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| APPLICATION OF THE SUB-REGULAR SOLUTION MODEL TO THE THERMODYNAMICAL ANALYSIS OF BlNARY EQUILIBRIUM DIAGRAMS |
| T'IEN TEH-CHENG;CHU HSI-HSIUNG Institute of Metal Research; Academia Sinica |
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Cite this article:
T'IEN TEH-CHENG;CHU HSI-HSIUNG Institute of Metal Research; Academia Sinica. APPLICATION OF THE SUB-REGULAR SOLUTION MODEL TO THE THERMODYNAMICAL ANALYSIS OF BlNARY EQUILIBRIUM DIAGRAMS. Acta Metall Sin, 1965, 8(1): 38-50.
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Abstract The application of the sub-regular solution model to the thermodynamical analysisof binary equilibrium diagrams has been discussed. A number of criterion-relations ofsub-regularity have been derived for different typical equilibrium cases. Calculationsshow that the solutions formed by the Ⅲ_B, Ⅳ_B, Ⅴ_B elements with Ge can be describedapproximately by the sub-regular solution model; the Ga-As melts in the region close tostoichiometry are nearly regular whereas the In-Sb melts are shown to be sub-regular. The constants of sub-regularity obtained can be used to calculate the thermodynamicquantities of the corresponding solutions.
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Received: 18 January 1965
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