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| LOCAL EQUILIBRIUM METHOD IN STUDYING PHASE DIAGRAM OF Mn-MnO SYSTEM |
| CHEN Qiyuan Central South University of Technology; Changsha |
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Cite this article:
CHEN Qiyuan Central South University of Technology; Changsha. LOCAL EQUILIBRIUM METHOD IN STUDYING PHASE DIAGRAM OF Mn-MnO SYSTEM. Acta Metall Sin, 1988, 24(6): 518-520.
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Abstract A special method based on the local equilibrium principle has been introduced inthe research of the phase diagram of Mn-MnO system. With this method, the difficulties of vol-atilization of Mn and the corrosion of Mn and MnO to refractory material were avoided. Thesolubility of oxygen in Mn and the composition of the interface between MnO and Mn weredetermined. Parts of the phase diagram of Mn-MnO system were constructed according to exper-imental results.
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Received: 18 June 1988
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1 陈启元,锰-氧系相图与二氧化锰热分解动力学,中南工业大学博士论文,1986 2 Schenck H, Frohberg M G, Nunninghoff R. Arch Eisenhuttenwes, 1964; 35: 269 3 Picard C, Gerdanian P. J Solid State Chem, 1974; 11: 190 4 Klingsberg C, Roy R. J Am Ceram S?c, 1960; 43: 620 5 Eror N G. Wagner J B Jr., J Electr?chem s?c, 1971; 118: 1665 6 B?cquet J-P, Kawahara M, Lacombe P. C R Hebd Seances Acad Sci (Paris), 1967; C265: 1318 |
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