Overview

Strengthening-Toughening Mechanism and Mechanical Properties of Span-Scale Heterostructure High-Entropy Alloy

  • Zibing AN ,
  • Shengcheng MAO ,
  • Ze ZHANG ,
  • Xiaodong HAN
Expand
  • 1.Institute of Microstructure and Properties of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China
    2.Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310058, China
MAO Shengcheng, professor, Tel: (010)67396769, E-mail: scmao@bjut.edu.cn;

Received date: 2022-07-04

  Revised date: 2022-08-03

  Online published: 2022-08-30

Supported by

National Key Research and Development Program of China(2021YFA1200201);National Natural Science Foundation of China(52071003);National Natural Science Foundation of China(91860202);National Natural Science Foundation of China(51988101);Interdisciplinary Cooperation Project of Beijing Science and Technology Nova Program(Z211100002121170);Beijing Municipal Education Commission Project(PXM2020_014204_000021);Discipline Innovation and Talent Introduction Program in Colleges and Universities(DB18015)

Abstract

High-entropy alloys overcome the limitations posed by traditional alloys due to features such as high strength, toughness, high wear resistance, and corrosion resistance. These alloys are novel metallic materials with excellent application potential; however, typically an inverse relationship is observed between the strength and ductility of a metal, which includes high-entropy alloys. Therefore, the design and development of high entropy alloys with high strength and high ductility have become a limitation in current research. Recently, heterostructure design has achieved great success in strengthening and toughening traditional metallic materials. Heterostructured and high-entropy alloys has garnered much attention and research interest to realize the strength and toughness of high-entropy alloys with high strength and high ductility. This study reviews the existing design models for heterostructures from the heterostructure scale perspective. Furthermore, the effects of different heterostructures on the strengthening and toughening mechanism and mechanical properties were analyzed, and future microstructural designs with high strength and toughness were anticipated.

Cite this article

Zibing AN , Shengcheng MAO , Ze ZHANG , Xiaodong HAN . Strengthening-Toughening Mechanism and Mechanical Properties of Span-Scale Heterostructure High-Entropy Alloy[J]. Acta Metall Sin, 2022 , 58(11) : 1441 -1458 . DOI: 10.11900/0412.1961.2022.00322

