本文研究了两种Ti/Al比对新型Ni-Fe-Cr基合金GH984G在长达上万小时高温时效过程中γ′沉淀相的粗化行为及其力学性能的影响规律. 结果表明:随时效温度从700℃升高至800℃,球形γ′沉淀相的粗化速率明显增大. 在700℃和750℃长期时效过程中,高Ti/Al比和低Ti/Al比合金γ′沉淀相的粗化行为均符合Lifshitz-Slyozof-Wagner (LSW) 理论,受扩散过程控制,高Ti/Al比合金中γ′沉淀相的粗化速率较高. 然而,800℃长期时效过程中,两种Ti/Al比合金γ′沉淀相的粗化行为偏离LSW理论,此外,时效时间小于3000h时,高Ti/Al合金的γ′沉淀相长大较快,进一步延长时效时间,低Ti/Al比合金的γ′沉淀相长大速率较快. Ti/Al比对合金标准热处理态和700~800℃一万小时时效后合金的700℃拉伸性能无明显影响. 通过选取合适的Ti/Al比,可以控制γ′沉淀相的粗化行为,增强合金组织稳定性.
In this research, the coarsening behavior of γ′ precipitates and the effects of Ti/Al ratios to tensile properties after long-term aging in GH984G were investigated. It was suggested that the coarsening of sphere γ′ precipitates growed faster with the aging temperature increased from 700℃ to 800℃. The growth kinetics of the γ′ precipitates were explained by Lifshitz-Slyozov-Wagner’s theory of element diffusion controlled growth at 700℃ and 750℃ during long-term aging. However, the coarsening of γ′ precipitates at 800℃ was contrary to Lifshitz-Slyozov-Wagner’s theory. The γ′ precipitates with high Ti/Al growed fast as the aging time less than 3000h, whereas it slowed down as aging time prolonged. Moreover, the coarsening of γ′ precipitates was fast at 800℃, whereas it slowed down as the aging temperature decreased to 700℃. Ti/Al had no effect on the alloy of standard heat treatment and 700 ℃ tensile properties after long time aging. Therefore, the γ′ precipitates of GH984G alloy possessed excellent stability of microstructure at 700℃, and it could control the γ′ precipitates growth further by adjusting Ti/Al ratio.
国家高技术发展计划项目;国家自然科学基金重点项目;国家能源局项目;中国科学院-四川省成果转化项目
谭梅林 王常帅 郭永安 郭建亭 周兰章. Ti/Al比对GH984G合金长期时效过程中γ′沉淀相粗化行为及拉伸性能的影响[J]. 金属学报, .
https://www.ams.org.cn/CN/Y0/V0/I0/0
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