金属学报  2005, Vol. 41 Issue (6): 669-672

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水热法合成负热膨胀材料ZrW2O8

邢奇凤;邢献然;杜 凌;于然波;陈 骏;邓金侠;罗 君

北京科技大学物理化学系; 北京 100083; 北京科技大学化学系; 北京 100083

Hydrothermal Synthesis of Negative Thermal Expansion Material ZrW2O8

XING Qifeng; XING Xianran; DU Ling; YU Ranbo; CHEN Jun; DENG Jinxia; LUO Jun

Department of Physical Chemistry; University of Science & Technology Beijing; Beijing 100083; Department of Chemistry; University of Science & Technology Beijing; Beijing 100083

邢奇凤; 邢献然; 杜凌; 于然波; 陈骏; 邓金侠; 罗君 . 水热法合成负热膨胀材料ZrW2O8[J]. 金属学报, 2005, 41(6): 669-672 .
, , , , , , . Hydrothermal Synthesis of Negative Thermal Expansion Material ZrW2O8[J]. Acta Metall Sin, 2005, 41(6): 669-672 .

摘要 参考文献 相关文章 Metrics 全文: PDF(146 KB)   摘要: 采用水热法在500 ℃的低温条件下成功地合成了具有负热膨胀系数的 材料ZrW2O8. X射线衍射结果表明, 当加入的盐酸溶液浓度c HCl≥6 mol/L时, 可用水热法合成出多晶前驱体ZrW2O7(OH)2(H2O)2. 运用 热重-差热分析法研究了前驱体ZrW2O7 (OH)2 (H2O) 2 和产物ZrW2O8的热稳定性. 结果表明, 前驱体在较低温度(500 ℃) 下灼烧即可获得产物ZrW2O8. 经X射线衍射和红外光谱分析证明, 所获得的产物为单一立方相ZrW2O8. 关键词 ： ZrW2O8,  水热合成,  负热膨胀     Abstract：Negative thermal expansion compound ZrW2O8 was successfully synthesized by hydrothermal method with low temperature heat treatment at 500 ℃. The XRD result showed that the crystalline precursor ZrW2O7 (OH) 2 (H2O) 2 was formed when the concentration of HCl was equal to or greater than 6 mol/L. The thermal stability of the synthesized ZrW2O8 and its precursor ZrW2O7 (OH) 2 (H2O) 2 were studied by thermo-gravimetric analysis (TGA) and differential thermal analysis (DTA), which confirmed ZrW2O8 could be synthesized through sintering the precursor at low temperature of 500 ℃. Powder X-ray diffraction and FT-IR spectroscopy investigations confirmed that the synthesized product is single cubic ZrW2O8 phase. Key words： ZrW2O8    hydrothermal synthesis    negative thermal expansion 收稿日期: 2004-08-31      ZTFLH:  TQ174   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 邢奇凤 邢献然 杜凌 于然波 陈骏 邓金侠 罗君 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2005/V41/I6/669 [1]Mary T A,Evans J S O,Vogt T,Sleight A W.Science,1996;272:90 [2]Evans J S O,Hu Z,Jorgensen J D,Argyriou D N,Short S,Sleight A W.Science,1997;275:61 [3]Zhao X H.Chin Chem Bull,1998;(11):19 (赵新华．化学通报,1998;(11):19) [4]Wang C,Wang T M,Shen R,Liang J K.Physics,2001;30:772 (王聪,王天民,沈容,梁敬魁．物理,2001;30:772) [5]Li S H,Zhao X H.Rare Met Cemented Carbides,2002;30(1):14 (李淑欢,赵新华．稀有金属与硬质合金,2002;30(1):14) [6]Nakajima N,Yamamura Y,Tsuji T.Solid State Commun,2003;128:193 [7]Holzer H,Dunand D C.J Mater Res,1999;14:780 [8]Verdon C,Dunand D C.Scr Mater,1997;36:1075 [9]Shen R,Wang C,Wang T M.J Inorg Mater,2002;17:1089 (沈容,王聪,王天民．无机材料学报,2002;17:1089) [10]Chang L L Y,Scroger M G,Phillips B.J Am Ceram Soc,1967;50:211 [11]Khosrovani N,Sleight A W,Vogt T.J Solid State Chem,1997;132:355 [12]Kameswari U,Sleight A W,Evans J S O.Int J Inorg Mater,2000;2:333 [13]Shen R,Wang T M,Bai H L,Xiong C J.Mater Eng,2003;(3):3 (沈容,王天民,白海龙,熊常健．材料工程,2003;(3):3) [14]Closmann C,Sleight A W.J Solid State Chem,1998;139:424 [15]Wilkinson A P,Lind C,Pattanaik S.Chem Mater,1999;11:101 [16]Kong X Y,Wu J S,Zeng Z P.J Chin Ceram Soc,1999;27:265 (孔向阳,吴建生,曾振鹏．硅酸盐学报,1999;27:265) [17]Evans J S O,Mary T A,Vogt T,Subramanian A,Sleight A W.Chem Mater,1996;8:2809 [18]Gallardo-Amores J M,Amador U,Moran E,Alario- Pranco M A.Int J Inorg Mater,2000;2:123a [1] 韦昭召, 马骁, 张新平. NiTi合金B2-B19′马氏体相变晶体学的拓扑模拟研究[J]. 金属学报, 2018, 54(10): 1461-1470. [2] 宋晓艳 孙中华. 负热膨胀反钙钛矿锰氮化合物的研究综述[J]. 金属学报, 2011, 47(11): 1362-1371. [3] 张从阳 朱洁 张茂才. Mn3(Cu1-xGex)N的负热膨胀现象[J]. 金属学报, 2009, 45(1): 97-101. Viewed Full text Abstract Cited   Shared      Discussed