PHASE DIAGRAM OF KF-LiCl-CaCl_2 SYSTEM

Acta Metall Sin

1994, Vol. 30

Issue (19): 301-303 DOI:

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PHASE DIAGRAM OF KF-LiCl-CaCl_2 SYSTEM

YAN Licheng;FANG Jianhui;XU Jingyan;YANG Jinxiu(Shanghai University of Science and Technology)

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YAN Licheng;FANG Jianhui;XU Jingyan;YANG Jinxiu(Shanghai University of Science and Technology). PHASE DIAGRAM OF KF-LiCl-CaCl_2 SYSTEM. Acta Metall Sin, 1994, 30(19): 301-303.

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Abstract Phase diagram of KF-LiCl-CaCl_2 system has been determined by methods of visual variable-temperature, DTA and XRD. A negative deviation for KF occurs in molten salt LiCl-CaCl_2 solution. The semi-quantitative relationship between the relative area of primary crystallization region for fluoride of divalent alkaline metal and the energetic parameter of solution was also discussed together with KF-LiCl-BaCl_2 and KF-LiCl-SrCl_2 systems made previously by the authors.

Key words: KF-LiCl-CaCl_2 phase diagram

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https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y1994/V30/I19/301

1GrubeG,RucelW．JPhyschemRefData,1975;4:95921942;35:213阎立诚,徐京燕,杨金秀,金属学报,1992;28:B4904陈念贻,张桂成．金属学报,1964;7:1115阎立诚,朱鹦鹦,陈念贻．高等学校化学学报,1984;5:7556阎立城,杨金秀,朱鹦鹦．金属学报,1987:23:B2047阎立诚,杨金秀,郁磊．上海科技大学学报,1988;11(2):18阎立诚,杨金秀,朱鹦鹦．高等学校化学学报,1988;9:7269范谨霞,阎立诚,杨金秀．上海科技大学学报,1990;13(1):8710范谨霞,杨金秀,阎立诚．上海科技大学学报,1990;13(4):8111阎立诚,杨金秀,朱蕾,徐京燕,范瑾霞．金属学报,1990;26:B136

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