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SIMULATION OF LEDGEWISE GROWTH KINETICS OF PROEUTECTIOD FERRITE UNDER INTERFACIAL REACTION–DIFFUSION MIXED CONTROL MODEL |
LIU Zhiyuan; YANG Zhigang; LI Zhaodong; LIU Zhenqing; ZHANG Chi |
Key Laboratory of Advanced Materials of Ministry of Education; Department of Materials Science and Engineering; Tsinghua University; Beijing 100084 |
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Cite this article:
LIU Zhiyuan YANG Zhigang LI Zhaodong LIU Zhenqing ZHANG Chi. SIMULATION OF LEDGEWISE GROWTH KINETICS OF PROEUTECTIOD FERRITE UNDER INTERFACIAL REACTION–DIFFUSION MIXED CONTROL MODEL. Acta Metall Sin, 2010, 46(4): 390-395.
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Abstract A mixed control model considering both carbon diffusion and interfacial reaction is established for ledgewise growth kinetics of proeutectiod ferrite during γ →α isothermal transformation in low carbon steels. In this model, the growth rate of ledgewise ferrite and the carbon concentration at the ledge riser are determined by both carbon diffusion at ledge riser in austenite and interfacial reaction rate of γ →α transformation, which is different from the traditional local equilibrium(LE) model. Simulation is done by utlizing this model to analyze the ledgewise growth kinetics of proeutectiod ferrite. And based on analysis of the characteristics of growth kinetics of proeutectiod ferrite obtained by the simulation, a factor S, which includes the effects of carbon diffusion, interface migration, temperature and composition, is proposed to characterize the control mode of growth kinetics. By judging this factor S, we can predict that if the carbon diffusion or interfacial reaction dominates the gowth kinetics of proeutectiod ferrite. In the case that the value S is relatively small, the growth kintics is mainly controlled by interfacial reaction. In the case that the value of S is quite large, the growth kinetics is controlled by carbon diffusion, which returns to the traditional local equilibrium model. The mixed control simulation results for ledgewise growth of proeutectoid ferrite at 720 ℃ in Fe–1%C (atomic fraction) alloy show a good agreement with the experimental results previously reported.
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Received: 07 July 2009
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Fund: Supported by National Natural Science Foundation of China (No.50871059) and Specialized Research Fund for the Doctoral Program of Higher Education (No.20070003006) |
[1] Sietsma J, van der Zwaag S. Acta Mater, 2004; 52: 4143
[2] Xu Z Y. Principle of Phase Change. Beijing: Science Press, 1988:1
(徐祖耀. 相变原理. 北京: 科学出版社, 1988: 1)
[3] Bhadeshia H K D H, Svensson L E, Gretoft B. Acta Metall, 1985; 33: 1271
[4] Vandermeer R A, Acta Metall Mater, 1990, 38: 2461
[5] Enomoto M. Metall Mater Trans, 2006; 37A: 1703
[6] Krielaart G P, Sietsma J, van der Zwaag S. Mater Sci Eng, 1997; A237: 216
[7] Onink M, Tichelaar F D, Brakman C M, Mittemeijer E J, van der Zwaag S. J Mater Sci, 1995; 30: 6223
[8] Nolfi F V, Shewman P G, Foster J S. Trans Metall Soc AIME, 1969; 245: 1427
[9] Kop T A, Van Leeuwen Y, Sietsma J, van der Zwaag S. ISIJ Int, 2000; 7: 713
[10] Wu R H, Ruan X Y, Zhang H B, Hsu T Y. J Mater Sci Technol, 2004; 20: 561
[11] Enomoto M. Acta Mater, 1987; 35: 935
[12] Enomoto M. Acta Mater, 1987; 35: 947
[13] Li Z D, Yang Z G, Liu Z Y, Wang Q C. J Iron Steel Res Int, 2007; 14(suppl1): 306
[14] Hillert M. Metall Trans, 1975; 6A: 5
[15] Trivedi R, Pound G M. J Appl Phys, 1967; 38: 3572
[16] Kinsman K R, Eichen E, Aaronson H I. Metall Trans, 1975; 6A: 303 |
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