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金属学报  1987, Vol. 23 Issue (3): 257-261    
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NaCl-KCl熔盐中电解渗Al电极过程的研究
马樟源;徐之强;曹铁梁;石声泰
中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所;江西大学82届毕业生
ELECTRODE PROCESS OF ELECTROLYTIC COATING OF Al IN FUSED NaCl-KCl SALT BATH
MA Zhangyuan; XU Zhiqiang; CAO Tieliang; SHI Shengtai (Shih Shing-Tai)(Shanghai Institute of Metallurgy; Academis Sinica) (Manuscript received 22 July; 1984; revised manuscript 26 November; 1985)
引用本文:

马樟源;徐之强;曹铁梁;石声泰. NaCl-KCl熔盐中电解渗Al电极过程的研究[J]. 金属学报, 1987, 23(3): 257-261.
, , , . ELECTRODE PROCESS OF ELECTROLYTIC COATING OF Al IN FUSED NaCl-KCl SALT BATH[J]. Acta Metall Sin, 1987, 23(3): 257-261.

全文: PDF(350 KB)  
摘要: 作者在熔盐中研究了Al的氧化/还原电位,作图法求得为-1.122V,阳极溶解为Al→Al~(3+)+3e用稳态法研究阴极过程,对一些离子的析出电位、AlCl_4~-扩散系数和Al~(3+)还原反应动力学参数进行了测量和讨论。
Abstract:The standard oxidation/reduction potential of Al including its valence state in fused salt was examined, The anodic dissolution of Al can be shown by the equation Al→Al~3+3e. The standard oxidation/reduction potential of Al in fused salt is-1.122V as obtained by graphical method. Cathodic process has been investigated by means of steady state method. Separate potentials of some ions, the coefficient of diffusion ,of AlCl_4~- ion and kinetic constants of Al ion reduction have been meastured and discussed.
收稿日期: 1987-03-18     
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