Research paper

Effect of Y Element on the Properties of Cu-Al-Ni High Temperature Shape Memory Alloy

  • Xin ZHANG ,
  • Bo CUI ,
  • Bin SUN ,
  • Xu ZHAO ,
  • Xin ZHANG ,
  • Qingsuo LIU ,
  • Zhizhong DONG
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  • 1.School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
    2.Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China
    3.College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
    4.Beijing Tianyi Shangjia High-Tech Materials Co. Ltd., Beijing 102400, China
ZHANG Xin, associate professor, Tel: 18630878641, E-mail: zhangxin3510110@tjut.edu.cnDONG Zhizhong, professor, Tel: 13820371235, E-mail: zhizhong.dong@email.tjut.edu.cn

Received date: 2021-09-16

  Revised date: 2021-11-10

  Online published: 2021-12-09

Supported by

National Natural Science Foundation of China(52071236);Natural Science Foundation of Tianjin(18JCYBJC87000)

Abstract

Cu-Al-Ni alloys are not yet widely used due to issues related to their coarse grains, unacceptable plasticity, and poor thermal stability. Here, the physical and mechanical properties, as well as the corrosion behavior, of Cu-Al-Ni alloys doped with Y element (Cu-13Al-4Ni-xY (x = 0.2, 0.5, mass fraction, %)) were studied. XRD, OM, SEM, TEM, electronic universal testing machine, and electrochemical workstation were used to characterize the microstructures and measure the properties of the Cu-13Al-4Ni-xY alloys. The results showed that at room temperature, the microstructure of Cu-13Al-4Ni-xY alloys was mainly an 18R martensite matrix. The (Cu, Al, Ni)4Y second phase was characterized to have a hexagonal structure. The mechanical properties of the Cu-13Al-4Ni-xY alloys improved as the Y element content increased. For example, when the Y content was increased from 0% to 0.5%, the compressive fracture strain increased from 10.5% to 19.3% and the fracture strength increased from 580 to 1185 MPa. Additionally, the fracture type of the alloy changed from intergranular to transgranular with the addition of Y. Finally, the results from electrochemical experiments showed that the corrosion behavior of the alloys decreased slightly with the addition of Y.

Cite this article

Xin ZHANG , Bo CUI , Bin SUN , Xu ZHAO , Xin ZHANG , Qingsuo LIU , Zhizhong DONG . Effect of Y Element on the Properties of Cu-Al-Ni High Temperature Shape Memory Alloy[J]. Acta Metall Sin, 2022 , 58(8) : 1065 -1071 . DOI: 10.11900/0412.1961.2021.00400

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