Research paper

Enhanced Mechanical Properties and Thermal Stability Mechanism of a High Solid Solution Al-Mg Alloy Processed by Cryogenic High-Reduction Hard-Plate Rolling

  • TIAN Teng ,
  • ZHA Min ,
  • YIN Haoliang ,
  • HUA Zhenming ,
  • JIA Hailong ,
  • WANG Huiyuan
Expand
  • 1 Key Laboratory of Automobile Materials of Ministry of Education, School of Materials Science and Engineering, Jilin University, Changchun 130025, China
    2 State Key Laboratory of Super Hard Materials, Jilin University, Changchun 130012, China
    3 International Center of Future Science, Jilin University, Changchun 130012, China
ZHA Min, professor, Tel:(0431)85094699, E-mail: minzha@jlu.edu.cn;
WANG Huiyuan, professor, Tel:(0431)85095415, E-mail: wanghuiyuan@jlu.edu.cn

Received date: 2022-05-12

  Revised date: 2022-11-18

  Online published: 2022-12-06

Supported by

National Natural Science Foundation of China(51922048);National Natural Science Foundation of China(51625402);National Natural Science Foundation of China(51790483)

Abstract

Al-Mg series alloys are highly desirable for structural applications, owing to their high specific strength, good formability, and excellent corrosion resistance. However, high-strength Al-Mg alloys prepared via severe plastic deformation generally exhibit poor thermal stability, which is caused by the high-density grain boundaries (GBs). Achieving simultaneous high strength and thermal stability in binary Al-Mg alloys remains a challenge. In this study, Al-9Mg alloys with a combination of high strength (~597 MPa), decent elongation (~7.7%), and enhanced thermal stability were developed via cryogenic high-reduction hard-plate rolling (CHR-HPR). The effects of solute Mg content on the microstructure evolution and mechanical properties of CHR-HPR Al-Mg alloys were systematically investigated using EBSD, TEM, microhardness measurements, and tensile tests. The high yield strength is derived from high-density dislocations and low-angle GBs promoted via the high content of solute Mg atoms and low deformation temperature. In addition to the positive roles of Mg atoms and low deformation temperature on work-hardening ability, the simultaneous improvement in the ultimate tensile strength and ductility of CHR-HPR Al-Mg alloys with increasing solute Mg content is partially attributed to the enhanced work hardening induced via the dynamic strain aging. Furthermore, the recrystallization temperature of the CHR-HPR Al-Mg alloys gradually increased with increasing solute Mg content, and the recrystallization temperature of CHR-HPR Al-9Mg could reach 400oC. The enhanced thermal stability of CHR-HPR Al-9Mg alloy is due to the high content Mg solute atoms, which strongly retard recovery and recrystallization by dragging dislocations and pinning GBs.

Cite this article

TIAN Teng , ZHA Min , YIN Haoliang , HUA Zhenming , JIA Hailong , WANG Huiyuan . Enhanced Mechanical Properties and Thermal Stability Mechanism of a High Solid Solution Al-Mg Alloy Processed by Cryogenic High-Reduction Hard-Plate Rolling[J]. Acta Metall Sin, 2024 , 60(4) : 473 -484 . DOI: 10.11900/0412.1961.2022.00239

