金属学报  1995, Vol. 31 Issue (24): 527-534

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低偏析高温合金M41的高温氧化性能研究

李铁藩;胡武生;沈嘉年

中国科学院金属腐蚀与防护研究所腐蚀科学开放实验室

HIGH TEMPERATURE OXIDATION PERFORMANCE OF SUPERALLOY M41

LI Tiefan; HU Wusheng; SHEN Jianian(State Key Laboratory of Corrosion Science; Institute of Corrosion and Prolection of Metals; Chinese Academy of Sciences; Shenyang 110015)

李铁藩;胡武生;沈嘉年. 低偏析高温合金M41的高温氧化性能研究[J]. 金属学报, 1995, 31(24): 527-534.
, , . HIGH TEMPERATURE OXIDATION PERFORMANCE OF SUPERALLOY M41[J]. Acta Metall Sin, 1995, 31(24): 527-534.

摘要 参考文献 相关文章 Metrics 全文: PDF(614 KB)   摘要: 用Ｍ１７和Ｋ３合金作对比，着重研究了低偏析镍基铸造高温合金Ｍ４１的高温氧化性能进行了恒温氧化、循环氧化以及Ｘ射线衍时（ＸＲＤ）、扫描电镜（ＳＥＭ）、能谱分析（ＥＤＡＸ）等实验，结果表明，Ｍ４１合金的氧化速度随温度升高以加速度方式增长，但小于Ｋ３合金，温度越高，差别越大；在１０００℃以上，Ｍ４１合金的氧化动力学规律明显偏低于抛物线规律．Ｍ４１合金循环氧化性能优于Ｍ１７合金，氧化膜粘附性较好，基本不脱落，在过渡氧化阶段，该合金主要形成Ｎｉ和Ｃｒ的氧化物：稳态氧化阶段的氧化层主要由连续致密的Ｃｒ２Ｏ３，外氧化层和树根状Ａｌ２Ｏ３内氧化层构成．内氧化随时间延长，温度升高而加剧，离外氧化层／基体界面越近，内氧化物颗粒越细、越多． 关键词 ： 镍基铸造高温合金,  高温氧化性能,  内氧化     Abstract：Compared with alloy M17 and K3, high temperature oxidation performance of low segregation cast nickel base superalloy M41 has been investigated by means of isothermial and cyclic oxidation, XRD, SEM, EDXA and X-ray element maps. Results show that oxidation rate of the alloy M41 accelerates with the rise of temperature, but is lower than that of the alloy K3. Scale adherance of the alloy M41 is better than that of the alloy K3 and M17, so its cyclic oxidation performance is superior to that of alloy M17. Oxidation kinetics of alloy M41 obviously deviate from parabolic law, because votilization of CrO3is severe above 1000℃ .The higher temperature is, the more severe volatilization is, so the more obvious deviation is. Volatilization of CrO3 is minor below 1000℃ ,so deviation is small. In transient oxidation stage, the alloy M41 primarily forms oxides of Ni and Cr, and in steady oxidation stage, scale consists mainly of a continuous and compact Cr2O3 at the outer layer and a tree root shaped Al2O3 at the inner oxidation layer. The internal oxidation becomes more severe with the rise of temperature and the prolongation of time.The nearer it is from the outer oxide layer/matrix interface, the more and smaller the particles of internal oxidation are. This article syntheticly analyses the results of experiments. Key words： cast nickel base superalloy    scale adherence    high temperature oxidation performance    internal oxidation      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 李铁藩 胡武生 沈嘉年 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1995/V31/I24/527 1KofstadP．HighTemperatureCorroston．London:ElsevierAppliedScience,1988:3292BohmG,KahlweitM．ActaMetall,1964;12:6413HOUY,StriingerJ．OxidMet,1992,38:323n [1] 张军,介子奇,黄太文,杨文超,刘林,傅恒志. 镍基铸造高温合金等轴晶凝固成形技术的研究和进展[J]. 金属学报, 2019, 55(9): 1145-1159. [2] 平发平，胡青苗，杨锐. 利用第一原理研究合金化对γ-TiAl,抗氧化性能的影响[J]. 金属学报, 2013, 29(4): 385-390. [3] 梁淑华; 徐磊; 方亮; 范志康 . Cu--Al预合金粉末中Al内氧化工艺的分析[J]. 金属学报, 2004, 40(3): 309-313 . [4] 呼和 . 镍基铸造高温合金的热等静压处理[J]. 金属学报, 2002, 38(11): 1199-1202 . [5] 徐岩; 郭守仁 . 微量元素P对Ni基铸造高温合金组织和持久性能的影响[J]. 金属学报, 2000, 36(12): 1240-1243 . [6] 申玉田; 吴人洁; 崔春翔; 孟凡斌 . 高强度高电导率Cu-Al2O3复合材料的制备[J]. 金属学报, 1999, 35(8): 888-892 . [7] 宁远涛;文飞;赵怀志;邓德国. Pd—Eu合金内氧化[J]. 金属学报, 1993, 29(9): 65-71. [8] 王福会;楼翰一;白林祥. Al-Y共渗涂层的研究[J]. 金属学报, 1990, 26(2): 106-109. [9] 宁远涛;李永年. Pd-40Ag-1M(M=Zr,Y)合金的内氧化行为[J]. 金属学报, 1989, 25(1): 96-103. [10] 黄乾尧;师燕渝. 一种镍基高温合金的碳化物析出与转化动力学[J]. 金属学报, 1988, 24(6): 399-403. [11] 杨锐;李东;万晓景. Ti-Al-La三元系中α_2相析出相界[J]. 金属学报, 1988, 24(4): 288-290. Viewed Full text Abstract Cited   Shared      Discussed