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Acta Metall Sin  1989, Vol. 25 Issue (5): 79-84    DOI:
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SELF-REACTION COEFFICIENTS OF Ca AND Mg IN LIQUID Sn
LIU Huanming;YANG Zupan;TIAN Yanwen The Steel Works No.2; Benxi Iron and Steel Company Northeast University of Technology; Shenyang LIU Huanming; assistant engineer; the Laboratory of Steel Works No.2; Benxi Iron and Steel Company; Benxi; Ltaoning
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LIU Huanming;YANG Zupan;TIAN Yanwen The Steel Works No.2; Benxi Iron and Steel Company Northeast University of Technology; Shenyang LIU Huanming; assistant engineer; the Laboratory of Steel Works No.2; Benxi Iron and Steel Company; Benxi; Ltaoning. SELF-REACTION COEFFICIENTS OF Ca AND Mg IN LIQUID Sn. Acta Metall Sin, 1989, 25(5): 79-84.

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Abstract  The interaction parameters of Ca, Ti and Mg in the Sn-based dilutesolution have been determined at 1500℃. Experimental measurements were taken byequilibrating the systems composed of the same component slags and various compo-nents Sn-based alloys with metallic Sn as flux and graphite as reducing agent un-der Ar atmosphere mixed with different portions of CO. It was found that a con-siderable error would be ommitted owing to neglect of the parameters ε_(Ca)~(Ca), ε_(Mg)~(Mg) andε_(Tl)~(Tl) in the Sn melts when the activities of the components CaO, MgO and TiO_2 inthe slags were estimated by this method.
Key words:  Sn-based dilute solution      free enthalpy of solvation      interaction parameter      slag-metal equilibrium method     
Received:  18 May 1989     
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