Acta Metall Sin  1993, Vol. 29 Issue (5): 56-62    DOI:

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EXTRACTION KINETICS AND INTERFACIAL CHEMISTRY FOR SYNERGISTIC EXTRACTION SYSTEMD_2EHPA-MPA-Fe~(3+)

LIU Difei Department of Chemical Engineering; Tsinghua University; BeijingYU Jingfen;professor;Department of Chemical Engieering.Tsinghua University;Beijing 100084

LIU Difei Department of Chemical Engineering; Tsinghua University; BeijingYU Jingfen;professor;Department of Chemical Engieering.Tsinghua University;Beijing 100084. EXTRACTION KINETICS AND INTERFACIAL CHEMISTRY FOR SYNERGISTIC EXTRACTION SYSTEMD_2EHPA-MPA-Fe~(3+). Acta Metall Sin, 1993, 29(5): 56-62.

Abstract References Related Articles Recommended Metrics Download:  PDF(476KB)  Export:  BibTeX | EndNote (RIS)       Abstract  The interfacial chemistry, synergistic effects and interfacial kinetics of thesynergistic extraction system D_2EHPA-MPA-Fe~(3+) have been studied, where MPA is amono-alkyl phosphate extraction with long carbon chain. D_2EHPA in the mixed extractionsystem strongly exhibits the effect on the thermodynamics of micella formation and interfaceproperties of MPA. Some thermodynamic parameters of micella formation were obtained.The interfacial adsorption behaviour of D_2EHPA is opposite to that of MPA. Theemulsification for single MPA and the mixed system was discussed. The synergistic effectswere found in this mixed extraction system. It is proved that the process of Fe~(3+) extractionfor non-mixed extraction system is controlled by chemical reaction, the controlling reactionoccurs at the interface, and the reaction rate equation is obtained. Key words:  interfacial chemistry      synergistic effect      Fe~(3+)      extraction kinetics      Received:  18 May 1993      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1993/V29/I5/56 1 於静芬,郁强,滕藤.有色金属(冶炼部分),1981;(6) :28 2 滕藤,於静芬,郁强.稀有金属,1983;2(2) :119 3 郁强,於静芬,滕藤.稀有金属,1985;4(1) :29 4 於静芬,刘涤非.铀矿冶,1989;8(2) :18 5 於静芬,熊毅钢.有色金属(季刊),1990;42(2) :67 6 於静芬,吉晨.高等学校化学学报,1992;13:224 7 於静芬,王彦玲,陈志洪,漆明鉴.核燃料,1966;(1) : [1] ZHAO Pingping, SONG Yingwei, DONG Kaihui, HAN En-Hou. Synergistic Effect Mechanism of Different Ions on the Electrochemical Corrosion Behavior of TC4 Titanium Alloy[J]. 金属学报, 2023, 59(7): 939-946. [2] Yanxin QIAO,Shuo WANG,Bin Liu,Yugui ZHENG,Huabing LI,Zhouhua JIANG. SYNERGISTIC EFFECT OF CORROSION AND CAVITATION EROSION OF HIGH NITROGEN STAINLESS STEEL[J]. 金属学报, 2016, 52(2): 233-240. [3] LIU Jincai;LU Jiufang Department of Chemical Engineering; Tsinghua University; Beijing Department of Chemical Engineering; Tsinghua University;Beijing 100084. KINETICS OF COPPER EXTRACTION BY N530-HEPTANE[J]. 金属学报, 1990, 26(4): 93-97. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed