金属学报  1986, Vol. 22 Issue (2): 124-133

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(Fe,Co,Ni)-P系合金电化学沉积条件与结构的关系

姜晓霞;张弦;林树智

中国科学院金属研究所;中国科学院金属研究所;中国科学院金属研究所

CORRELATION BETWEEN STRUCTURE OF ELECTROCHEMICALLY DEPOSITED (Fe,Co,Ni)-P LAYERS AND PROCESS CONDITIONS

JIANG Xiaoxia; ZHANG Xuan; LIN Shuzhi (Institute of Metal Research; Academia Sinica; Shenyang)

姜晓霞;张弦;林树智. (Fe,Co,Ni)-P系合金电化学沉积条件与结构的关系[J]. 金属学报, 1986, 22(2): 124-133.
, , . CORRELATION BETWEEN STRUCTURE OF ELECTROCHEMICALLY DEPOSITED (Fe,Co,Ni)-P LAYERS AND PROCESS CONDITIONS[J]. Acta Metall Sin, 1986, 22(2): 124-133.

摘要 参考文献 相关文章 Metrics 全文: PDF(2999 KB)   摘要: 用测定阴极极化曲线、比色分析、X射线、扫描电镜及电子探针分析等方法系统地研究了(Fe,Co,Ni)-P合金电化学沉积条件与镀层结构的关系。结果表明:电化学沉积条件对镀层结构的影响是通过镀层中磷含量变化实现的;镀液中NaH_2PO_2浓度及pH值是两种主要影响因素;找出了电位与结构关系以及各系非晶态结构小片堆垛最高高度。 Abstract：A study has been made of the structure of the electrochemically deposited amorphous (Fe, Co, Ni)-P layers with relation to the process conditions, e.g. pH value, current density, metallic salt concentration, etc., by means of X-ray analysis, SEM and EPMA. Results showed that the effect of the process on the structure is realized by changing the P content of the layer. While P contained over 8%, below 3% or between 3 and 8%, a layer may be constructed as amorphous alloy, supersaturated solution or mixed structures respectively. The major factors affecting the structure of the deposited layer are found to be the concentration of NaH_2PO_2 and pH value of the bath. The structure of the layer may be also influenced by the potential of electro-deposition. The Fe-P, Co-P or Ni-P system is similar in amorphous structure of which the highest thickness of stack of the atomic face is 2.0, 2.5 or 6.5nm respectively. 收稿日期: 1986-02-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 姜晓霞 张弦 林树智 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1986/V22/I2/124 1 石桥知;鹰野修;青木公二,金属表面技术,21 (1970) ,541;31 (1980) ,28． 2 Brenner, A., J. Res. Nat. Bur. Stand., 44 (1950) , 109． 3 增井宽二,日本金属学会誌,41 (1977) ,1130． 4 #12 5 #12 6 云南省交通科学研究所,镀铁电镀液研究,1970． 7 武汉锅炉厂403车间,防腐包装,1979． 8 渡(刀辶)徹,金属表面技术,32 (1981) ,601． 9 吉岡正三,金属表面技术,20 (1961) ,172． 10 林树智;黑祖昆,物理学报,33 (1984) ,302． 11 Dixmier, J.; Gunier, A., Rev, Metall,, (Paris), 64 (1967) , 53．[ No related articles found! Viewed Full text Abstract Cited   Shared      Discussed