References

1 Zha M, Zhang H M, Jia H L, et al. Prominent role of multi-scale microstructural heterogeneities on superplastic deformation of a high solid solution Al-7Mg alloy[J]. Int. J. Plast., 2021, 146: 103108
2 Tang Y P, Goto W, Hirosawa S, et al. Concurrent strengthening of ultrafine-grained age-hardenable Al-Mg alloy by means of high-pressure torsion and spinodal decomposition[J]. Acta Mater., 2017, 131: 57
3 Yuan T, Zhao X H, Jiang X Q, et al. Mechanism of grain refinement of pulse current assisted plasma arc welded Al-Mg alloy[J]. Acta Metall. Sin., 2024, 60: 323
  袁 涛, 赵晓虎, 蒋晓青 等. 脉冲电流辅助等离子弧焊Al-Mg合金晶粒细化机理[J]. 金属学报, 2024, 60: 323
4 Zha M, Zhang H M, Meng X T, et al. Stabilizing a severely deformed Al-7Mg alloy with a multimodal grain structure via Mg solute segregation[J]. J. Mater. Sci. Technol., 2021, 89: 141
5 Jang D H, Park Y B, Kim W J. Significant strengthening in superlight Al-Mg alloy with an exceptionally large amount of Mg (13?wt%) after cold rolling[J]. Mater. Sci. Eng., 2019, A744: 36
6 Morishige T, Hirata T, Uesugi T, et al. Effect of Mg content on the minimum grain size of Al-Mg alloys obtained by friction stir processing[J]. Scr. Mater., 2011, 64: 355
7 Sun J X, Yang K, Wang Q Y, et al. Microstructure and mechanical properties of 5356 aluminum alloy fabricated by TIG arc additive manufacturing[J]. Acta Metall. Sin., 2021, 57: 665
  孙佳孝, 杨 可, 王秋雨 等. 5356铝合金TIG电弧增材制造组织与力学性能[J]. 金属学报, 2021, 57: 665
8 Zha M, Li Y J, Mathiesen R H, et al. Microstructure evolution and mechanical behavior of a binary Al-7Mg alloy processed by equal-channel angular pressing[J]. Acta Mater., 2015, 84: 42
9 Liu Y, Liu M P, Chen X F, et al. Effect of Mg on microstructure and mechanical properties of Al-Mg alloys produced by high pressure torsion[J]. Scr. Mater., 2019, 159: 137
10 Ruppert M, Schunk C, Hausmann D, et al. Global and local strain rate sensitivity of bimodal Al-laminates produced by accumulative roll bonding[J]. Acta Mater., 2016, 103: 643
11 Luo X, Feng Z Q, Yu T B, et al. Transitions in mechanical behavior and in deformation mechanisms enhance the strength and ductility of Mg-3Gd[J]. Acta Mater., 2020, 183: 398
12 Konkova T, Mironov S, Korznikov A, et al. Microstructural response of pure copper to cryogenic rolling[J]. Acta Mater., 2010, 58: 5262
13 Wang Y M, Chen M W, Zhou F H, et al. High tensile ductility in a nanostructured metal[J]. Nature, 2002, 419: 912
14 Zha M, Li Y J, Mathiesen R H, et al. High ductility bulk nanostructured Al-Mg binary alloy processed by equal channel angular pressing and inter-pass annealing[J]. Scr. Mater., 2015, 105: 22
15 Krymskiy S, Sitdikov O, Avtokratova E, et al. 2024 aluminum alloy ultrahigh-strength sheet due to two-level nanostructuring under cryorolling and heat treatment[J]. Trans. Nonferrous Met. Soc. China, 2020, 30: 14
16 Kumar V, Kumar D. Investigation of tensile behaviour of cryorolled and room temperature rolled 6082 Al alloy[J]. Mater. Sci. Eng., 2017, A691: 211
17 Zhang H M, Zha M, Jia H L, et al. Influences of the Al3Sc particle content on the evolution of bimodal grain structure and mechanical properties of Al-Mg-Sc alloys processed by hard-plate rolling[J]. Mater. Sci. Eng., 2021, A802: 140451
18 Zha M, Meng X T, Zhang H M, et al. High strength and ductile high solid solution Al-Mg alloy processed by a novel hard-plate rolling route[J]. J. Alloys Compd., 2017, 728: 872
19 Zha M, Liang J W, Xing H, et al. Spheroiding and refining of coarse CaMgSn phase in Mg-Al-Sn-Ca alloys for simultaneously improved strength and ductility via sub-rapid solidification and controlled rolling[J]. Mater. Sci. Eng., 2022, A834: 142598
20 Li Y K, Zha M, Jia H L, et al. Tailoring bimodal grain structure of Mg-9Al-1Zn alloy for strength-ductility synergy: Co-regulating effect from coarse Al2Y and submicron Mg17Al12 particles[J]. J. Magnes. Alloy., 2021, 9: 1556
