金属学报  1966, Vol. 9 Issue (2): 127-141

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高炉型渣脫硫的离子理論

魏寿崑

北京钢铁学院

THE IONIZATION THEORY OF DESULPHURIZATION WITH THE BLAST-FURNACE-TYPE SLAGS

WEI SHOU-KUN (Peking Institute oF Ferrous Metallurgy)

魏寿崑. 高炉型渣脫硫的离子理論[J]. 金属学报, 1966, 9(2): 127-141.
. THE IONIZATION THEORY OF DESULPHURIZATION WITH THE BLAST-FURNACE-TYPE SLAGS[J]. Acta Metall Sin, 1966, 9(2): 127-141.

摘要 参考文献 相关文章 Metrics 全文: PDF(1071 KB)   摘要: 根据新提出的碱度指标,对低碱度高炉型渣的离子结构作了假定。利用前文提出的、适用于各种碱性炼钢型渣的硫分配比公式: (％S)/[％S]=32L_Sf_S/γ_(Fe~(2+))γ_(S~(2-))·(∑n+∑n-)/n_(FeO)对Hatch和Chipman,Taylor和Stobo以及等的饱和碳铁液和高炉型渣平衡实验数据进行处理分析,得出: Igγ_(Fe~(2+))γ_(S~(2-))=-53.5 N_(O~(2-))+2.12。进一步计算证明了该硫分配比公式也适用于一般的低碱度渣。对碱性炼钢型渣适用的、关于FeO含量对脱硫作用的规律证明了也适用于低碱度渣。将f_S与(％S)/[％S]合并考虑,则(％S)/α_S基本上不受温度和铁液成分的影响。 Abstract：In a previous paper, it has been ascertained by the same author, that the sulphurdistribution-ratio formula, based on the complete-ionization theory of slag constitution and with the introduction of activity coefficients,(％S)/[％S]=32L_sf_s/(γ_(Fe~(2+))+γ_(S~(2-))·(∑n+∑n-)/n_(FeO) is adaptable to different kinds of basic steel-making slags, and could explain unanimously the different controversial arguments as regards the effect of FeO upon desulphurization. It is the purpose of this paper to show that the same formula might equally well be applicable to the acid or less basic blast-furnace-type slags, and to try to work out a tentative method of calculation. With this view in mind, according to the "basicity index" (∑b-2n_(Al_2O_3))/(n_(SiO_2)-n_(Al_2O_3)) newly proposed, the following acid radicals have been assumed to be present in the blast-furnace-type slags: SiO_~(4-), Si_2O_7~(6-), Si_3O_9~(6-), Al_2SiO_7~(4-), Al_2Si_2O_8~(2-) and AlO_3~(3-). Elaboration of the experimental data of Hatch and Chipman, Taylor and Stobo, as well as and others gave the following empirical relation:logγ_(Fe~(2+))γ_(S~(2-))=-53.5 No~(2-)+2.12. With this relation and the above formula, evaluation of the sulphur-distribution-ratio of the basic cupola for the low-basicity practice gave values practically in good agreement with those found in practice. Further calculation has shown that the effects of the FeO-content of the less basic slag upon desulphurization follow the same regularity as those of the basic slags. Thus the above-given sulphur-distribution-ratio formula might be considered as a most general and universal formula, which holds true for the sulphur-distribution between molten iron with any carbon content, and slags with either low or high FeO-content, as well as slags with either high basicity for the steel-making slags or low basicity for the blast-furnace-type slags. Furthermore, the (%S)/αs value as calculated is found to be practically independent of temperature as well as the composition of the molten iron. 收稿日期: 1966-02-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 魏寿崑 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1966/V9/I2/127 [1] 魏寿崑:金属学报,1964,7,157． [2] #12 [3] #12 [4] Hatch, G. G., Chipman, J.: Trans. AIME,, 1949, 185, 274, 831． [5] Filer, E. W., Darken, L. S.: Trans. AIME, 1952, 194, 253． [6] Grant, N. J., Kalling, U., Chipman, J.: Trans. AIME, 1951, 191, 666． [7] Grant, N. J., Troili, O., Chipman, J.: Trans. AIME, 1951, 191, 672． [8] Taylor, J., Stobo, J. J.: J. Iron Steel Inst. (London), 1954, 178, 360． [9] #12 [10] Schenck, H., Frohberg, M. G., Gammal, T. El.: Arch. Eisenhuttenw., 1960, 31, 11． [11] Schenck, H., Fohberg, M. G., Gammal, T. El.: Arch. Eisenhuttenw., 1960, 31, 471． [12] Schenck, H.. Frohberg, M. G., Gammal, T. El.: Arch. Eisenhuttenw,., 1961, 32, 63． [13] Schenck. H., Frohberg, M. G., Gammal, T. El.: Arch. E, isenhuttenw., 1962, 33, 589． [14] 邹元爔:金属学报,1956,1,127,143． [15] #12 [16] Kalyanram, M. R., MacFarlane, T. G., Bell, H. B.: J. Iron Steel Inst. (London), 1960． , 195, 58． [17] Giedroyc, V., McPhail, A. N., Mitckell, J. G.: J. Iron Steel Inst. (London), 1964, 202, 11． [18] Frohberg. M. G., Arch. Eisenhuttenw., 1961, 32, 597． [19] #12 [20] Gokcen, N. A.: Trans. AIME., 1956, 206, 1558． [21] AIME: Electric Furnace Steelmaking (Interscience, 1963) , vol. 2, p. 133-134． [22] Bockris, J. O'M.. Kitchener, J. A., Ignatowicz, S. et al.: Trans. Faraday Soc., 1952, 48, 75． [23] Bockris, J. O'M., Mackenzie, J. D., Kitchener, J. A.: Trans. Faraday Soc.. 1955, 51, 1734． [24] Bockris, J. O'M., Tomlinson, J. W., White, J. L.: Trans. Faraday Soc,, 1956, 52, 299． [25] #12 [26] Sherman, C. W., Chipman, J.: Trans. AIME, 1952, 194, 597． [27] Morris, J. P., Buehl, R. C.: Trans. AIME, 1950, 188, 317; 另见文献 [21] , vol. 2, p. 122． [28] AIME: Electric Furnace Steelmaking, (Intersscience, 1963) , Vol. 2． p. 455 (Tab. 22-12) . [29] 上海市冶金工业局中心试验室、中国科学院冶金陶瓷研究所:全国转炉会议资料汇编,(上海科技出版社,1959年),第1辑,28-78页. [30] Carter, S. F.: Trans. Am. Foundrymen's Soc., 1953, 61, 52． [31] 参阅文献[1] .x No related articles found! Viewed Full text Abstract Cited   Shared      Discussed