金属学报  1997, Vol. 33 Issue (7): 763-768

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Vogel—Fulcher定律与玻璃转变温度的关系

蒋青;徐晓亚;赵明

吉林工业大学;长春;130025;吉林工业大学;长春;130025;吉林工业大学;长春;130025

RELATIONSHIP BETWEEN VOGELFULCHER LAW AND GLASS TRANSITION TEMPERATURE

JIANG Qing;XU Xiaoya;ZHAO Ming (Jilin University of Technoloasl; Changchun 130025)

蒋青;徐晓亚;赵明. Vogel—Fulcher定律与玻璃转变温度的关系[J]. 金属学报, 1997, 33(7): 763-768.
, , . RELATIONSHIP BETWEEN VOGELFULCHER LAW AND GLASS TRANSITION TEMPERATURE[J]. Acta Metall Sin, 1997, 33(7): 763-768.

摘要 参考文献 相关文章 Metrics 全文: PDF(524 KB)   摘要: 通过在不同加热速度、不同坩埚材料和不同样品质量条件下测定In，Zn，Sn，Pb等元素的熔点，校正了加热速度对差示扫描量热仪显示温度的影响．根据对仪器温度校正的结果，研究了Ni33Zr67，Zr65Al7.5Ni10Cu15Co2.5，Pt69.0Ni9.6P21.4，聚醚砜（PES）和聚苯乙烯（PS）等材料的玻璃转变的动力学特征结果表明，玻璃转变温度与加热速度对数成正比，且这种关系并不违反Vogel－Fulcher定律．根据测量的玻璃转变温度和Vogtl－Fulcher定律计算了材料的理想玻璃转变温度和玻璃转变激活能． 关键词 ： 玻璃转变温度,  差示扫描量热仪,  加热速度,  Vogel－Fulcher定律     Abstract：The apparent temperatures on Differential Scanning Calorimeter were calibrated by measuring the melting temperature of In, Zn, Sn and Ph with different heating rates, different crucibles and different sample weights. Based on the calibrated results, the kinetic characteristics of the glass transition for Ni33Zr67, Zr65Al7.5Ni10Cu,,Co2.5,Pt69.0Ni9.6P2104, polyethersulfone and polystyrene were studied. The results show that there is a linear relation ship between the logarithm of heating rates and the glass transition temperatures. It is argued that this linear relationship is not against the Vogel-Fulcher law. According to the measured glass transition temperatures and Vogel-Fulcher law, the ideal glass transition temperature and the activation energy for the glass transition were calculated. Key words： glass transition temperature    DSC    heating rate    Vogel-Fulcher law 收稿日期: 1997-07-18      基金资助:国家自然科学基金!59371006;;霍英东教育基金!040103 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 蒋青 徐晓亚 赵明 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1997/V33/I7/763 1Zallen R. The Phyjlcs ofAmorrkous Solids. New York: A Whey—Interscience Publication, 1983: 3 2Johnson W L.Prog Mater Sci,1986;30:81 3Saslow W S.Phys Rev,1988;37B:676 4 BruningR,Samwer J H.Phys Rev,1992;46B:318 5 KloseG,FechtJH.Mater Sci Eng,1994;A179/180:77 6蒋青,赵明,吕晓霞.材料研究学报, 1997; 11: 187 7 LuckR,JiangQ,Predel B R.J Non-Cryst Solids,1990;117-118:911 8Shi F G.J Mater Res, 1994;9: 1908 9Kauzmann W. Chem Rev, 1948; 43: 21 [1] 贾婷婷,坚增运,许军锋,朱满,常芳娥. Ge30Se70硫系玻璃的特征温度和性能*[J]. 金属学报, 2016, 52(6): 755-760. [2] 沈涛;王景唐. 过冷液态金属热力学性质的变分计算[J]. 金属学报, 1990, 26(3): 119-125. Viewed Full text Abstract Cited   Shared      Discussed