Microstructure and Strength-Toughness of a Cu-Contained Maraging Stainless Steel

  • WANG Bin ,
  • NIU Mengchao ,
  • WANG Wei ,
  • JIANG Tao ,
  • LUAN Junhua ,
  • YANG Ke
Expand
  • 1Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou 450003, China
    2Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hong Kong 999077, China
    3Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    4AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China
    5Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong 999077, China

Received date: 2021-12-31

  Revised date: 2022-03-15

  Online published: 2022-05-30

Supported by

National Natural Science Foundation of China(51201160);Youth Innovation Promotion Association of Chinese Academy of Sciences(2017233)

Abstract

An increase in strength often leads to a decrease in the ductility and toughness of maraging stainless steels; this phenomenon is known as the strength-ductility/toughness trade-off dilemma in structural materials. Some studies have found that the introduction of submicro/nanometer-sized retained or reverted austenite could mitigate the strength-ductility/toughness trade-off of high-strength maraging stainless steels. In this work, a novel strategy to accelerate austenite reversion by Cu addition in a Fe-Ni-Mo-Co-Cr maraging stainless steel was studied. In addition, the aging behavior and its effects on the mechanical properties of a Cu-containing Fe-Cr-Co-Ni-Mo maraging stainless steel were systematically studied. Transmission electron microscope characterizations showed that Cu- and Mo-rich phases precipitated from the steel matrix in sequence during the aging process; more specifically, a part of Mo-rich phase nucleated at the Cu-rich phase and then grew. Moreover, along with the segregation of Cu and Ni, reverted austenite was formed gradually. With an increase in the aging time, the stability of the reverted austenite increased, resulting in a substantial increase in its toughness. After aging for 90 h, the yield and tensile strengths of the steel reached 1270 and 1495 MPa, respectively, and the impact energy and fracture toughness were 81 J and 102 MPa·m1/2, respectively, showing an excellent match of strength and toughness compared with commercial maraging stainless steels.

Cite this article

WANG Bin , NIU Mengchao , WANG Wei , JIANG Tao , LUAN Junhua , YANG Ke . Microstructure and Strength-Toughness of a Cu-Contained Maraging Stainless Steel[J]. Acta Metall Sin, 2023 , 59(5) : 636 -646 . DOI: 10.11900/0412.1961.2021.00599

