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SELF-DIFFUSION IN IRON-50% COBALT ALLOY |
TSIEN CHIH-CHIANG;KAO SHU-CHUN;CHANG PEI-LIN Institute of Metal Research; Academia Sinica |
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Cite this article:
TSIEN CHIH-CHIANG;KAO SHU-CHUN;CHANG PEI-LIN Institute of Metal Research; Academia Sinica. SELF-DIFFUSION IN IRON-50% COBALT ALLOY. Acta Metall Sin, 1965, 8(3): 326-331.
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Abstract The self-diffusion coefficients of Fe~(55) and Co(60) in iron-50% cobalt alloy in thetemperature range of 850-980℃ (α-region) have been measured by means of the"residual activity" method. The results are as follows: D_(Fe)= 0.26 exp(-55,600/RT) cm~2/sec, D_(Co)=14 exp(-65,000/RT) cm~2/sec. From quasi-chemical approach an approximate relationship between the activationenergies of self-diffusion in concentrated homogeneous solid solutions and those of self-diffusion and impurity diffusion in one of the components is derived as 7Q_(Fe)-3Q_(Co)=5Q_(Co)~0-Q_(Fe)~0. This relationship is found to be applicable in the Fe-50% Co alloy (α-region).
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Received: 18 March 1965
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[1] #12. [2] 高树濬、钱知强:物理学报,1965,21,622。 [3] Hirone, T., Kunitomi, N., Sakamoto, M.: J. Phys. Soc. Japan, 1958, 13, 840. [4] Peart, R. F., Tomlin, D. H.: Acta Met., 1962, 10, 123. [5] 钱知强、高树濬、张沛霖:金属学报, 1965, 8, 319. [6] Sagel, K.: Tabellen zur Rontgenstrukturanalyse, (Springer-Verlag, Berlin, 1958) . [7] Buffington, F. S., Bakalar, I. D., Cohen, M.: The Physics of Powder Metallurgy, ed. W. Kingston, (McGraw-Hill, 1951) , p. 92. [8] Zener, C.: Imperfections in Nearly Perfect Crystal, (Wiley, 1952) , p. 289. [9] #12. [l0] #12. [11] Borg, R. J., Birchenall, C. E.: Trans. AIME, 1960, 218, 980. [12] Borg, R. J., Lai, D. Y. F.: Acta Met., 1963, 11, 861.h |
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