References

1 Zherebtsov S, Salishchev G, Galeyev R, et al. Mechanical properties of Ti-6Al-4V titanium alloy with submicrocrystalline structure produced by severe plastic deformation [J]. Mater. Trans., 2005, 46: 2020
2 Chong Y, Zhang R P, Hooshmand M S, et al. Elimination of oxygen sensitivity in α-titanium by substitutional alloying with Al [J]. Nat. Commun., 2021, 12: 6158
3 Huskins E L, Cao B, Ramesh K T. Strengthening mechanisms in an Al-Mg alloy [J]. Mater. Sci. Eng., 2010, A527: 1292
4 Altıparmak S C, Yardley V A, Shi Z S, et al. Challenges in additive manufacturing of high-strength aluminium alloys and current developments in hybrid additive manufacturing [J]. Int. J. Lightweight Mater. Manuf., 2021, 4: 246
5 Wei Y J, Li Y Q, Zhu L C, et al. Evading the strength-ductility trade-off dilemma in steel through gradient hierarchical nanotwins [J]. Nat. Commun., 2014, 5: 3580
6 Yeh J W, Chen S K, Lin S J, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes [J]. Adv. Eng. Mater., 2004, 6: 299
7 Cantor B, Chang I T H, Knight P, et al. Microstructural development in equiatomic multicomponent alloys [J]. Mater. Sci. Eng., 2004, A375-377: 213
8 Yeh J W. Recent progress in high-entropy alloys [J]. Ann. Chim. Sci. Mat., 2006, 31: 633
9 Zhang W R, Liaw P K, Zhang Y. Science and technology in high-entropy alloys [J]. Sci. China Mater., 2018, 61: 2
10 George E P, Raabe D, Ritchie R O. High-entropy alloys [J]. Nat. Rev. Mater., 2019, 4: 515
11 Gludovatz B, Hohenwarter A, Catoor D, et al. A fracture-resistant high-entropy alloy for cryogenic applications [J]. Science, 2014, 345: 1153
12 Schuh B, Mendez-Martin F, Völker B, et al. Mechanical properties, microstructure and thermal stability of a nanocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation [J]. Acta Mater., 2015, 96: 258
13 Ding Z Y, Cao B X, Luan J H, et al. Synergistic effects of Al and Ti on the oxidation behaviour and mechanical properties of L12-strengthened FeCoCrNi high-entropy alloys [J]. Corros. Sci., 2021, 184: 109365
14 Geng Y S, Chen J, Tan H, et al. Vacuum tribological behaviors of CoCrFeNi high entropy alloy at elevated temperatures [J]. Wear, 2020, 456-457: 203368
15 Zhang Y, Zhou Y J, Lin J P, et al. Solid-solution phase formation rules for multi-component alloys [J]. Adv. Eng. Mater., 2008, 10: 534
16 Guo S, Ng C, Lu J, et al. Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys [J]. J. Appl. Phys., 2011, 109: 103505
17 Oh H S, Kim S J, Odbadrakh K, et al. Engineering atomic-level complexity in high-entropy and complex concentrated alloys [J]. Nat. Commun., 2019, 10: 2090
18 Zhou Z Q, Zhou Y J, He Q F, et al. Machine learning guided appraisal and exploration of phase design for high entropy alloys [J]. npj Comput. Mater., 2019, 5: 128
19 Wang Z J, Huang Y H, Yang Y, et al. Atomic-size effect and solid solubility of multicomponent alloys [J]. Scr. Mater., 2015, 94: 28
20 Senkov O N, Scott J M, Senkova S V, et al. Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy [J]. J. Alloys Compd., 2011, 509: 6043
21 Senkov O N, Wilks G B, Scott J M, et al. Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high entropy alloys [J]. Intermetallics, 2011, 19: 698
22 Huang H L, Wu Y, He J Y, et al. Phase-transformation ductilization of brittle high-entropy alloys via metastability engineering [J]. Adv. Mater., 2017, 29: 1701678
23 Wu Z, Bei H, Pharr G M, et al. Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures [J]. Acta Mater., 2014, 81: 428
24 Rao J C, Diao H Y, Ocelík V, et al. Secondary phases in Al x CoCrFeNi high-entropy alloys: An in-situ TEM heating study and thermodynamic appraisal [J]. Acta Mater., 2017, 131: 206
25 Park J M, Yang D C, Kim H J, et al. Ultra-strong and strain-hardenable ultrafine-grained medium-entropy alloy via enhanced grain-boundary strengthening [J]. Mater. Res. Lett., 2021, 9: 315
26 Gwalani B, Soni V, Lee M, et al. Optimizing the coupled effects of Hall-Petch and precipitation strengthening in a Al0.3CoCrFeNi high entropy alloy [J]. Mater. Des., 2017, 121: 254
27 He Y X, Yang H X, Zhao C D, et al. Enhancing mechanical properties of Al0.25CoCrFeNi high-entropy alloy via cold rolling and subsequent annealing [J]. J. Alloys Compd., 2020, 830: 154645
28 He F, Chen D, Han B, et al. Design of D022 superlattice with superior strengthening effect in high entropy alloys [J]. Acta Mater., 2019, 167: 275
29 Chen D, He F, Han B, et al. Synergistic effect of Ti and Al on L12-phase design in CoCrFeNi-based high entropy alloys [J]. Intermetallics, 2019, 110: 106476
30 Liu W H, Lu Z P, He J Y, et al. Ductile CoCrFeNiMox high entropy alloys strengthened by hard intermetallic phases [J]. Acta Mater., 2016, 116: 332
31 Naeem M, He H Y, Harjo S, et al. Extremely high dislocation density and deformation pathway of CrMnFeCoNi high entropy alloy at ultralow temperature [J]. Scr. Mater., 2020, 188: 21
32 Deng Y, Tasan C C, Pradeep K G, et al. Design of a twinning-induced plasticity high entropy alloy [J]. Acta Mater., 2015, 94: 124
33 Li Z M, Pradeep K G, Deng Y, et al. Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off [J]. Nature, 2016, 534: 227
34 Yang T, Zhao Y L, Tong Y, et al. Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys [J]. Science, 2018, 362: 933
35 Shi P J, Li R G, Li Y, et al. Hierarchical crack buffering triples ductility in eutectic herringbone high-entropy alloys [J]. Science, 2021, 373: 912
36 Wei D X, Li X Q, Schönecker S, et al. Development of strong and ductile metastable face-centered cubic single-phase high-entropy alloys [J]. Acta Mater., 2019, 181: 318
37 Ma E, Wu X L. Tailoring heterogeneities in high-entropy alloys to promote strength-ductility synergy [J]. Nat. Commun., 2019, 10: 5623
38 Ding Q Q, Zhang Y, Chen X, et al. Tuning element distribution, structure and properties by composition in high-entropy alloys [J]. Nature, 2019, 574: 223
39 Chen X F, Wang Q, Cheng Z Y, et al. Direct observation of chemical short-range order in a medium-entropy alloy [J]. Nature, 2021, 592: 712
40 Wang J, Jiang P, Yuan F P, et al. Chemical medium-range order in a medium-entropy alloy [J]. Nat. Commun., 2022, 13: 1021
41 Pan Q S, Zhang L X, Feng R, et al. Gradient cell-structured high-entropy alloy with exceptional strength and ductility [J]. Science, 2021, 374: 984
42 An Z B, Mao S C, Liu Y N, et al. Hierarchical grain size and nanotwin gradient microstructure for improved mechanical properties of a non-equiatomic CoCrFeMnNi high-entropy alloy [J]. J. Mater. Sci. Technol., 2021, 92: 195
43 Zheng X Y, Xie W B, Zeng L F, et al. Achieving high strength and ductility in a heterogeneous-grain-structured CrCoNi alloy processed by cryorolling and subsequent short-annealing [J]. Mater. Sci. Eng., 2021, A821: 141610
44 Zhang C, MacDonald B E, Guo F W, et al. Cold-workable refractory complex concentrated alloys with tunable microstructure and good room-temperature tensile behavior [J]. Scr. Mater., 2020, 188: 16
45 Zhu Y T, Wu X L. Perspective on hetero-deformation induced (HDI) hardening and back stress [J]. Mater. Res. Lett., 2019, 7: 393
46 Yang M X, Yan D S, Yuan F P, et al. Dynamically reinforced heterogeneous grain structure prolongs ductility in a medium-entropy alloy with gigapascal yield strength [J]. Proc. Natl. Acad. Sci. USA, 2018, 115: 7224
47 Jang T J, Choi W S, Kim D W, et al. Shear band-driven precipitate dispersion for ultrastrong ductile medium-entropy alloys [J]. Nat. Commun., 2021, 12: 4703
48 Du X H, Li W P, Chang H T, et al. Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy [J]. Nat. Commun., 2020, 11: 2390
49 An Z B, Mao S C, Liu Y N, et al. A novel HfNbTaTiV high-entropy alloy of superior mechanical properties designed on the principle of maximum lattice distortion [J]. J. Mater. Sci. Technol., 2021, 79: 109
50 Lee C, Chou Y, Kim G, et al. Lattice-distortion-enhanced yield strength in a refractory high-entropy alloy [J]. Adv. Mater., 2020, 32: 2004029
51 Feng R, Feng B J, Gao M C, et al. Superior high-temperature strength in a supersaturated refractory high-entropy alloy [J]. Adv. Mater., 2021, 33: 2102401
52 Wu Y, Zhang F, Yuan X Y, et al. Short-range ordering and its effects on mechanical properties of high-entropy alloys [J]. J. Mater. Sci. Technol., 2021, 62: 214
53 Bu Y Q, Wu Y, Lei Z F, et al. Local chemical fluctuation mediated ductility in body-centered-cubic high-entropy alloys [J]. Mater. Today, 2021, 46: 28
54 Yin S, Ding J, Asta M, et al. Ab initio modeling of the role of local chemical short-range order on the Peierls potential of screw dislocations in body-centered cubic high-entropy alloys [J]. npj Comput. Mater., 2020, 6: 1
55 Hu Q, Guo S, Guo J L, et al. Effect of Mo on high-temperature strength of refractory complex concentrated alloys: A perspective of electronegativity difference [J]. J. Alloys Compd., 2022, 906: 164186
56 Lei Z F, Liu X J, Wu Y, et al. Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes [J]. Nature, 2018, 563: 546
57 Lilensten L, Couzinié J P, Perrière L, et al. Study of a bcc multi-principal element alloy: Tensile and simple shear properties and underlying deformation mechanisms [J]. Acta Mater., 2018, 142: 131
58 Antillon E, Woodward C, Rao S I, et al. Chemical short range order strengthening in a model FCC high entropy alloy [J]. Acta Mater., 2020, 190: 29
59 Fernández-Caballero A, Wróbel J S, Mummery P M, et al. Short-range order in high entropy alloys: Theoretical formulation and application to Mo-Nb-Ta-V-W system [J]. J. Phase Equilib. Diffus., 2017, 38: 391
60 Li Q J, Sheng H, Ma E. Strengthening in multi-principal element alloys with local-chemical-order roughened dislocation pathways [J]. Nat. Commun., 2019, 10: 3563
61 Fantin A, Lepore G O, Manzoni A M, et al. Short-range chemical order and local lattice distortion in a compositionally complex alloy [J]. Acta Mater., 2020, 193: 329
62 Jian W R, Xie Z C, Xu S Z, et al. Effects of lattice distortion and chemical short-range order on the mechanisms of deformation in medium entropy alloy CoCrNi [J]. Acta Mater., 2020, 199: 352
63 Kostiuchenko T, Ruban A V, Neugebauer J, et al. Short-range order in face-centered cubic VCoNi alloys [J]. Phys. Rev. Mater., 2020, 4: 113802
64 He Z F, Jia N, Yan H L, et al. Multi-heterostructure and mechanical properties of N-doped FeMnCoCr high entropy alloy [J]. Int. J. Plast., 2021, 139: 102965
65 Zhang R P, Zhao S T, Ding J, et al. Short-range order and its impact on the CrCoNi medium-entropy alloy [J]. Nature, 2020, 581: 283
66 Su I A, Tseng K K, Yeh J W, et al. Strengthening mechanisms and microstructural evolution of ductile refractory medium-entropy alloy Hf20Nb10Ti35Zr35 [J]. Scr. Mater., 2022, 206: 114225
67 Gerold V, Karnthaler H P. On the origin of planar slip in f.c.c. alloys [J]. Acta Metall., 1989, 37: 2177
68 Hamdi F, Asgari S. Influence of stacking fault energy and short-range ordering on dynamic recovery and work hardening behavior of copper alloys [J]. Scr. Mater., 2010, 62: 693
69 Cao B X, Zhao Y L, Yang T, et al. L12 -strengthened Co-rich alloys for high-temperature structural applications: A critical review [J]. Adv. Eng. Mater., 2021, 23: 2100453
70 Yang T, Cao B X, Zhang T L, et al. Chemically complex intermetallic alloys: A new frontier for innovative structural materials [J]. Mater. Today, 2022, 52: 161
