Prediction of the primary intermetallic compound formed in Fe(Ni)-Sn nanoparticles system
Dong Xing-Long;Jun-Peng Lei
大连理工大学
Cite this article:
Dong Xing-Long; Jun-Peng Lei. Prediction of the primary intermetallic compound formed in Fe(Ni)-Sn nanoparticles system. Acta Metall Sin, 2008, 44(8): 922-926 .
Abstract Based on Miedema semi-empirical model and an empirical specific heat equation, the effective heat of formation and its temperature dependence were calculated for Fe-Sn and Ni-Sn systems. Fe-Sn and Ni-Sn nanoparticles were prepared by an arc discharge method and the formed phases were experimentally determined by X-ray diffraction (XRD). Theoretically predicted primary intermetallic compounds were FeSn2 in Fe-Sn system and Ni3Sn4 in Ni-Sn system, which was well consistent with the experimental results of nanoparticles.
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