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Acta Metall Sin  1982, Vol. 18 Issue (2): 211-220    DOI:
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THERMODYNAMIC EQUILIBRIUM OF Cu-Fe-S-Cl-H_2O SYSTEM AND ITS POTENTIAL DIAGRAM
Huang Zhenqian Central South Institute of Mining and Metallurgy; Changsha
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Huang Zhenqian Central South Institute of Mining and Metallurgy; Changsha. THERMODYNAMIC EQUILIBRIUM OF Cu-Fe-S-Cl-H_2O SYSTEM AND ITS POTENTIAL DIAGRAM. Acta Metall Sin, 1982, 18(2): 211-220.

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Abstract  The Cu-Fe-S-Cl~--H_2O system has been thermodynamically analyzed in view of the principle that every component in a solution is in equilibrium each other, and then the potential-pH diagram of the chalcopyrite-Cl~--H_2O system has been constructed.The thermodynamic analysis indicated that a CuCl stable region may be occurred in correspondence with certain contents of Cl in solution,and does not appear beyond this limits of Cl content.The possible way to yield CuCl from the Cu-Fe-S-Cl~--H_2O system has also been discussed.
Received:  18 February 1982     
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1 Majima,H.,Can.Met.Q.,8(1969) ,269.
2 黄振谦,有色金属(冶炼部分),1980,№ 5,38.
3 傅崇说,郑蒂基,中南矿冶学院学报,(1980) ,№3,12.
4 张祥麟,络合物化学,冶金工业出版社,1978,p.23.
5 Miller,J.D.;Herbst,J.A.;Sepulveda,J.L.,Trans.Soc.Min.Eng.AIME,260(1976) ,166.
6 Sillen,L.G.;Martell,A.E.,Stability Constants of Metal-Ion Complexes,Chemical Society,Special Publications,No.17,London,1964,p.271.
7 Butler,J.N.,Ionic Equilibrium,A Mathematical Approach,Reading,Mass.,Addison-Weslcy,1964,p.261.
8 黄振谦,中南矿冶学院学报,(1981) ,No.2,48.
9 Latimer,W.M.,Oxidation Potentials,Prentice-Hall,New York,1953,p.392.
10 中国科学院贵阳地球化学研究所,简明地球化学手册,科学出版社,1977.
11 Garrels,R.M.;Christ,C.L.,Solutions,Minerals and Equilibria,Harper and Row,New York,1965,p.411.
12 龟谷博;青木爱子,电气化学工业物理化学,40(1972) ,720._
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