References

1 Jiang S H, Wang H, Wu Y, et al. Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation[J]. Nature, 2017, 544: 460
2 H?ttestrand M, Nilsson J O, Stiller K, et al. Precipitation hardening in 12%Cr-9%Ni-4%Mo-2%Cu stainless steel[J]. Acta Mater., 2004, 52: 1023
3 Yang K, Niu M C, Tian J L, et al. Research and development of maraging stainless steel used for new generation landing gear[J]. Acta Metall. Sin., 2018, 54: 1567
  杨 柯, 牛梦超, 田家龙 等. 新一代飞机起落架用马氏体时效不锈钢的研究[J]. 金属学报, 2018, 54: 1567
4 Luo H W, Shen G H. Progress and perspective of ultra-high strength steels having high toughness[J]. Acta Metall. Sin., 2020, 56: 494
  罗海文, 沈国慧. 超高强高韧化钢的研究进展和展望[J]. 金属学报, 2020, 56: 494
5 Liu Z B, Liang J X, Su J, et al. Research and application progress in ultra-high strength stainless steel[J]. Acta Metall. Sin., 2020, 56: 549
  刘振宝, 梁剑雄, 苏 杰 等. 高强度不锈钢的研究及发展现状[J]. 金属学报, 2020, 56: 549
6 Dong H. Year 2020: 200th anniversary for alloy steel—Preword of special issue for alloy steel[J]. Acta Metall. Sin., 2020, 56: I
  董 瀚. 2020年: 合金钢200周年——“合金钢专刊”前言[J]. 金属学报, 2020, 56: I
7 Speer J, Matlock D K, De Cooman B C, et al. Carbon partitioning into austenite after martensite transformation[J]. Acta Mater., 2003, 51: 2611
8 Tian Y Q, Zhang H J, Chen L S, et al. Effect of alloy elements partitioning behavior on retained austenite and mechanical property in low carbon high strength steel[J]. Acta Metall. Sin., 2014, 50: 531
  田亚强, 张宏军, 陈连生 等. 低碳高强钢合金元素配分行为对残余奥氏体和力学性能的影响[J]. 金属学报, 2014, 50: 531
9 Kong H J, Yang T, Chen R, et al. Breaking the strength-ductility paradox in advanced nanostructured Fe-based alloys through combined Cu and Mn additions[J]. Scr. Mater., 2020, 186: 213
10 Li Y, Li W, Liu W Q, et al. The austenite reversion and co-precipitation behavior of an ultra-low carbon medium manganese quenching-partitioning-tempering steel[J]. Acta Mater., 2018, 146: 126
11 Cao H W, Luo X H, Zhan G F, et al. Effect of intercritical quenching on the microstructure and cryogenic mechanical properties of a 7 pct Ni steel[J]. Metall. Mater. Trans., 2017, 48A: 4403
12 Zhang H L, Sun M Y, Liu Y X, et al. Ultrafine-grained dual-phase maraging steel with high strength and excellent cryogenic toughness[J]. Acta Mater., 2021, 211: 116878
13 He Y, Yang K, Sha W. Microstructure and mechanical properties of a 2000 MPa grade Co-free maraging steel[J]. Metall. Mater. Trans., 2005, 36A: 2273
14 Raabe D, Ponge D, Dmitrieva O, et al. Nanoprecipitate-hardened 1.5 GPa steels with unexpected high ductility[J]. Scr. Mater., 2009, 60: 1141
15 Niu M C, Yang K, Luan J H, et al. Cu-assisted austenite reversion and enhanced TRIP effect in maraging stainless steels[J]. J. Mater. Sci. Technol., 2022, 104: 52
16 Seko A, Nishitani S R, Tanaka I, et al. First-principles calculation on free energy of precipitate nucleation[J]. Calphad, 2004, 28: 173
17 Liang J X, Liu Z B, Yang Z Y. Development and application of high strength stainless steel[J]. Aerosp. Mater. Technol., 2013, 43: 1
  梁剑雄, 刘振宝, 杨志勇. 高强不锈钢的发展与应用技术[J]. 宇航材料工艺, 2013, 43: 1
18 Kuehmann C, Tufts B, Trester P. Computational design for ultra high-strength alloy[J]. Adv. Mater. Process., 2008, 166: 37
19 Xiang S, Wang J P, Sun Y L, et al. Effect of ageing process on mechanical properties of martensite precipitation-hardening stainless steel[J]. Adv. Mater. Res., 2011, 146-147: 382
20 Couturier L, De Geuser F, Descoins M, et al. Evolution of the microstructure of a 15-5PH martensitic stainless steel during precipitation hardening heat treatment[J]. Mater. Des., 2016, 107: 416
21 Habibi-Bajguirani H R, Jenkins M L. High-resolution electron microscopy analysis of the structure of copper precipitates in a martensitic stainless steel of type PH 15-5[J]. Philos. Mag. Lett., 1996, 73: 155
22 Salje G, Feller-Kniepmeier M. The diffusion and solubility of copper in iron[J]. J. Appl. Phys., 48: 1833
23 Nitta H, Yamamoto T, Kanno R, et al. Diffusion of molybdenum in α-iron[J]. Acta Mater., 2002, 50: 4117
24 Cracknell A, Petch N J. Frictional forces on dislocation arrays at the lower yield point in iron[J]. Acta Metall., 1955, 3: 186
25 Han G, Xie Z J, Li Z Y, et al. Evolution of crystal structure of Cu precipitates in a low carbon steel[J]. Mater. Des., 2017, 135: 92
26 Niu M C, Zhou G, Wang W, et al. Precipitate evolution and strengthening behavior during aging process in a 2.5 GPa grade maraging steel[J]. Acta Mater., 2019, 179: 296
27 Kong H J, Xu C, Bu C C, et al. Hardening mechanisms and impact toughening of a high-strength steel containing low Ni and Cu additions[J]. Acta Mater., 2019, 172: 150
28 Fahr D. Stress- and strain-induced formation of martensite and its effects on strength and ductility of metastable austenitic stainless steels[J]. Metall. Mater. Trans., 1971, 2B: 1883
29 Jimenez-Melero E, Van Dijk N H, Zhao L, et al. Characterization of individual retained austenite grains and their stability in low-alloyed TRIP steels[J]. Acta Mater., 2007, 55: 6713
30 Lacroix G, Pardoen T, Jacques P J. The fracture toughness of TRIP-assisted multiphase steels[J]. Acta Mater., 2008, 56: 3900
31 Luo H W, Wang X H, Liu Z B, et al. Influence of refined hierarchical martensitic microstructures on yield strength and impact toughness of ultra-high strength stainless steel[J]. J. Mater. Sci. Technol., 2020, 51: 130
32 Shu D L. Mechanical Properties of Engineering Materials[M]. 3rd Ed., Beijing: China Machine Press, 2016: 73
  束德林. 工程材料力学性能[M]. 第3版, 北京: 机械工业出版社, 2016: 73
Outlines

/