Please wait a minute...
Acta Metall Sin  2009, Vol. 45 Issue (8): 978-982    DOI:
论文 Current Issue | Archive | Adv Search |
TEM OBSERVATION OF THE Al3Er PHASE DURING HOMOGENIZING OF THE 5083 ALLOY WITH Er ADDITION
LIN Shuangping; HUANG Hui; WEN Shengping; NIE Zuoren
College of Materials Science and Engineering; Beijing University of Technology; Beijing 100124
Cite this article: 

LIN Shuangping HUANG Hui WEN Shengping NIE Zuoren. TEM OBSERVATION OF THE Al3Er PHASE DURING HOMOGENIZING OF THE 5083 ALLOY WITH Er ADDITION. Acta Metall Sin, 2009, 45(8): 978-982.

Download:  PDF(4180KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The research on scandium additions in aluminium alloys has gained some interests over the last decades, due to the precipitation of Al3Sc phase particles, which have the beneficial effect on mechanical properties, weldability and corrosion resistance. But Sc is a very expensive strategic
metal. Therefore, a breakthrough of the selection of RE is expected. However, only a limited number of possibilities exist in Al–based alloys for the formation of coherent strengthening particles that are thermodynamically stable and have the ordered, L12 structure. It involves the addition of some suitable alloying elements such as La, Ce, Y, Sc and especially to Sc, while the effects of other single elements are scarcely referred. Recent studies have considered Er as a promising alloying element in Al–alloy, and it has been shown that a small Er addition can improve the material properties in several Al–alloy systems. Most of the beneficial effects are attributed to the formation of the Al3Er phase in these alloys.
However, few research have been done on the effect of homogenizing treatment on the precipitation of Er modified 5083 alloy. Although the Al3Sc and Al3(Sc,Zr) particles are wildly studied, but few studies about coherency and coarsening behaviors of Al3Er have been reported. The present investigation provides some information about orientation relationships of the precipitates with matrix and the coherency behavior of Al3Er phase.
Al3Er phase precipitates durinhomogenizing of the Er modified 5083 alloy produced by direct chill casting were analyzed by transmission electron microscopy (TEM).The results show that many particles with different shapes and sizes precipitate during homogenizing. Spheric precipitates with the size between 10—50 nm is Al3Er phase which are good coherent/semi–coherent with matrix; the orientation relationships between matrix and the spheric precipitates are derived:[111]m//[111]sp, (110)m//(110)sp, (101)m//(101)sp; [011]m//[011]s, (100)m//(200)sp, where the indexs m and sp indicate matrix and spheric precipitate, respectivety.

The radius for coherent/semi-conherent transition of Al3Er particle is determinined as 12---20 nm by TEM analysis; The calculated value of critical transition radius (rt=9.44 nm) of the Al3Er precipitates is correspondent with the experiments.

Key words:  homogenizing      Al3Er      coherent/semi-coherent     
Received:  15 December 2008     
ZTFLH: 

TG146.2

 
Fund: 

Supported by High Technology Research and Development Program of China (Nos.2006AA03A207 and 2007AA03Z514)

URL: 

https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2009/V45/I8/978

[1] Hecht R L, Kannan K, Ghosh A K, Bieler T R eds., Superplasticity and Superplastic Forming. Warrendale, PA:TMS, 1995: 259
[2] Kaibyshev R, Musin F, Lesuer D R, Nieh T G. Mater Sci Eng, 2003; A342: 169
[3] Wang Z T, Tian R Z. Handbook of Aluminum Alloy and It’s Processing. Changsha: Central South University Press, 2005: 292
(王祝堂, 田荣璋. 铝合金及其加工手册. 长沙: 中南大学出版社, 2005: 292)
[4] Nie Z R, Jin T N, Zou J X, Fu J B, Yang J J, Zuo T Y. Trans Nonferrous Met Soc Chin, 2003; 13: 509
[5] Filatov Y A, Yelagin V I, Zakharov V V. Mater Sci Eng, 2000; A280: 97
[6] Yang J J, Nie Z R, Jin T N, Xu G F, Fu J B, Ruan H Q,Zuo T Y. Trans Nonferrous Met Soc Chin, 2003; 13: 1035
[7] Kendig K L, Miracle D B. Acta Mater, 2002; 50: 4165
[8] Marquies E A, Seidman D N. Acta Mater, 2001; 49: 1909
[9] Yin Z M, Jiang F, Pan Q L. Trans Nonferrous Met Soc Chin, 2003; 13: 515
[10] Ratchev P, Verlinden B, Van Houtte P. Acta Metall Mater, 1995; 43: 621
[11] Jena A K, Chaturvedi M C. Phase Transformation in Materials, New Jersey: Prentice Hall, 1992: 61
[12] ElaginV I, Zakharov V V, Rostova T D. Met Sci Heat Treat, 1992; 34: 37
[13] Sanders I R E, Baumann S F, Stumpf H C. Mater Sci Technol, 1989; 31: 65
[14] Hollinshead P A. Mater Sci Technol, 1992; 8: 57
[15] Cao B Y, Joshib S P, Ramesh K T. Scr Mater, 2009; 60: 619
[16] Villars P, Calvert L D. Handbook of Crystallographic Data for Intermetallic Phases, Metals Park, Oh: ASM,1985; 2: 975
[17] Mondolfo L F. Aluminum Alloys: Structure and Properties. Beijing: Metal Industry Press, 1988: 12
([美]L. F. 蒙多尔福. 铝合金的组织与性能. 北京: 冶金工业出版社, 1988: 12)
[18] Seidman D N, Marquis E A, Dunand D C. Acta Mater, 2002; 50: 4021
[19] Jesser W A. Philos Mag, 1968; 19: 993
[20] Marquis E A, Seidman D N. Acta Mater, 2005; 53: 4259
[21] Iwamura S, Miura Y. Acta Mater, 2004; 52: 591

[1] ZHANG Yuelai, DUAN Deli, ZHAO Yuhang, HOU Sihan, LI Shu. SYNTHESIS AND ELECTRICAL PROPERTIES OF NiCrAl ELECTRO-THERMAL ALLOY FOAMS[J]. 金属学报, 2013, 49(2): 214-220.
[2] . Effect of homogenizing treatment on microstructures and properties of AZ91 alloy[J]. 金属学报, 2006, 42(10): 1014-1018 .
No Suggested Reading articles found!