金属学报  1987, Vol. 23 Issue (6): 553-559

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Ni液中Ce-O,Ce-S,Ce-S-O平衡的研究

王龙妹;杜挺

冶金部钢铁研究总院;冶金部钢铁研究总院

Ce-O, Ce-S AND Ce-S-O EQUILIBRIA IN LIQUID Ni

by WANG Longmei; DU Ting (Central Iron and Steel Research Institute; Ministry of Metallurgical Industry; Beijing) (Manuscript received 10 February; 1986; revised manuscript 11 August; 1986)

王龙妹;杜挺. Ni液中Ce-O,Ce-S,Ce-S-O平衡的研究[J]. 金属学报, 1987, 23(6): 553-559.
, . Ce-O, Ce-S AND Ce-S-O EQUILIBRIA IN LIQUID Ni[J]. Acta Metall Sin, 1987, 23(6): 553-559.

摘要 参考文献 相关文章 Metrics 全文: PDF(425 KB)   摘要: 由低温无水电解稀土夹杂物和固体电解质定氧活度测得Ni液中Ce_2O_3,CeS及Ce_2O_2S生成反应的平衡常数,由此可得: △G°_(Ce_2O_3)=-116240+315.8 T △G°_(Ces)=-570280+220.1 T △G°_(Ce_2O_2S)=-984850+238.5 T 由实验测得数据经热力学分析计算得到1600℃Ni液中a_O-a_S平衡图,为理论上预测夹杂物生成的先后次序及类型提供了依据。 Abstract：Reaction constants of the formation of Ce_2O_3, CeS and Ce_2O_2S in liquid Ni at 1500 to 1600℃ have been determined, then the standard Gibbs energies (J·mol) were obtained: △G°_(Ce_2O_3)=-116240+315.8 T △G°_(Ces)=-570280+220.1 T △G°_(Ce_2O_2S)=-984850+238.5 T The reaction coefficients e_O~(Ce) and e_S~(Ce) have also be determined: e_O~(Ce)=-333451/T+149.7 e_S~(Ce)=-276228/T+146.0 The equilibrium phase diagram of a_o-a_s for Ni-Ce-S-O system at 1600℃ was also given. 收稿日期: 1987-06-18      基金资助:中国科学院科学基金 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王龙妹 杜挺 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1987/V23/I6/553 1 王龙妹,杜挺.金属学报,1984;20:A286 2 王龙妹,杜挺.金属学报,1985;21:A249 3 王龙妹,杜挺.中国稀土学报,198S;3(2) :76 4 Schmalzfried H. Z Electrochem Ber Bunsenges Gesell Phys Chem, 1962; 66: 572 5 Fischer W A, Ackerman W A, Arch Eisenhuettenwes, 1966; 37: 43 6 Janke D. Fischer W A. Arch Eisenhuettenwes, 1975; 46: 755 7 徐秀光,王常珍,张贺林.东北工学院学报,1983;37(4) :29 8 Wang Longmei, Du Ting. Proc of the Int Conf on Rare Earth Development and Applications, Beijing, 1985, Beijing: Science Press, 1985, Vol; Ⅱp. 1165 9 Buzek Z. Hutn Listy, 1979; 34(10) : 699 10 Venal W V, Geiger G H. Metall Trans, 1973; 4: 2567 11 Vahed A, Kay D A R. Metall Trans, 1976; 7B: 375 12 《数学手册》编写组.数学手册,人民教育出版社,1979:8 13 王龙妹,杜挺.稀土.1983;(4) :48 No related articles found! Viewed Full text Abstract Cited   Shared      Discussed