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EVALUATION AND ANALYSIS OF THE ELECTROCHEMICAL CAPACITY OF METAL HYDRIDE ELECTRODE USING HYDROGEN STORAGE ALLOYS IN ALKALINE AQUEOUS SOLUTION |
JIANG Jianjun (Huazhong University of Science and Technology; Wuhan 430074); LEI YOngquan;SUN Dalin;WU Jing;WANG Qidong (Zhejiang University; Hangzhou 310027) |
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Cite this article:
JIANG Jianjun (Huazhong University of Science and Technology; Wuhan 430074); LEI YOngquan;SUN Dalin;WU Jing;WANG Qidong (Zhejiang University; Hangzhou 310027). EVALUATION AND ANALYSIS OF THE ELECTROCHEMICAL CAPACITY OF METAL HYDRIDE ELECTRODE USING HYDROGEN STORAGE ALLOYS IN ALKALINE AQUEOUS SOLUTION. Acta Metall Sin, 1997, 33(7): 729-736.
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Abstract To determinate an appropriate method measuring the performance of a metal hydride electrode, three different electrochemical apparatus were designed. The results showed that electrochemical capacity of hydride measured by a conventional three-electrode open cell was higher than that determined in a sandwiched and in a sealed Ni/MH test cell.The electrochemical capacity of a hydride electrode measured in a sandwiched Ni/MH cell was very close to that measured in a sealed test cell. In order to optimize the metal hydride electrode alloy and elevalute the discharge capacity of an alloy, the factors affecting the discharge process of an actual hydride electrode were examined theoretically and experimentally. It can be concluded that the electrochemical capacity of a hydride electrode depends not only on the intrinsic properties of a hydrogen storage alloy, but also on the electrode preparation method and its working environment.
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Received: 18 July 1997
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