金属学报  1979, Vol. 15 Issue (1): 85-93

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二元复合氧化物的稳定性规律

陈念贻;温元凯

中国科学院上海冶金研究所;中国科学技术大学

ON THE STABILITY OF BINARY COMPLEX OXIDES

Chen Nianyi;Wen Yuankai Shanghai Institute of Metallurgy; Academia Sinica University of Science and Technology of china

陈念贻;温元凯. 二元复合氧化物的稳定性规律[J]. 金属学报, 1979, 15(1): 85-93.
, . ON THE STABILITY OF BINARY COMPLEX OXIDES[J]. Acta Metall Sin, 1979, 15(1): 85-93.

摘要 参考文献 相关文章 Metrics 全文: PDF(479 KB)   摘要: 本文采用键参数函数方法,总结二元复合氧化物稳定性的规律。研究表明:离子键型复合氧化物的生成热,主要与离子半径和价数有关。具有部分共价性的复合氧化物的生成热和热力学稳定性,除上述因素外,还与失屏参数有关。 Abstract：Factors concerning with the stability of binary complex oxides has been stu-died. For complex oxides with ionic bonds,the main factors determining the heatof formation of such oxides appear to be the relevant ionic radius and the va-lency of the component elements. For oxides with partial covalency, however, thescreening parameter proposed in this paper may also be important in addition tothe factors mentioned above. 收稿日期: 1979-01-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 陈念贻 温元凯 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1979/V15/I1/85 [1] Erdos, E., Collect. Czech. Chem. Commun., 27 (1962) , 1428． [2] Schwitzgebel, K. et al., J. Chem. Eng. Data, 16 (1971) , 418． [3] Капустниский:络合物热化学(中译本),科学出版社,北京,1963． [4] Thilo, E. et al., Z. Anorg. Allg. Chem., 303 (1960) , 90． [5] 陈念贻,中国科学,(1974) ,№6,580;(1975) ,№ 4,399． [6] 陈念贻,金属学报,11(1974) ,№ 2,154． [7] 1963． [8] 陈念贻,键参数函数及其应用,科学出版社,北京,1976．W No related articles found! Viewed Full text Abstract Cited   Shared      Discussed