金属学报  2011, Vol. 47 Issue (2): 203-208    DOI: 10.3724/SP.J.1037.2010.00298

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(Au, Ag, Cu)/SiO2二元金属单分散复合薄膜非线性光吸收性的Mie理论模拟

严丽平, 张波萍, 王士京, 赵翠华, 李顺

北京科技大学材料科学与工程学院, 北京 100083

SIMULATION ON NONLINEAR OPTICAL ABSORPTION OF BINARY METALS DISPERSED (Au, Ag, Cu)/SiO2 NANO-COMPOSITE FILMS BY MODIFIED MIE THEORY

YAN Liping, ZHANG Boping, WANG Shijing, ZHAO Cuihua, LI Shun

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083

严丽平 张波萍 王士京 赵翠华 李顺. (Au, Ag, Cu)/SiO₂二元金属单分散复合薄膜非线性光吸收性的Mie理论模拟[J]. 金属学报, 2011, 47(2): 203-208.
, , , , . SIMULATION ON NONLINEAR OPTICAL ABSORPTION OF BINARY METALS DISPERSED (Au, Ag, Cu)/SiO₂ NANO-COMPOSITE FILMS BY MODIFIED MIE THEORY[J]. Acta Metall Sin, 2011, 47(2): 203-208.

摘要 参考文献 相关文章 Metrics 全文: PDF(717 KB)   摘要: 采用修正的Mie理论模拟计算了(Ag, Cu)/SiO2, (Au, Cu)/SiO2和(Ag, Au)/SiO2二元单质金属纳米颗粒分散体系的理论吸收光谱. 研究发现, 二元金属纳米颗粒分别以单质金属形式存在时, 吸收光谱分别在2个波段处出现表面等离子共振吸收峰, 二元金属的相对含量影响吸收峰的峰强, 与峰位无关. 理论模拟吸收光谱与前人实验结果符合良好. 关键词 ： Mie理论,  (Au, Ag, Cu)/SiO2复合薄膜,  非线性光吸收     Abstract：Due to the surface plasmon resonance (SPR) and enhanced local field effect of metal particles, nano-composite films exhibit a variety of properties, such as large third order nonlinear susceptibility, superfast response time and absorption peaks in the optical spectra at a special wavelength. Therefore they are attractive candidates for optical communication, such as information storage and optical device. In recent years, the metal nanoparticle nonlinear optical composite films have been developed rapidly, expanded from single metal nano particle dispersion system to the dual metal nano particle dispersion system. However, theoretical study on the nonlinear optical absorption of the dual metal nano particle dispersion system is quite rare. In this study, the optical absorption spectra of the (Ag, Cu)/SiO2, (Au, Cu)/SiO2 and (Ag, Au)/SiO2 binary metals dispersed nano-composite films were simulated by modified Mie theory. When the metal particles with a low full factor are smaller than the incident wavelength in diameters, the optical spectra of (Ag, Cu)/SiO2, (Au, Cu)/SiO2 and (Ag, Au)/SiO2 composite films in which the nanoparticles solely dispersed in each metal state, can be calculated and analyzed based on the modified Mie theory using the optical parameters of the component. Two SPR absorption peaks appear in the corresponding wavelength of the single metal dispersed nano-composite films. The intensities of SPR absorption peaks depend strongly on the relative content of binary metals, while their peak positions are constant regardless of the content. The calculated optical absorption spectra by proposed method in this study are in good agreement with the reported experiment results. It suggests that the linear superposition method is feasible to calculate the absorption spectra of other separated binary and/or multiplex metals dispersed nano--composite films. Key words： Mie theory    (Au, Ag, Cu)/SiO2 nano-composite film    nonlinear optical absorption spectra 收稿日期: 2010-06-24      ZTFLH:  TB3   基金资助: 国家重点基础研究发展计划项目2007CB613301和国家自然科学基金项目50972012资助 作者简介: 严丽平, 女, 1986年生, 硕士生 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 严丽平 张波萍 王士京 赵翠华 李顺 44.8K 链接本文: https://www.ams.org.cn/CN/10.3724/SP.J.1037.2010.00298      或      https://www.ams.org.cn/CN/Y2011/V47/I2/203 [1] Ni X Y, Lu J X, Wei J D. Acta Opt Sin, 2004; 24: 433 (倪星元, 吕俊霞, 魏建东. 光学学报, 2004; 24: 433) [2] Li Y, Sun X W, Wang J. Acta Opt Sin, 2005; 25: 77 (李 燕, 孙小伟, 王 建. 光学学报, 2005; 25: 77) [3] Wang W T, Yang G, Chen Z H. J Appl Phys, 2002; 92: 7242 [4] Yu B L, Zhu C S, Gan F X. Acta Phys Sin, 1997; 46: 2394 (于保龙, 朱从善, 干福熙. 物理学报, 1997; 46: 2394) [5] Bohren C F. Absorption and Scattering of Light by Small Particles. New York: Wiley, 1983: 130 [6] Huang W Y, Qian W, El–Sayed M A. Nano Lett, 2004; 4: 1741 [7] Feldheim D L, Colby A F. Metal Nanoparticles: Synthesis, Characterization and Applications. New York: Marcel Dekker, 2002: 89 [8] Gao L Z, Zhang X T, Dai S X. Acta Phys–Chim Sin, 2004; 20: 647 (高丽珍, 张兴堂, 戴树玺. 物理化学学报, 2004; 20: 647) [9] Liu L, Su X R. Chin Phys, 2008; 17B: 2170 [10] Zhao C H, Zhang B P, Shang P P. Chin Phys, 2009; 18B: 5539 [11] Yang P F, Cu Y, Gong Q H. Chin Phys, 2008; 17B: 3880 [12] Yang G, Chen Z |. Acta Phys Sin, 2006; 55: 4342 (杨 光, 陈正豪. 物理学报, 2006; 55: 4342) [13] Shi H Z, Zhang L, Cai W P. J Appl Phys, 2000; 87: 1572 [14] Sun X F, Wei C P, Li Q Y. Acta Phys Sin, 2009; 58: 5816 (孙小飞, 魏长平, 李启源. 物理学报, 2009; 58: 5816) [15] Lei D Y, Li J, Ong H C. Appl Phys Lett, 2007; 91: 021112 [16] De G, Tapfer L, Catalano M. Appl Phys Lett, 1996; 68: 3820 [17] Kreibig U, Vollmer M. Optical Properties of Metal Clusters. Berlin: Springer, 1995: 379 [18] Arnold G W, Bordes J A. J Appl Phys, 1977; 48: 1488 [19] Halperin W P. Rev Mod Phys, 1986; 58: 533 [20] Liao H B, Wen W J, Wong G K. J Appl Phys, 2003; 93: 4485 [21] Tanahashi I, Manabe Y, Tohda T. J Appl Phys, 1996; 79: 1244 [22] Babapour A, Akhavan O, Moshfegh A Z. Thin Solid Films, 2006; 515: 77 [23] Beckers L, Schubert J, Zander W. J Appl Phys, 1998; 83: 3305 [24] Palik E D. Handbook of Optical Constants of Solids. San Diego: Academic Press, 1985: 735 No related articles found! Viewed Full text Abstract Cited   Shared      Discussed