Acta Metall Sin  1996, Vol. 32 Issue (2): 144-148    DOI:

Current Issue | Archive | Adv Search |

THERMODYNAMIC STABILITY OF COMPLEX OXIDE Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4)

XING Hianran; QIAO Zhiyu; WEI Shoukun(University of Science and Technology Beijing; Beijing 100083)(Manuscript received 1995-05-02; in revised form 1995-11-05)

XING Hianran; QIAO Zhiyu; WEI Shoukun(University of Science and Technology Beijing; Beijing 100083)(Manuscript received 1995-05-02; in revised form 1995-11-05). THERMODYNAMIC STABILITY OF COMPLEX OXIDE Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4). Acta Metall Sin, 1996, 32(2): 144-148.

Abstract References Related Articles Recommended Metrics Download:  PDF(352KB)  Export:  BibTeX | EndNote (RIS)       Abstract  An assembly for performing EMF measurements using a CaF2 single crystal as a solid state electrolyte has been constructed. From the EMF data, the standard Gibbs energies of formation of member oxides in the Sm-Ba-Cu-O system were calculated. It is found that the thermodynamic stability of the complex oxide Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4）decreases with the increase in the solid solubility x.(Correspondent: XING Xianran, associate professor-Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083.) Key words:  electromotive force (EMF)      thermodynamic stability      high temperature superconductor      Received:  18 February 1996      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1996/V32/I2/144 1RothRS．AdvCeramMater,1987;2:3032AsanoH,YokoyamaY．ModernPhysLettB,1988;2:5833JCPDSCard,6一399,19884QiaoZhiyu,XingXianran,YuanWenxia,WeiSoukun,ChenXiaolong,LiangJinkui,XieShishen.JAlloysCompounds,1993,202:775邢献然.北京科技大学博士论文,19936BarinI,KnackeO,KubachewskiO．Thermochemicalpropertiesofinorganicsubstancesandsupple-ment,Dusseldorf:Springer-Verleg,19777XingXianran,QiaoZhiyu,YuanWenxia,WeiSoukun,ChenXiaolong,RaoGuanghui,LiangJinkui．JMaterSciTech,1994;10:269 [1] BIAN Weimin ZHU Yimei ZHOU Lian. DETERMINATION OF SPACE GROUP OF INCOMMENSURATE MODULATION STRUCTURE PHASES IN Bi HIGH TEMPERATURE SUPERCONDUCTORS[J]. 金属学报, 2009, 45(6): 673-679. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed