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INTERACTION BETWEEN Pb AND C, Pb AND Ce IN Fe-C-Pb, Fe-C_(sat)-Pb-Ce LIQUID SOLUTIONS |
WANG Zhengyue;DU Ting;WANG Longmei Central Iron and Steel Research Institute; Ministry of Metallurgical Industry; Beijing |
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Cite this article:
WANG Zhengyue;DU Ting;WANG Longmei Central Iron and Steel Research Institute; Ministry of Metallurgical Industry; Beijing. INTERACTION BETWEEN Pb AND C, Pb AND Ce IN Fe-C-Pb, Fe-C_(sat)-Pb-Ce LIQUID SOLUTIONS. Acta Metall Sin, 1988, 24(3): 236-241.
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Abstract The thermodynamic properties of Fe-C-Pb liquid solution in the tem-perature range 1300--1400℃ have been studied using the equilibrium method betweenPb vapour and liquid Fe in sealed Mo reaction chamber. The temperature depend-ence of the first and second order interaction coefficients between C and Pb areobtained as follows: e_(Pb)~C=9205(1/T)-4.578, γ_(Pb)~C=-1047(1/T)+0.512. The thermody-namic preperties of Fe-C_(sat)-Pb-Ce liquid solution at 1300℃ have been determinedusing the equilibrium method between vapour and liquid in a graphite cruciblesealed in a vacuum quartz tube. The interaction coefficients between Ce and Pb arederived to be: e_(Pb)~(Ce)=-2. 11, e_(Ce)~(Pb)=-1.43.
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Received: 18 March 1988
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