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| STATISTICAL THEORY OF MOLTEN SALT SOLUTIONS Ⅰ. ENERGY OF MIXING OF BINARY SYSTEMS |
| CHEN NIAN-YI; ZHENG GUI-CHENG;(Institute of Metallurgy; Academia Sinica) |
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Cite this article:
CHEN NIAN-YI; ZHENG GUI-CHENG;(Institute of Metallurgy; Academia Sinica). STATISTICAL THEORY OF MOLTEN SALT SOLUTIONS Ⅰ. ENERGY OF MIXING OF BINARY SYSTEMS. Acta Metall Sin, 1964, 7(1): 12-23.
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Abstract From the radial distribution function theory of molten salts, a three-dimensional statistical model was suggested for binary salt solutions, containing monovalent ions only. By this model, formulas for the heat of mixing, the excess free energy of mixing, and the liquidus lines of certain binary phase diagrams were derived. Calculations for various binary alkali nitrate mixtures and binary alkali halide mixtures were made. The results were in good agreement with the experimental values.
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Received: 18 January 1964
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