71 Orowan E. Fracture and strength of solids [J]. Rep. Prog. Phys., 1949, 12: 185
72 Liang Y J, Wang L J, Wen Y R, et al. High-content ductile coherent nanoprecipitates achieve ultrastrong high-entropy alloys [J]. Nat. Commun., 2018, 9: 4063
73 An Z B, Mao S C, Yang T, et al. Spinodal-modulated solid solution delivers a strong and ductile refractory high-entropy alloy [J]. Mater. Horiz., 2021, 8: 948
74 Fan L, Yang T, Zhao Y L, et al. Ultrahigh strength and ductility in newly developed materials with coherent nanolamellar architectures [J]. Nat. Commun., 2020, 11: 6240
75 Zhou X L, Feng Z Q, Zhu L L, et al. High-pressure strengthening in ultrafine-grained metals [J]. Nature, 2020, 579: 67
76 Wu X L, Zhu Y T. Heterogeneous materials: A new class of materials with unprecedented mechanical properties [J]. Mater. Res. Lett., 2017, 5: 527
77 Ma E, Zhu T. Towards strength-ductility synergy through the design of heterogeneous nanostructures in metals [J]. Mater. Today, 2017, 20: 323
78 Wu X L, Jiang P, Chen L, et al. Extraordinary strain hardening by gradient structure [J]. Proc. Natl. Acad. Sci. USA, 2014, 111: 7197
79 Cheng Z, Zhou H F, Lu Q H, et al. Extra strengthening and work hardening in gradient nanotwinned metals [J]. Science, 2018, 362: eaau1925
80 Otto F, Hanold N L, George E P. Microstructural evolution after thermomechanical processing in an equiatomic, single-phase CoCrFeMnNi high-entropy alloy with special focus on twin boundaries [J]. Intermetallics, 2014, 54: 39
81 Wu S W, Wang G, Wang Q, et al. Enhancement of strength-ductility trade-off in a high-entropy alloy through a heterogeneous structure [J]. Acta Mater., 2019, 165: 444
82 Wang X, Li Y S, Zhang Q, et al. Gradient structured copper by rotationally accelerated shot peening [J]. J. Mater. Sci. Technol., 2017, 33: 758
83 Tao N R, Wang Z B, Tong W P, et al. An investigation of surface nanocrystallization mechanism in Fe induced by surface mechanical attrition treatment [J]. Acta Mater., 2002, 50: 4603
84 Hasan M N, Liu Y F, An X H, et al. Simultaneously enhancing strength and ductility of a high-entropy alloy via gradient hierarchical microstructures [J]. Int. J. Plast., 2019, 123: 178
85 Shi P J, Zhong Y B, Li Y, et al. Multistage work hardening assisted by multi-type twinning in ultrafine-grained heterostructural eutectic high-entropy alloys [J]. Mater. Today, 2020, 41: 62
86 Wang M L, Lu Y P, Wang T M, et al. A novel bulk eutectic high-entropy alloy with outstanding as-cast specific yield strengths at elevated temperatures [J]. Scr. Mater., 2021, 204: 114132
87 Xiong T, Zheng S J, Pang J Y, et al. High-strength and high-ductility AlCoCrFeNi2.1 eutectic high-entropy alloy achieved via precipitation strengthening in a heterogeneous structure [J]. Scr. Mater., 2020, 186: 336
88 Shi P J, Ren W L, Zheng T X, et al. Enhanced strength-ductility synergy in ultrafine-grained eutectic high-entropy alloys by inheriting microstructural lamellae [J]. Nat. Commun., 2019, 10: 489
89 Lu Y P, Dong Y, Guo S, et al. A promising new class of high-temperature alloys: Eutectic high-entropy alloys [J]. Sci. Rep., 2014, 4: 6200
90 Fu Z Q, Jiang L, Wardini J L, et al. A high-entropy alloy with hierarchical nanoprecipitates and ultrahigh strength [J]. Sci. Adv., 2018, 4: eaat8712
91 Jia Z Y, Zhang S Z, Huo J T, et al. Heterogeneous precipitation strengthened non-equiatomic NiCoFeAlTi medium entropy alloy with excellent mechanical properties [J]. Mater. Sci. Eng., 2022, A834: 142617
92 Qin S, Yang M X, Jiang P, et al. Designing structures with combined gradients of grain size and precipitation in high entropy alloys for simultaneous improvement of strength and ductility [J]. Acta Mater., 2022, 230: 117847
Outlines

/