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CLASSIFICATION OF THERMODYNAMIC PROPERTIES OF BINARY METALLIC MELTS ACCORDING TO THEIR PHASE DIAGRAMS |
Zhang Jian (Institute of Metallurgy; University of Science and Technology Beijing; Beijing 100083) |
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Cite this article:
Zhang Jian (Institute of Metallurgy; University of Science and Technology Beijing; Beijing 100083). CLASSIFICATION OF THERMODYNAMIC PROPERTIES OF BINARY METALLIC MELTS ACCORDING TO THEIR PHASE DIAGRAMS. Acta Metall Sin, 1998, 34(1): 75-85.
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Abstract After combining investigation of thermodynamic properties of binary metallic melts with their phase diagrams, it has been found that when the calculating models of mass action concentrations of metallic melts are formulated according to their main phase diagrams (i.e.phase diagrams involving compound formation, involving peritectic, involving saturated phase,involving solid solution and involving eutectic), the calculated thermodynamic properties (mass action concentrations) will rigorously obey the mass action law, except for the continuous solid solution obeying Raoult's law.
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Received: 18 January 1998
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