Acta Metall Sin  1991, Vol. 27 Issue (2): 83-88    DOI:

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SYNERGISTIC AND ANTAGONISTIC EFFECTS OF Zn(Ⅱ) EXTRACTION WITHHEH/EHP AND PRIMARY AMINE N_(1923)

HAN Shumin;MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica

HAN Shumin;MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica. SYNERGISTIC AND ANTAGONISTIC EFFECTS OF Zn(Ⅱ) EXTRACTION WITHHEH/EHP AND PRIMARY AMINE N_(1923). Acta Metall Sin, 1991, 27(2): 83-88.

Abstract References Related Articles Recommended Metrics Download:  PDF(469KB)  Export:  BibTeX | EndNote (RIS)       Abstract  The extraction of Zn(Ⅱ) from hydrochloride medium with 2-ethylhe-xylphosphonic acid mono-2-ethylhexyl ester (HRH/EHP, HA) and hydrochloridesalt of primary amine N_(1923) (RNH_3Cl) in n-heptane has been investigated. A syn-ergistic effect and antagonistic effect were found to be present in the system. ltwas ascertained that the interaction between HA and RNH_3Cl during extraction,HA_(0)+RNH_3Cl_(0)?RNH_3A_(0)+H~(+)+Cl~(-), seriously affected the extraction of Zn(Ⅱ)and that the synergistic or antogonistic extraction of Zn(Ⅱ) could be obtained inthe presence of excess RNH_3Cl over HA or excess HA over RNH_3Cl. Key words:  HEH/EHP      primary amine      Zn(Ⅱ)      synergistic extraction      antagonistic effect      Received:  18 February 1991      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1991/V27/I2/83 1 于淑秋.稀有金属,1989;13:289,290 2 韩树民,李德谦.应用化学,待发表 3 Inoue Y, Tochiyama O, Oda I. J Inorg Nucl Chem, 1979; 41: 1376 4 Brunett T P, Lakkis Z, Lakkis M, Leroy J F. Polyhedron. 1985; 4(4) : 579 5 马根样,李德谦.核化学与放射化学,1989;11(1) :40 6 徐光宪,王文清,吴谨光,高宏成,施鼐萃取化学原理,上海:上海科学技术出版社,1984:126 7 沈静兰,孙思修,高自立,赵康,房德仁,冯明良,景立新.山东大学学报(自然科学版),1984;(4) :70 8 乐少明,李德谦,倪嘉缵.无机化学,1987;3(2) :86 9 Sato T, Kato T. J Inorg Nucl Chem. 1977; 39: 120 [1] LIU Huizhou;YU Shuqiu;CHEN Jiayong Institute of Chemical Metallurgy; Academia Sinica; Beijing. MECHANISM OF EXTRACTION AND STRIPPING OF Fe(Ⅲ) WITH PRIMARY AMINE N1923 AS EXTRACTANT AND n-OCTANE AS DILUENT[J]. 金属学报, 1991, 27(4): 84-87. [2] MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica. SYNERGISTIC EXTRACTION OF Cd(II) WITH PRIMARY AMINE N-1923 AND NEUTRAL ORGANOPHOSPHORUS REAGENTS[J]. 金属学报, 1989, 25(1): 104-110. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed