金属学报  1994, Vol. 30 Issue (16): 150-155

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LiF-CaF_2,NaF-CaF_2和KF-CaF_2系熔体热力学参量及相图的计算

许茜;于亚鑫;邱竹贤

东北大学

THERMODYNAMIC PROPERTIES AND PHASE DIAGRAMS OF Li-CaF_2,NaF-CaF_2 AND KF-CaF_2

XU Qian;YU Yaxin;QIU Zhuxian(Northeastern University;Shenyang)(Manuscript received 25 June;1993)

许茜;于亚鑫;邱竹贤. LiF-CaF_2,NaF-CaF_2和KF-CaF_2系熔体热力学参量及相图的计算[J]. 金属学报, 1994, 30(16): 150-155.
, , . THERMODYNAMIC PROPERTIES AND PHASE DIAGRAMS OF Li-CaF_2,NaF-CaF_2 AND KF-CaF_2[J]. Acta Metall Sin, 1994, 30(16): 150-155.

摘要 参考文献 相关文章 Metrics 全文: PDF(333 KB)   摘要: 本文将ＤＣＡ模型应用于ＬｉＦ－ＣａＦ２，ＮａＦ－ＣａＦ２和ＫＦ－ＣａＦ２熔体，并假设在这些熔体中存在络合离子．利用已有的上述混合熔体量热和熔盐相图的实验数据估计了熔体模型中的参数，并计算了熔体的混合热力学参量及相图．计算结果与实验结果吻合较好． 关键词 ： ＬｉＦ－ＣａＦ_２,  ＮａＦ－ＣａＦ_２,  ＫＦ－ＣａＦ_２,  ＤＣＡ模型,  熔体热力学性质,  熔盐相图     Abstract：The discrete complex anion modle was introduced to the molten salt solutions of LiF-CaF2,NaF-CaF2-and KF-CaF2,based upon the assumption of existence of the CaF3 complex ions contained in the melts.A set of parameters were evaluated from experimental data about enthalpies of mixing and phase diagrams of the above three systems.The thermodynamic properties and phase diagrams of the melts were calculated by using the model.The results obtained were in good agreement with experimental data.Correspondent:XU Qian,(Department of Nonferrous Metallurgy,Northeastern University,Shenyang 110006) Key words： LiF-CaF_2    NaF-CaF_2    KF-CaF_2    DCA model    thermodynamic property    phase diagram      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 许茜 于亚鑫 邱竹贤 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1994/V30/I16/150 1PeltonAD,ThompsonWT．CanJChem,1970;48:15852KarakayaI,ThompsonWT．CanMetallQ,1986;25(4):3073HongKC,KleppaOJ．JPhysChem,1978;82(14):15964KleppaOJ,WakiharaM．JInorgNuclChem,1976;38:7155KleppaOJ,HonhKC．JPhysChem,1974;78(15):14796DeadmoreDL,MachinJS．JPhysChem,1960;64:8247BukhalovaGA,SulaimankulovK,BostandzhiyouAK．RussJInorgChem,1959;4:5168IshaqueM．BullSocChimFr,1952;2:1309BarinI,KnackeO．ThermochemicalPropertiesofInorgnicSubstance．Berlin:Springer-Verlag,1973:170,362,401,516 [1] 唐波;钦佩;柳妙修;张未名;陈念贻. 人工神经网络在熔盐相图中间相预报中的应用[J]. 金属学报, 1994, 30(13): 22-26. [2] 王淑兰;张翊凤;隋殿鹏. SmCl_3-PbCl_2和SmCl_3-PbCl_2-CaCl_2系相图的研究[J]. 金属学报, 1993, 29(2): 70-73. [3] 李瑞青;周国治. NaCl-BaCl_2-SrCl_2三元熔盐相图的计算[J]. 金属学报, 1989, 25(3): 90-95. Viewed Full text Abstract Cited   Shared      Discussed