金属学报  1965, Vol. 8 Issue (2): 177-186

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二元系中杂质元素分布系数和相平衡图间的经验关系

王渭源

中国科学院冶金研究所

AN EMPIRICAL RELATION BETWEEN THE DISTRIBUTION COEFFICIENT OF IMPURITIES IN BINARY ALLOYS AND THE PHASE DIAGRAM

WANG WEI-YUAN Institute of Metallurgy; Academia Sinica

王渭源. 二元系中杂质元素分布系数和相平衡图间的经验关系[J]. 金属学报, 1965, 8(2): 177-186.
. AN EMPIRICAL RELATION BETWEEN THE DISTRIBUTION COEFFICIENT OF IMPURITIES IN BINARY ALLOYS AND THE PHASE DIAGRAM[J]. Acta Metall Sin, 1965, 8(2): 177-186.

摘要 参考文献 相关文章 Metrics 全文: PDF(704 KB)   摘要: 在Ge或Si和杂质元素组成的二元系中,及Au-Bi,Au-Tl,Ag-Bi,Ag-Pb,Ag-Tl(后一元素表示杂质)中,发现杂质元素分布系数K_B的对数和液相线上组分A的开方浓度。x_(A,L)~(1/2)间有直线关系。据此外推求得的Ge或Si(IV族)中熔点下分布系数K_B~o和实验结果相当符合,也求得了Au,Ag,Cu(Ⅰ族),Mg(Ⅱ族),Al(Ⅲ族)中某些杂质的K_B~o。在这些系统中,发现如Fischler在Ge或Si中所指出的那样,K_B~o和杂质元素的最大固溶度之间也有简单的经验关系。 Abstract：A linear relation has been obtained between the logarithm of the distribution co-efficient of impurities logK_B and the square root of liquidus composition for componentA x_(A, L)~(1/2). in binary systems of Ge or Si with impurities. This relationship hasbeen found to be also applicable to Au-Bi, Au-Tl, Ag-Bi, Ag-Pb and Ag-Tl systems,where the second element represents the impurity. The distribution coefficients at themelting point (K_B~o) of impurities in Ge or Si obtained by extrapolating to zero concentra-tion are in reasonable agreement with the experimental values. Besides, the values K_B~oof certain impurities in Au, Ag, Cu (from group I), Mg (from group II) and Al (fromgroup III) have been calculated. It is shown that in these systems a simple correlationexists between K_B~o and the maximum molar solid solubility of impurities, just like thatfound earlier by Fischler in the binary systems of Ge or Si. 收稿日期: 1965-02-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王渭源 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1965/V8/I2/177 [1] Trumbore, F. A.: Bell System Tech. J., 1960, 39, 205． [2] Thurmond, C. D., Kowalchik, M.: Bell System Tech. J., 1960, 39, 169． [3] Hansen, M.: Constitution of Binary Alloys, (McGraw-Hill, 1958) , 有关各图. [4] Fischler, S.: J. Appl. Phys., 1962, 33, 1615． [5] Thurmond, C. D., Struthers, J. D.: J. Phys. Chem., 1953, 57, 831． [6] Hall, R. N.: J. Phys. Chem. Solids, 1957, 3, 63． [7] Thurmond, C. D.: Semi-conductors, ed. N. B. Hanny, (Reinhold, 1959) , p. 145． [8] Thurmond, C. D.: Metallurgical Society Conferences, Properties of Elemental and Compound Semiconductors, ed. H. C. Gatos, (Interscience, 1960) , p. 121． [9] Raub, E., Engel, A.: Metallforschung 1946, 1, 76． [10] Trumbore, F. A., Isenberg, C. R., Porbansky, E. M.: J. Phys. Chem. Solids, 1959, 9, 60． [11] Trumbore, F. A., Porbansky, E. M., Tartaglia, A. A.: J. Phys. Chem. Solids, 1959, 11, 239． [12] Thurmond, C. D., Trumbore, F. A., Kowalchik, M.: J. Chem. Phys., 1956, 25, 799L. [13] Tolmie, E. D., Robins, D. A.: J. Inst. Metals, 1956--57, 85, 171． [14] Yue, A. S., Clark, J. B.: Trans. AIME, 1958, 212, 881． [15] Yue, A. S., Clark, J. B.: Trans. AIME, 1960, 218, 55． [16] #12 [17] Albert, P., Montariol, F., Reich, R. et al.: Radioisotope Conference, ed. J. E. Johnson, (Butterworths, 1954) , vol. 2, p. 75． [18] Burton, J. A., Prim, R. C., Slichter, W. P.: J. Chem. Phys., 1953, 21, 1987． [19] Kubaschewski, O., Evans, E. LL.: Metallurgical Thermochemistry, 3rd ed., (Pergamon, 1958) , p. 286, 292． No related articles found! Viewed Full text Abstract Cited   Shared      Discussed