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Acta Metall Sin  2004, Vol. 40 Issue (12): 1264-1268     DOI:
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Cr-O-N FILMS DEPOSITED BY ARC ION PLATING AS ACTIVE DIFFUSION BARRIERS
WANG Qimin; GUO Minghu; KE Peiling; SUN Chao; HUANG Rongfang; WEN Lishi
State Key Laboratory for Corrosion and Protection; Institute of Metal Research;
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WANG Qimin; GUO Minghu; KE Peiling; SUN Chao; HUANG Rongfang; WEN Lishi. Cr-O-N FILMS DEPOSITED BY ARC ION PLATING AS ACTIVE DIFFUSION BARRIERS. Acta Metall Sin, 2004, 40(12): 1264-1268 .

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Abstract  Cr-O-N films with different chemical composition were deposited using arc ion plating (AIP) between NiCoCrAlY coatings and the DSM11 substrate as diffusion barriers. The inhibition effects of the diffusion barriers on the interdiffusion of the alloy elements in the DSM11/Cr-O-N/NiCoCrAlY system were studied after exposured at 900 ℃ for 1400 h. The influences of the barriers on the oxidation kinetics were also investigated. The results indicate that the Cr-O-N layers can change into Al-rich oxide layers with active bonding with the coatings and the substrates during the high temperature exposure. The Al-rich oxide layers hindered the interdiffusion of the alloying elements between DSM11 substrate and NiCoCrAlY coating. Thus the Cr-O-N layers can act as active diffusion barrier. The O and N compositions in the Cr-O-N layer affect the continuity and density of the Al--rich oxide layers, and influence the inhibition effect of the diffusion barriers accordingly. All the Cr-O-N barriers decreased the weight gain of the NiCoCrAlY coatings at 900 ℃. The improvement extent of the Cr-O-N barriers on the oxidation behavior of the NiCoCrAlY coatings is corresponding with the inhibition capacity of the barriers.
Key words:  Cr-O-N      reactive diffusion barrier      arc ion plating (AIP)      
Received:  22 October 2003     
ZTFLH:  TG111.5  
  TG174.44  

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https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2004/V40/I12/1264

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[1] LU Xuyang, YU Daqian, JIANG Sumeng, LIU Shanchuan, GONG Jun, SUN Chao. HOT CORROSION BEHAVIOR OF A (NiCoCrAlYSiB+AlSiY) COMPOSITE COATING[J]. 金属学报, 2012, 48(4): 461-468.
[2] ;. The adhesive behaviour of NiCrAlY coatings with Cr-O-N diffusion barriers[J]. 金属学报, 2008, 44(7): 876-882 .
[3] WANG Qimin; WU Yingna; KE Peiling; JI Ailing; SUN Chao; HUANG Rongfang; WEN Lishi. HOT CORROSION BEHAVIOR OF Ni--Co--Cr--Al--Y--Si--B COATING DEPOSITED BY AIP[J]. 金属学报, 2004, 40(4): 399-403 .
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