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金属学报  1966, Vol. 9 Issue (2): 148-157    
  论文 本期目录 | 过刊浏览 |
熔盐溶液的统计理论——第三部分 三元同离子系的相平衡
陈念贻;张桂成
中国科学院冶金研究所;中国科学院冶金研究所
STATISTICAL THEORY OF MOLTEN SALT SOLUTIONS Ⅲ. PHASE EQUILIBRIUM OF TERNARY HOMO-IONIC SYSTEMS
CH'N NIAN-YI; CHANG KUI-CH'NG (Instiute of Metallurgy; Academia Sinica)
引用本文:

陈念贻;张桂成. 熔盐溶液的统计理论——第三部分 三元同离子系的相平衡[J]. 金属学报, 1966, 9(2): 148-157.
, . STATISTICAL THEORY OF MOLTEN SALT SOLUTIONS Ⅲ. PHASE EQUILIBRIUM OF TERNARY HOMO-IONIC SYSTEMS[J]. Acta Metall Sin, 1966, 9(2): 148-157.

全文: PDF(719 KB)  
摘要: 根据我们以前提出的熔盐溶液的统计模型,和零级近似规则溶液理论,导出了AB-AC-AD型和A_2B-AC-AD型三元熔盐相图的液相面方程式。计算结果用若干三元相图进行了验证,结果符合较好。对其他类型的三元同离子系相图,则讨论了溶解能参数和相图几何特征的关系。
Abstract:From a statistical model of molten salt solutions, suggested in Part Ⅰ, two equations for the liquidus surfaces of the phase diagrams of AB-AC-AD and A_2B-AC-AD types were derived. The results of calculation were compared with the experimental data of many ternary phase diagrams, with good agreement, For the ternary homo-ionic Systems of other types, some relations between the geometric characteristics of the phase diagrams and the energetic parameters of solution were discussed.
收稿日期: 1966-02-18     
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