21 Li Y K, Zha M, Rong J, et al. Effect of large thickness-reduction on microstructure evolution and tensile properties of Mg-9Al-1Zn alloy processed by hard-plate rolling[J]. J. Mater. Sci. Technol., 2021, 88: 215
22 Jin Z Z, Zha M, Jia H L, et al. Balancing the strength and ductility of Mg-6Zn-0.2Ca alloy via sub-rapid solidification combined with hard-plate rolling[J]. J. Mater. Sci. Technol., 2021, 81: 219
23 Zhang H, Zha M, Tian T, et al. Prominent role of high-volume fraction Mg17Al12 dynamic precipitations on multimodal microstructure formation and strength-ductility synergy of Mg-Al-Zn alloys processed by hard-plate rolling (HPR)[J]. Mater. Sci. Eng., 2021, A808: 140920
24 Zhou F, Liao X Z, Zhu Y T, et al. Microstructural evolution during recovery and recrystallization of a nanocrystalline Al-Mg alloy prepared by cryogenic ball milling[J]. Acta Mater., 2003, 51: 2777
25 Alyani A, Kazeminezhad M. Annealing behavior of aluminum after low-temperature severe plastic deformation[J]. Mater. Sci. Eng., 2021, A824: 141810
26 Dhal A, Panigrahi S K, Shunmugam M S. Insight into the microstructural evolution during cryo-severe plastic deformation and post-deformation annealing of aluminum and its alloys[J]. J. Alloys Compd., 2017, 726: 1205
27 Gao Y H, Liu G, Sun J. Recent progress in high-temperature resistant aluminum-based alloys: Microstructural design and precipitation strategy[J]. Acta Metall. Sin., 2021, 57: 129
  高一涵, 刘 刚, 孙 军. 耐热铝基合金研究进展: 微观组织设计与析出策略[J]. 金属学报, 2021, 57: 129
28 Hasegawa H, Komura S, Utsunomiya A, et al. Thermal stability of ultrafine-grained aluminum in the presence of Mg and Zr additions[J]. Mater. Sci. Eng., 1999, A265: 188
29 Hayes J S, Keyte R, Prangnell P B. Effect of grain size on tensile behaviour of a submicron grained Al-3wt%-Mg alloy produced by severe deformation[J]. Mater. Sci. Technol., 2000, 16: 1259
30 Zha M, Meng X T, Yu Z Y, et al. Enhancing thermal stability of binary Al-Mg alloys by tailoring grain orientations using a high solute Mg content[J]. Metall. Mater. Trans., 2019, 50A: 5264
31 Jin S B, Tao N R, Marthinsen K, et al. Deformation of an Al-7Mg alloy with extensive structural micro-segregations during dynamic plastic deformation[J]. Mater. Sci. Eng., 2015, A628: 160
32 Han B S, Wei L J, Xu Y J, et al. Effect of pre-deformation on microstructure and mechanical properties of ultra-high strength Al-Zn-Mg-Cu alloy after ageing treatment[J]. Acta Metall. Sin., 2020, 56: 1007
  韩宝帅, 魏立军, 徐严谨 等. 预变形对超高强Al-Zn-Mg-Cu合金时效组织与力学性能的影响[J]. 金属学报, 2020, 56: 1007
33 Kreyca J, Kozeschnik E. State parameter-based constitutive modelling of stress strain curves in Al-Mg solid solutions[J]. Int. J. Plast., 2018, 103: 67
34 Fu S H, Cheng T, Zhang Q C, et al. Two mechanisms for the normal and inverse behaviors of the critical strain for the Portevin-Le Chatelier effect[J]. Acta Mater., 2012, 60: 6650
35 Jobba M, Mishra R K, Niewczas M. Flow stress and work-hardening behaviour of Al-Mg binary alloys[J]. Int. J. Plast., 2015, 65: 43
36 Ma K K, Wen H M, Hu T, et al. Mechanical behavior and strengthening mechanisms in ultrafine grain precipitation-strengthened aluminum alloy[J]. Acta Mater., 2014, 62: 141
37 Pan H C, Kang R, Li J R, et al. Mechanistic investigation of a low-alloy Mg-Ca-based extrusion alloy with high strength-ductility synergy[J]. Acta Mater., 2020, 186: 278
38 Hansen N. Hall-Petch relation and boundary strengthening[J]. Scr. Mater., 2004, 51: 801
39 Valiev R Z, Enikeev N A, Murashkin M Y, et al. On the origin of the extremely high strength of ultrafine-grained Al alloys produced by severe plastic deformation[J]. Scr. Mater., 2010, 63: 949
40 Liu G, Zhang P, Yang C, et al. Aluminum alloys: Solute atom clusters and their strengthening[J]. Acta Metall. Sin., 2021, 57: 1484
  刘 刚, 张 鹏, 杨 冲 等. 铝合金中的溶质原子团簇及其强韧化[J]. 金属学报, 2021, 57: 1484
41 Chen Y J, Roven H J, Gireesh S S, et al. Quantitative study of grain refinement in Al-Mg alloy processed by equal channel angular pressing at cryogenic temperature[J]. Mater. Lett., 2011, 65: 3472
Outlines

/