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Acta Metall Sin  1990, Vol. 26 Issue (1): 113-119    DOI:
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KINETIC STUDY OF DESULPHURIZATION ALONG METAL-SLAG INTERFACE
JIANG Guochang;XU Kuangdi;DENG Jianxiong Shanghai University of Technology GUO Zhancheng; GUAN Yulong University of Science and Technology Beijing Institute of Metallurgy and Materials;Shanghai University of Technology; Shanghai 200072
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JIANG Guochang;XU Kuangdi;DENG Jianxiong Shanghai University of Technology GUO Zhancheng; GUAN Yulong University of Science and Technology Beijing Institute of Metallurgy and Materials;Shanghai University of Technology; Shanghai 200072. KINETIC STUDY OF DESULPHURIZATION ALONG METAL-SLAG INTERFACE. Acta Metall Sin, 1990, 26(1): 113-119.

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Abstract  An electrochemical model, directly deduced from the principle of elec-trochemistry, together with the calculational method for initial oxygen potentialalong the metal-slag interface may be available to quantitatively describe the plotof %S vs time. It was found that during desulphurization both the distribution con-stant of S along metal-slag interface, L_S~*, and distribation index inside the bulk,L'_S, vary with the descending of oxygen potential along metal-slag interface. Butthe plot of L_S~* vs time is quite different from L'_S vs time, being of parabola or hy-perhola type respectively. The variation of the driving force parameter vs time,obtained either calculated or experimental, plotted as a camel hump.
Key words:  desulphurization      metal-slag interface      electrochemical model     
Received:  18 January 1990     
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