gibbs energy and excess partial molar Gibbs energy in all phases have been reviewed. Considering the significance and the limitation of calculation of phase diagram, it is pointed out that the combination of calculation with measurement is the best method for construction of molten salt phase diagrams. The procedure of this method have also been described.
收稿日期: 1987-04-18     
基金资助:国家自然科学基金资助课题
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